journal article·2011-06

Effect of ageing in the electrolyte and water on porous anodic films on zirconium

F. Muratore, T. Hashimoto, P. Skeldon, G.E. Thompson

Corrosion Science· Volume 53· Issue 6
Publisher page

Abstract

The present study demonstrates the significant influence of ageing in the formation electrolyte on the morphology and composition of anodic films grown on zirconium in 0.35. M ammonium fluoride in glycerol. Ageing after anodizing, by immersion in the electrolyte for 1. h, is shown to promote a transition from a porous to a nanotubular morphology, due to the dissolution of the fluoride-rich intratubular material in which the nanotubes are embedded. The morphological change is accompanied by a significant loss of zirconium and fluorine from the film. In contrast, ageing in deionized water has little influence on the films. © 2011 Elsevier Ltd.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Anodic Oxide Films and Nanostructures · Concrete Corrosion and Durability · Concrete and Cement Materials Research

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