journal article·2019-05Open access

Uranium carbide oxidation from 873 K to 1173 K

Claudia Gasparrini, Renaud Podor, Olivier Fiquet, Denis Horlait, Sarah May, Mark R. Wenman, William E. Lee

Corrosion Science· Volume 151

Abstract

Abstract Oxidation of UC was studied from 873 to 1173 K in air and in 10 Pa oxygen using a High Temperature Environmental SEM (HT-ESEM). Conversion to U3O8 improved when using 873 K as the oxide product was a fine powder. At higher temperatures (973 K to 1173 K) oxidation slowed due to a densification process with formation of coarse fragments. The oxide fragmentation at 973 K and 1073 K and oxide pulverisation at 873 K were observed in situ in a HT-ESEM. Cracking induced fragmentation and pulverisation was linked to stresses generated from the volumetric transformation from UC to U3O8.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Nuclear Materials and Properties · Radioactive element chemistry and processing · Nuclear reactor physics and engineering

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (56)

Show source-provided references
1. Nuclear Decommissioning Authority · 2013
2. Nuclear Decommissioning Authority · 2012
3. Nuclear Decommissioning Authority · 2014 · 1
4. The ignition of uranium mononitride and uranium monocarbide in oxygen10.1016/0022-3115(67)90185-7 ↗
5. Kinetic study of the reaction between uranium monocarbide and water vapor10.1246/bcsj.40.1878 ↗
6. Kinetic studies of the hydrolysis of uranium monocarbide in the temperature range 30°C–90°C10.1016/0022-1902(70)80249-4 ↗
7. Chemical state of complex uranium oxides10.1103/PhysRevLett.111.253002 ↗
8. Thermodynamic and thermophysical properties of the actinide oxides, in: Sect. 2.02 Compr10.1016/B978-0-08-056033-5.00009-4 ↗
9. Reaction of uranium monocarbide powder in oxidizing atmospheres10.1016/0040-6031(73)85026-9 ↗
10. Matcheret · 1970
11. Isothermal oxidation of uranium monocarbide powder under controlled oxygen partial pressures10.1080/18811248.1976.9734020 ↗
12. The Oxidation of UC and UN Powder in Air10.1080/18811248.1968.9732521 ↗
13. Oxidation of uranium monocarbide10.1016/0022-5088(62)90027-9 ↗
14. Effect of humidity on the surface oxidation of UC single crystals at room temperature10.1063/1.1658277 ↗
15. Experimental kinetic study of oxidation of uranium monocarbide powders under controlled oxygen partial pressures below 230°C10.1016/j.jnucmat.2012.08.002 ↗
16. Thermodynamic and experimental study of UC powders ignition10.1016/j.jnucmat.2009.06.009 ↗
17. Siekhaus · 2015
18. Oxidation of UC: an in situ high temperature environmental scanning electron microscopy study10.1016/j.jnucmat.2017.07.016 ↗
19. On the origin of the sigmoid shape in the UO2 oxidation weight gain curves10.1016/j.jeurceramsoc.2009.04.010 ↗
20. Coppersthwaite · 2005
21. Mathematical model of the oxidation of a uranium carbide fuel pellet including an adherent product layer10.1016/j.apm.2017.01.041 ↗
22. Mathematical modelling of the pre-oxidation of a uranium carbide fuel pellet10.1016/j.compchemeng.2015.05.001 ↗
23. Uranium oxides formed in air and water in the temperature range 200-375 °C
24. Matzke · 1986
25. Oxidation of uranium dioxide in air at 350–1000°C10.1016/0022-3115(60)90051-9 ↗
26. Manara · 2012
27. Experiments on pyrochemical reprocessing of uranium carbide fuel
28. The structures of the carbides, nitrides and oxides of uranium10.1021/ja01181a029 ↗
29. Carbon positions in uranium carbides10.1107/S0365110X59000445 ↗
30. Fritsche · 1988
31. The phase transition in alpha-U3O8 at 210°C10.1107/S002188987000571X ↗
32. Triuranium heptaoxides: Heat capacities and thermodynamic properties of α- and β-U3O7 from 5 to 350°K10.1016/0022-3697(62)90055-0 ↗
33. Structure de U4O910.1107/S0365110X61002448 ↗
34. Oxidation of UO2 pellets in air10.1080/18811248.1968.9732532 ↗
35. Formation of columnar U3O8 grains on the oxidation of UO2 pellets in air at 900°C10.1016/0022-3115(94)90262-3 ↗
36. Morphological and functional effects of graphene on the synthesis of uranium carbide for isotopes production targets10.1038/s41598-018-26572-5 ↗
37. On the oxidation mechanism of pure tungsten in the temperature range 600-800°C10.1016/j.corsci.2011.12.027 ↗
38. Grain morphology and crystal structure of pre-transition oxides formed on Zircaloy-410.1016/j.corsci.2013.05.007 ↗
39. Columnar to equiaxed transition in solidification processing10.1016/S1468-6996(01)00047-X ↗
40. Recycling process for sinter-active U3O8 powders10.1080/18811248.2010.9711976 ↗
41. A review of the oxidation of uranium dioxide at temperatures below 400°C10.1016/S0022-3115(97)00343-7 ↗
42. Cuboctahedral oxygen clusters in U3O710.1016/S0022-3115(03)00318-0 ↗
43. Sintering of mixed UO2 and U3O8 powder compacts10.1016/S0022-3115(99)00212-3 ↗
44. Neutron diffraction measurements of the residual stresses in Al2O3-ZrO2(CeO2) ceramic composites10.1111/j.1151-2916.1994.tb09758.x ↗
45. Ahn · 1996
46. Implication of volume changes in uranium oxides: a density functional study10.1016/j.solidstatesciences.2013.06.013 ↗
47. Experimental characterization and modeling of UO2 grain boundary cracking at high temperatures and high strain rates10.1016/j.jnucmat.2015.02.018 ↗
48. Relevance of structure, fragmentation and reactivity of coal to combustion and oxy-combustion10.1016/j.fuel.2016.11.034 ↗
49. Oxidation of carbon: what we know and what we still need to know10.1016/j.egypro.2017.07.155 ↗
50. Effect of oxidation on creep of silicon-nitride-based ceramics
51. Grain growth in sintered uranium dioxide: II, columnar grain growth10.1111/j.1151-2916.1962.tb11027.x ↗
52. Transport phenomena in nuclear fuels under severe temperature gradients10.1016/0022-3115(79)90147-8 ↗
53. Lang · 1960
54. Matpro — Version 11 A Handbook of Materials Properties for Use in the Analysis of Light Water Reactor Fuel Rod Behavior, Idaho Natl
55. Implication of volume changes in uranium oxides: a density functional study10.1016/j.solidstatesciences.2013.06.013 ↗
56. Theoretical investigation of structural and mechanical properties of uranium oxide, uranium 2010