journal article·2016-05Open access

High-throughput characterization of the effects of H2O vapour on early oxidation across Al Fe Ni1−− composition space

Matthew A. Payne, James B. Miller, Andrew J. Gellman

Corrosion Science· Volume 106

Abstract

Abstract The presence of H2O vapour in an oxidizing environment can increase the critical aluminium concentration, N Al * , required to establish a passivating Al2O3 scale in multicomponent alumina-forming alloys. This work used AlxFeyNi1 − x − y composition spread alloy film combinatorial libraries to determine N Al * (x, y) continuously across AlxFeyNi1 − x − y composition space (x = 0 → 1, y = 0 → [1 − x]) in a 10% H2O/air mixture at 427 °C. The N Al * (x, y) in this environment was significantly higher across much of composition space than that previously measured in dry air. Physical insights from the observed differences are considered using a modified Wagner–Maak model.
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Research context

OpenAlex topics: High-Temperature Coating Behaviors · Catalytic Processes in Materials Science · Advanced ceramic materials synthesis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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