journal article·2013-12

Oxidation kinetics and mechanisms of four-direction carbon/carbon composites and their components in carbon dioxide at high temperature

Fei Qin, Li-na Peng, Guo-qiang He, Jiang Li

Corrosion Science· Volume 77
Publisher page

Abstract

Abstract Thermogravimetric analysis and scanning electron microscopy were used to study the oxidation kinetics of four-direction carbon/carbon composites and their components (fibres and matrix) in a CO 2 atmosphere at high temperature. The ablation processes were restricted to reaction-limited oxidation. The mass loss rate was estimated for the four-direction carbon/carbon composites and their components within the temperature of range of 600–1400 °C. The pressure exponent for the reaction of carbon/carbon composites and CO 2 was 0.62, and the pre-exponential factor and activation energy for the reactions of CO 2 and the carbon/carbon composites, carbon fibres and matrix were determined, respectively.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Advanced ceramic materials synthesis · Thermal and Kinetic Analysis · Advanced materials and composites

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (25)

Show source-provided references
1. Fitzer · 1998 · 190
2. C/C composite oxidation model: I. Morphological experimental investigations10.1016/S0008-6223(99)00103-7 ↗
3. D. Boury, M. Munoz, A. Albert, J.B. Lassalle, Ariane 5 SRM nozzle evolution, in: 38th AIAA/ASME/SAE/ASEE Joint Propulsion Conference and Exhibit, Indianapolis, Indiana, USA, AIAA 2002-4193, 2002.10.2514/6.2002-4193 ↗
4. Ablation of carbon-based materials: multiscale roughness modelling10.1016/j.compscitech.2008.09.019 ↗
5. Analytical modeling of the steady state ablation of a 3D c/c composite10.1016/j.ijheatmasstransfer.2008.01.008 ↗
6. Y. Aspa, Modeling of c/c Composites Ablation in Nozzle Throat, Institut de Mecanique des Fluides de Toulouse, PhD Thesis, 2006.
7. The reactivity of carbon–carbon composites10.1016/0008-6223(90)90104-7 ↗
8. Ablation behavior of HfC protective coating for carbon/carbon composites in oxyacetylene combustion flame10.1016/j.corsci.2012.08.064 ↗
9. C/SiC/Mo–Si–Cr multilayer coating for carbon/carbon composites against oxidation at high temperature10.1016/j.corsci.2012.05.023 ↗
10. Ablation of pierced c/c composite nozzles in an oxygen/ethanol combustion gas generator10.1016/j.carbon.2008.10.009 ↗
11. Ablation of the carbon/carbon composite nozzle-throat in a small solid rocket motor10.1016/j.carbon.2010.11.037 ↗
12. Improving the oxidation resistance of carbon/carbon composites at low temperature by controlling the grafting morphology of carbon nanotubes on carbon fibres10.1016/j.corsci.2012.03.031 ↗
13. Morphology, thermal response and anti-ablation performance of 3D-four directional pitch-based carbon/carbon composites10.1016/j.corsci.2012.04.036 ↗
14. Multilayer and multi-component oxidation protective coating system for carbon/carbon composites from room temperature to 1873K
15. Microstructure and evolution of iridium coating on the c/c composites ablated by oxyacetylene torch10.1016/j.actaastro.2009.08.008 ↗
16. Burning carbon particles in the presence of water vapor10.1016/0010-2180(81)90047-X ↗
17. Modeling of graphite oxidation in a stagnation-point flow field using detailed homogeneous and semiglobal heterogeneous mechanisms with comparisons to experiments10.1016/0010-2180(95)00151-4 ↗
18. The gasification of carbon by carbon dioxide at high temperatures and pressures10.1016/0008-6223(80)90061-5 ↗
19. Oxidation and ablation of 3D carbon–carbon composite at up to 3000°C10.1016/0008-6223(94)00172-V ↗
20. Oxidation kinetics and mechanisms of a 2D-c/c composite10.1016/j.carbon.2006.06.027 ↗
21. A theoretical/experimental approach to the intrinsic oxidation reactivities of c/c composites and of their components10.1016/j.carbon.2007.09.034 ↗
22. Research of 4D c/c composite material throat insert by mix weaved with carbon fibre and axial carbon rod, China
23. Effect of combustion gas mass flow rate on carbon/carbon composite nozzle ablation in a solid rocket motor10.1016/j.carbon.2011.11.034 ↗
24. Investigation on ablation behaviour of CFRC composites prepared at different pressure10.1016/j.compositesa.2004.03.024 ↗
25. Effect of oxygen partial pressure on the high-temperature oxidation of CVD SiC10.1016/S0010-938X(01)00066-X ↗