journal article·2018-05

Corrosion resistance mechanism of palladium film-plated stainless steel in boiling H 2 SO 4 solution

Junlei Tang, Zhiheng Zhang, Yingying Wang, Pengfei Ju, Yuming Tang, Yu Zuo

Corrosion Science· Volume 135
Publisher page

Abstract

Abstract The protection mechanism and corrosion behavior of the Pd film-plated stainless steel in a boiling H2SO4 solution were investigated in this paper. Potentiodynamic measurements, galvanic corrosion tests, electrochemical impedance spectroscopy and X-ray photoelectron spectroscopy were conducted to study the electrochemical modification effect of the Pd film on the passivation of stainless steel substrate. The results showed that the Pd film mainly influenced the cathodic process of corrosion. The corrosion potential of the Pd-plated stainless steel was determined by the cathode/anode area ratio. The degradation process of Pd film-plated stainless steel included three stages: stable passivation, slow corrosion and accelerated corrosion.
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Research context

OpenAlex topics: Corrosion Behavior and Inhibition · Hydrogen embrittlement and corrosion behaviors in metals · High-Temperature Coating Behaviors

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References (46)

Show source-provided references
1. Review of different passivity theories and new observations on the passivity of iron, nickel and chromium, 190810.1515/zpch-1908-6302 ↗
2. Corrosion by some organic acids and related compounds10.5006/0010-9312-8.1.14 ↗
3. Development of pitting resistant Fe-Cr-Mo alloys10.5006/0010-9312-30.3.77 ↗
4. The behavior of the chromium nickel stainless steels in sulfuric acid10.5006/0010-9312-6.8.235 ↗
5. Electrochemical characteristics of stainless steel using impressed current cathodic protection in seawater10.1016/S1003-6326(08)60380-5 ↗
6. Self-passivation of Fe-Cr-PGM alloys in reducing acids studied by electrochemical and electron spectroscopic techniques10.1016/0169-4332(90)90040-7 ↗
7. Facile preparation of hopeite coating on stainless steel by chemical conversion method10.1016/j.surfcoat.2013.12.054 ↗
8. Oxidation and electrical behavior of ferritic stainless steel interconnect with Fe-Co-Ni coating by electroplating10.1016/j.jpowsour.2012.05.013 ↗
9. Influence of layer compositions and annealing conditions on complete formation of ternary PdAgCu alloys prepared by sequential electroless and electroplating methods10.1016/j.matchemphys.2016.10.010 ↗
10. An electroless plating film of palladium on 304 stainless steel and its excellent corrosion resistance10.1016/j.tsf.2008.04.049 ↗
11. Study on corrosion resistance of palladium films on 316L stainless steel by electroplating and electroless plating10.1016/j.corsci.2008.07.014 ↗
12. Composition and corrosion resistance of palladium film on 316L stainless steel by brush plating10.1016/S1003-6326(11)61146-1 ↗
13. Chromium-palladium films on 316L stainless steel by pulse electrodeposition and their corrosion resistance in hot sulfuric acid solutions10.1016/j.corsci.2011.07.029 ↗
14. The characteristics of a Pd-Ni/Pd-Cu double coating on 316L stainless steel and the corrosion resistance in stirred boiling acetic and formic acids mixture10.1016/j.matchemphys.2013.12.024 ↗
15. Facile preparation of superamphiphobic phosphate – Cu coating on iron substrate with mechanical stability, anti-frosting properties, and corrosion resistance10.1007/s10853-016-0710-1 ↗
16. Localized electrochemical deposition of copper microstructures10.1149/1.1393237 ↗
17. Electrodeposited Pd-Ni-Mo film as a cathode material for hydrogen evolution reaction10.1016/j.electacta.2015.06.134 ↗
18. A new successive system for hydrogenation of styrene using a two-compartment cell separated by a Pd sheet electrode10.1149/1.1836603 ↗
19. Construction of a new dehydrogenation system using a two-compartment cell separated by a palladized Pd sheet electrode10.1016/S0022-0728(98)00425-2 ↗
20. The one electron reduction of primary alkyl iodides at palladiated surfaces. A convenient and general source of alkyl radicals10.1016/j.jelechem.2005.03.044 ↗
21. Sorption behavior of the overpotential-deposited H species in the cathodic H2 evolution reaction at Pd and Pt-Pd electrode composite electrodes10.1149/1.2096096 ↗
22. Electrochemical behaviour of palladium electrode: oxidation, electrodissolution and ionic adsorption10.1016/j.electacta.2008.05.046 ↗
23. Influence of temperature on the growth of surface oxides on palladium electrodes10.1016/S0022-0728(00)00505-2 ↗
24. An electrochemical and X-ray photoelectron spectroscopy study of the passive state of chromium10.1149/1.2069514 ↗
25. The cumulative effecy of alloying elements N, W Mo and Cu on the corrosion behaviour of 17Cr-13Ni stainless steel in 2N H2SO410.1016/S0010-938X(96)00033-9 ↗
26. The electrochemical behavior of austenitic stainless steel with different degrees of sensitization in the transpassive potential region in 1 M H2SO4 containing chloride10.1016/j.corsci.2003.09.020 ↗
27. Binary Zr–Ni/Co metallic glass films: role of the structural state on their durability10.1016/j.actamat.2015.01.056 ↗
28. Galvanic corrosion of Al alloys-III. The effect of area ratio10.1016/S0010-938X(75)80019-9 ↗
29. The electrochemical permeation of hydrogen in steels without palladium coating. Part II: study of the influence of microstructure on hydrogen diffusion10.1016/0010-938X(95)00080-4 ↗
30. Methods for increasing the corrosion resistance of metal alloys10.5006/0010-9312-14.5.39 ↗
31. The mechanism of passivating-type inhibitors10.1149/1.2428683 ↗
32. Corrosion and electrochemical behavior of chromium-noble metal alloys10.1149/1.2428234 ↗
33. Corrosion of passive alloys: the effect of noble metal additions
34. The chemical composition of the passive film on Fe24Cr and Fe24Cr11Mo studied by AES, XPS and SIMS10.1016/0010-938X(91)90013-F ↗
35. A bipolar model of the passivity of stainless steels-II. The influence of aqueous molybdate10.1016/0010-938X(89)90058-9 ↗
36. A bipolar model of the passivity of stainless steels-III the mechanism of MoO42− formation and incorporation10.1016/0010-938X(89)90059-0 ↗
37. Open circuit potentials of metallic chromium and austenitic 304 stainless steel in aqueous sulphuric acid solution and the influence of chloride ions on them10.1016/j.corsci.2008.01.012 ↗
38. Investigation of a passive film on an iron-chromium alloy by AES and XPS10.1002/sia.740110403 ↗
39. Non-crystalline chromium, molybdenum and tungsten phosphate films prepared by metal organic chemical vapour deposition10.1016/0040-6090(91)90122-E ↗
40. Characterization of oxide structures formed on nickel-chromium alloy during low pressure oxidation at 500-600°C10.1007/BF00666809 ↗
41. The enhanced passivation of 316L stainless steel in a simulated fuel cell environment by surface plating with palladium10.1016/j.corsci.2012.09.037 ↗
42. XPS investigations of electrochemically formed passive layers on Fe/Cr-alloys in 0.5 M H2SO410.1016/j.corsci.2004.01.007 ↗
43. Low temperature XPS studies of NO and N2O adsorption on Al(100)10.1016/0039-6028(89)90383-X ↗
44. Low temperature XPS and AES studies of O2 adsorption on Al(100)10.1016/0039-6028(89)90001-0 ↗
45. XPS analysis of oxides10.1002/sia.740120210 ↗
46. Anodic protection of stainless steel by galvanic coupling with platinum10.1016/0013-4686(65)87008-6 ↗