journal article·2008-04

Photoelectrochemical imaging of metal-scale decohesion on titanium thermally oxidised in oxygen

Y. Wouters, L. Marchetti, A. Galerie, J.-P. Petit

Corrosion Science· Volume 50· Issue 4
Publisher page

Abstract

Abstract Important compressive stress developed in TiO 2 films thermally grown on pure titanium in oxygen is known to induce scale decohesion at the metal–oxide interface. If such a phenomenon is identified in the literature to play a key role on life time of many materials used at high temperatures, no data at the microscopic level can be found at this time. In the present work using photoelectrochemical microscopy, new information in the form of two specific images ICI (interface cohesion image) and SQI (structural quality image) could be obtained. Such images revealed the level of scale decohesion induced by growth stress as well as the structural quality of the oxide layer.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: High-Temperature Coating Behaviors · Metal and Thin Film Mechanics · Thermography and Photoacoustic Techniques

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (38)

Show source-provided references
1. Oxidation mechanism of titanium and the TA6V4 alloy by water vapor10.1016/0022-5088(78)90123-6 ↗
2. Kinetics of titanium oxidation by water vapor between 750 and 1000°10.1051/jcp/1984810271 ↗
3. V.I. Dyachkov, Effect of dissolution of oxygen and hydrogen in titanium on the kinetics of its oxidation in a water–vapor atmosphere, Vestnik Leningradskogo Universiteta, Seriya 4: Fizika, Khimiya 1 (1990) 37–44.
4. Kofstad · 1987
5. Thermal oxidation of titanium by water vapour10.1016/S0167-2738(97)00400-1 ↗
6. Interfacial reactions and diffusion during the thermal oxidation of titanium in water vapour10.4028/www.scientific.net/MSF.251-254.113 ↗
7. Depletion-Layer photoeffects in semiconductors10.1103/PhysRev.116.84 ↗
8. L. Antoni, Propriétés semi-conductrices de films passifs sur aciers inoxydables formés en milieu chlorure, PhD Thesis, Institut National Polytechnique de Grenoble, France, 1996 (in French).
9. Y. Marfaing, Aspects théoriques sur les jonctions solides dans les semi-conducteurs, Ecole Interface Semi-conducteur/Electrolyte Aussois, CNRS editor, 1984, pp. 35–47.
10. Photoelectrochemical imaging of the etching and passivation of silicon in aqueous KOH10.1016/S0022-0728(96)04764-X ↗
11. Surface sensitive photoelectrochemical imaging of the derivatized surface of TiO2 on Ti10.1149/1.2069214 ↗
12. Recombination effects on current–voltage characteristics of illuminated surface barrier cells10.1149/1.2124042 ↗
13. Photocharacteristics for electrolyte–semiconductor junctions10.1149/1.2131595 ↗
14. Photoelectrochemical imaging and microscopic reactivity of oxidized titanium10.1016/S0013-4686(97)00085-6 ↗
15. Photoelectrochemical investigations of passive films on titanium electrodes10.1149/1.2108969 ↗
16. Structural and electronic properties of anodes in photoelectrolytical cells10.1117/12.936303 ↗
17. Correlation between titania film structure and near ultraviolet optical absorption10.1063/1.369553 ↗
18. Study of the thermal oxidation of Fe-15 Cr by combined Raman and photoelectrochemical imaging10.4028/www.scientific.net/MSF.461-464.681 ↗
19. Mechanisms of chromia scale failure during the course of 15-18Cr ferritic stainless steel oxidation in water vapour10.3184/096034005782750527 ↗
20. Thermal oxidation of metallic niobium by water vapor10.1023/A:1010385427776 ↗
21. Y. Wouters, Oxydation thermique des métaux dans la vapeur d’eau, cas du nickel et du titane, PhD Thesis, Institut National Polytechnique de Grenoble, France, 1996 (in French).
22. Surface-controlled photoelectrochemical microscopy of thin metal oxide films10.1039/fd9929400063 ↗
23. Heterogeneous growth of anodic oxide film on a polycrystalline titanium electrode observed with a scanning electrochemical microscope10.1149/1.1393227 ↗
24. In situ high-resolution photoelectrochemical imaging of precursor sites for pitting in polycrystalline titanium10.1149/1.1391961 ↗
25. Production of polycrystalline n-titanium dioxide layers for photoelectrochemical purpose10.1515/zna-1981-0108 ↗
26. The influence of surface structure on the photoelectrochemistry of polycrystalline n-titanium dioxide films10.1515/zna-1981-0707 ↗
27. Thin titanium dioxide film electrodes prepared by thermal oxidation10.1149/1.2069501 ↗
28. Effects of electrochemical reduction of polycrystalline TiO2 photoelectrodes in acidic solutions10.1016/0165-1633(87)90057-8 ↗
29. J. Mougin, Tenue mécanique de couche d’oxyde thermique générées sur le chrome et sur quelques aciers inoxydables ferritiques, PhD Thesis, Institut National Polytechnique de Grenoble, France, 2001 (in French).
30. Stress effects in high temperature oxidation of metals10.1179/imr.1995.40.1.1 ↗
31. Determination of mechanical adhesion energy of thermal oxide scales on AISI 430Ti alloy10.1179/174328407X168964 ↗
32. Thermal oxidation kinetics and oxide scale adhesion of 15Cr alloys in function of their silicon content10.1016/j.actamat.2006.04.023 ↗
33. Measuring adhesion of thermal alumina scale on FeCrAls
34. Adhesion behaviour of thermal oxide scales grown on ferritic stainless steels proposed as interconnects in SOFCs
35. Measuring adhesion of chromia and alumina scales on iron-based alloys10.4028/www.scientific.net/MSF.461-464.631 ↗
36. Oxidation kinetics and scale spallation of iron–chromium alloys with different titanium contents10.4028/www.scientific.net/MSF.461-464.705 ↗
37. Kofstad · 1987
38. The role of the metal/oxide interface in the growth of passive films in aqueous environments10.1016/j.corsci.2004.03.004 ↗