Borate configuration and surface pre-functionalization effects on the boronizing behavior and corrosion inhibition
Source abstract
Abstract
Surface boronizing treatment, which forms lattice defects between the boronized layer and the metal substrate, is an effective anti-corrosion strategy. We explored the bonding mode between boron-oxygen ligands and Fe substrate. [BO3] is bonded to Fe with Fe-B bonds, while [BO4] tends to form Fe-O bonds. The larger coordination number of B and O is beneficial to resist Cl- attack. Furthermore, carbon steels were amino-functionalized through a silanol condensation reaction . The electronic localization shifted toward Fe, which was conducive to the formation of hydrogen bonds between amidogen and boron-oxygen complex anions, which increased the boronizing efficiency by tenfold.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Corrosion Behavior and Inhibition · Hydrogen embrittlement and corrosion behaviors in metals · Nuclear Materials and Properties
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (31)
Show source-provided references
1. The nature of rusts and corrosion characteristics of low alloy and plain carbon steels in three kinds of concrete pore solution with salinity and different pH10.1016/j.corsci.2011.11.012 ↗
2. Role of climatic conditions on corrosion characteristics of structural steels10.1016/j.corsci.2007.06.026 ↗
3. Chloride threshold level for corrosion of steel in concrete10.1016/j.corsci.2007.05.007 ↗
4. Role of a clay sediment deposit on the corrosion of carbon steel in 0.5 mol L−1 NaCl solutions10.1016/j.corsci.2010.02.033 ↗
5. A study on the interaction between chloride ions and CO2 towards carbon steel corrosion10.1016/j.corsci.2020.108531 ↗
6. The role of acetic acid or H+ in initiating crevice corrosion of N80 carbon steel in CO2-saturated NaCl solution10.1016/j.corsci.2017.08.028 ↗
7. Single-boss crevice former for studying crevice corrosion of UNS S32003 in chloride-containing solution at high temperature10.1016/j.jallcom.2014.09.060 ↗
8. The role ofalloyed molybdenum in austenitic stainless steels in the inhibitation of pitting in neutral halide solutions10.5006/0010-9312-32.9.347 ↗
9. Effects of temperature and potential on the inhibitive action ofoxoacid salts for pitting in high-temperature chloride solutions10.5006/1.3280470 ↗
10. Auger electron spectroscopic and electrochemical analysis ofthe effect ofalloying elements on the passivation behavior of stainless steel10.5006/0010-9312-34.2.52 ↗
11. Role of alloyed molybdenum on corrosion resistance of austenitic Ni–Cr–Mo–Fe alloys in H2S–Cl- environments10.1016/j.corsci.2015.05.053 ↗
12. Corrosion of stainless steel 316L in simulated formation water environment with CO2–H2S–Cl-10.1016/j.corsci.2009.08.010 ↗
13. Mechanisms of grain boundary engineering10.1016/j.actamat.2005.11.046 ↗
14. Stabilizing nanostructures in metals using grain and twin boundary architectures10.1038/natrevmats.2016.19 ↗
15. Chemical boundary engineering: a new route toward lean, ultrastrong yet ductile steels10.1126/sciadv.aay1430 ↗
16. Grain nucleation and growth during phase transformations10.1126/science.1076681 ↗
17. Effect of boronizing treatment on the oxidation resistance of Zr2(AlSi)4C5/SiC composite10.1016/j.corsci.2019.108201 ↗
18. In-situ synthesis of SiC-ZrB2 coating by a novel pack cementation technique to protect graphite against oxidation10.1016/j.jallcom.2016.08.112 ↗
19. Effects of temperature and the incorporation of W on the oxidation of ZrB2 ceramics10.1016/j.corsci.2013.11.030 ↗
20. Nanomechanical characterization and fracture toughness of FeB and Fe2B iron borides produced by gas boriding of Armco iron10.1016/j.surfcoat.2017.07.020 ↗
21. Corrosion behavior of boronized nickel-based alloys in the molten chloride Salt10.1016/j.corsci.2021.109285 ↗
22. Study on self-lubricating properties of AlCoCrFeNi2.1 eutectic high entropy alloy with electrochemical boronizing10.1016/j.surfcoat.2022.128082 ↗
23. Enhancement of tribo-corrosion performance of carbon steel through boronizing and BN-based coatings10.1016/j.triboint.2020.106666 ↗
24. Surface boronizing can weaken the excitonic effects of BiOBr nanosheets for efficient O2 activation and selective NO oxidation under visible light Irradiation10.1021/acs.est.2c03769 ↗
25. Toward a slow-release borate inhibitor to control mild steel corrosion in simulated recirculating water10.1021/acsami.7b15507 ↗
26. Novel inorganic solid controlled-release inhibitor for Q235-b anticorrosion treatment in 1 M HCl10.1016/j.apsusc.2017.04.150 ↗
27. Boosting ethane/ethylene separation by MOFs through the amino-functionalization of pores10.1002/anie.202213015 ↗
28. Microenvironment engineering of Ru single-atom catalysts by regulating the cation vacancies in NiFe-layered double hydroxides10.1002/adfm.202109218 ↗
29. Pt–Ru dimer electrocatalyst with electron redistribution for hydrogen evolution reaction10.1021/acscatal.2c00851 ↗
30. Anti-corrosion for reversible zinc anode via a hydrophobic interface in aqueous zinc batteries
31. The response of boronized 34CrAlMo5-10 (EN41B) steel tonanoindentation, oxidation, and wear