journal article·2024-04

High-temperature corrosion of a Si3N4/W composite exposed to molten MgCl2-NaCl-KCl salts

Yueqi Wu, Mingyong Jia, Zhifeng Huang, Qiang Shen, Fei Chen

Corrosion Science· Volume 230
Publisher page

Abstract

The high-temperature corrosion behavior of a Si 3N 4/W composite under the molten MgCl 2 -NaCl-KCl salts has been investigated. It is suggested that the molten salts diffuse along the physical surface defects and enter the interior of adjacent Si 3N 4 /W grains, leading to the 9.1% bending strength loss after 400 hours for corrosion. In air atmosphere, oxidation products WO 2, WO 3 , and corrosion product MgWO 4 caused a 34.3% bending strength decrease after 400 hours for corrosion. This study elucidates the high-temperature molten chloride salt corrosion mechanisms of the Si 3N 4 /W composite material under two different atmospheres. The composite demonstrates relatively excellent corrosion resistance in service environments.
Source: expertdata · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Advanced ceramic materials synthesis · Magnesium Oxide Properties and Applications · Recycling and utilization of industrial and municipal waste in materials production

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (41)

Show source-provided references
1. Opportunities and challenges for a sustainable energy future10.1038/nature11475 ↗
2. Renewable energy resources: current status, future prospects and their enabling technology10.1016/j.rser.2014.07.113 ↗
3. State of the art on high temperature thermal energy storage for power generation. Part 1-Concepts, materials and modellization10.1016/j.rser.2009.07.035 ↗
4. A review of solar collectors and thermal energy storage in solar thermal applications10.1016/j.apenergy.2012.11.051 ↗
5. Materials compatibility for the next generation of concentrated solar power plants10.1016/j.ensm.2018.02.023 ↗
6. Thermal energy storage technologies for concentrated solar power - a review from a materials perspective10.1016/j.renene.2019.10.127 ↗
7. Investigation of using molten salt as heat transfer fluid for dry cooled solar parabolic trough power plants under desert conditions10.1016/j.enconman.2017.10.101 ↗
8. Thermal energy storage technologies and systems for concentrating solar power plants10.1016/j.pecs.2013.02.001 ↗
9. Concentrated solar power plants: review and design methodology10.1016/j.rser.2013.01.032 ↗
10. Heat transfer fluids for concentrating solar power systems – a review10.1016/j.apenergy.2015.01.125 ↗
11. Molten chloride salts for next generation CSP plants: electrolytical salt purification for reducing corrosive impurity level10.1016/j.solmat.2019.04.021 ↗
12. Assessment of a novel ternary eutectic chloride salt for next generation high-temperature sensible heat storage10.1016/j.enconman.2018.04.100 ↗
13. Thermal energy storage using chloride salts and their eutectics10.1016/j.applthermaleng.2016.07.046 ↗
14. Latest developments, assessments and research trends for next generation of concentrated solar power plants using liquid heat transfer fluids10.1016/j.rser.2022.112844 ↗
15. Molten chloride salts for next generation concentrated solar power plants: mitigation strategies against corrosion of structural materials10.1016/j.solmat.2018.12.020 ↗
16. Perspective of concentrating solar power10.1016/j.energy.2020.117373 ↗
17. High-temperature corrosion behavior of superalloys in molten salts - a review10.1080/10408436.2016.1243090 ↗
18. Corrosion behavior of metallic alloys in molten chloride salts for thermal energy storage in concentrated solar power plants: a review10.1007/s11705-018-1720-0 ↗
19. One piece ceramic heat exchanger for concentrating solar power electric plants10.1016/j.renene.2020.07.070 ↗
20. A high-performance lung-inspired ceramic 3D-printed heat exchanger for high-temperature energy-efficient systems10.1016/j.applthermaleng.2022.119378 ↗
21. Ceramic-metal composites for heat exchangers in concentrated solar power plants10.1038/s41586-018-0593-1 ↗
22. Corrosion and protection of metallic materials in molten carbonates for concentrating solar power and molten carbonate electrolysis applications10.1016/j.corcom.2023.01.003 ↗
23. Molten chloride salt technology for next-generation CSP plants: compatibility of Fe-based alloys with purified molten MgCl2-KCl-NaCl salt at 700 °C10.1016/j.apenergy.2022.119708 ↗
24. C-276 nickel alloy corrosion in eutectic Na2CO3/NaCl molten salt under isothermal and thermal cycling conditions10.1016/j.solmat.2022.111695 ↗
25. Aggressive corrosion of C-276 nickel superalloy in chloride/sulphate eutectic salt10.1016/j.solener.2021.09.023 ↗
26. The corrosion resistance mechanisms of the cr-coated SiC in molten Na2SO4 salt: strengthened boundaries and protective scales10.1016/j.corsci.2021.109421 ↗
27. Characterization of corrosion resistance of C/C–SiC composite in molten chloride mixture MgCl2/NaCl/KCl at 700 °C10.1038/s41529-019-0104-3 ↗
28. Material selection and corrosion studies of candidate bearing materials for use in molten chloride salt10.1115/1.4054507 ↗
29. A novel thermally matched conductive phase of silicon nitride ceramics10.1016/j.jpcs.2023.111379 ↗
30. The fabrication of tungsten reinforced silicon nitride ceramics by altering nitrogen pressure10.1016/j.ceramint.2018.12.061 ↗
31. Improving abrasive wear resistance of Si3N4 ceramics with self-matching through tungsten induced tribochemical wear10.1016/j.wear.2022.204254 ↗
32. Study on Tungsten metallization and interfacial bonding of silicon nitride high-temperature co-fired ceramic substrates10.3390/ma16072937 ↗
33. Silicon nitride and related materials10.1111/j.1151-2916.2000.tb01182.x ↗
34. Effects of alloying elements on the corrosion behavior of Ni-based alloys in molten NaCl-KCl-MgCl2 salt at different temperatures10.1016/j.corsci.2018.08.021 ↗
35. Shielding characteristics of nanocomposites for protection against X- and gamma rays in medical applications: effect of particle size, photon energy and nano-particle concentration10.1007/s00411-020-00865-8 ↗
36. Synergistic effect of binary fluoride sintering additives on the properties of silicon nitride ceramics10.1016/j.ceramint.2022.04.167 ↗
37. Corrosion of oxide bonded silicon carbide refractories by molten salts in solid waste-to-energy facilities10.1016/j.ceramint.2012.04.007 ↗
38. Corrosion behavior of metallic alloys in molten chloride salts for thermal energy storage in concentrated solar power plants: a review10.1007/s11705-018-1720-0 ↗
39. Identification of light elements in silicon nitride by aberration-corrected scanning transmission electron microscopy10.1016/j.ultramic.2012.05.008 ↗
40. Fatigue behavior of silicon nitride ceramics10.1016/j.ceramint.2023.06.095 ↗
41. Microstructure and shear fracture behavior of Mo/AlN/Mo symmetrical compositionally graded materials10.1016/j.msea.2021.142591 ↗