The role of electrode potential in CaCO3 scaling on steel surfaces under cathodic and corrosion conditions
Source abstract
Abstract
The role of electrode potential in CaCO 3 scaling behavior and kinetics on carbon steel and stainless steel surfaces is investigated through electrochemical tests, surface characterization, and numerical modeling. Under cathodic conditions, calcite is the dominant CaCO 3 polymorph, its lateral growth on steel surfaces follows exponential kinetics. However, under gradually promoted corrosion conditions of carbon steel, the presence of corrosion products induces more aragonite deposition and inhibits the lateral growth of CaCO 3 scale, gradually evolving from exponential to linear kinetics. This work provides further insight into how the cathodic and anodic reactions of steel corrosion respectively promote and inhibit CaCO 3 scaling.
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Research context
OpenAlex topics: Corrosion Behavior and Inhibition · Calcium Carbonate Crystallization and Inhibition · Hydrogen embrittlement and corrosion behaviors in metals
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (64)
Show source-provided references
1. A review of heterogeneous nucleation of calcium carbonate and control strategies for scale formation in multi-stage flash (MSF) desalination plants10.1016/j.desal.2018.05.008 ↗
2. A Novel approach for the evaluation of under deposit corrosion in marine environments using combined analysis by electrochemical impedance spectroscopy and electrochemical noise10.1016/j.electacta.2016.08.146 ↗
3. Mechanism of electrochemical corrosion of carbon steel under deoxygenated water drop and sand deposit10.1016/j.electacta.2013.10.079 ↗
4. Corrosion behaviour of Q235B carbon steel in sediment water from crude oil10.1016/j.corsci.2016.04.045 ↗
5. Effect of calcium on X65 carbon steel pitting in saturated CO2 environment10.1016/j.electacta.2022.139899 ↗
6. Stable Prenucleation calcium carbonate clusters10.1126/science.1164271 ↗
7. A critical review on fouling influence factors and antifouling coatings for heat exchangers of high-salt industrial wastewater
8. An electrochemical method for testing the scaling susceptibility of insulating materials10.1149/1.1418376 ↗
9. Kinetic study of the electrocrystallization of calcium carbonate on metallic substrates10.1016/j.jcrysgro.2006.03.025 ↗
10. Influence of water hardness, substrate nature and temperature on heterogeneous calcium carbonate nucleation10.1016/j.desal.2004.06.061 ↗
11. Influence of water composition and substrate on electrochemical scaling10.1149/1.1393501 ↗
12. Experimental observation of surface morphology effect on crystallization fouling in plate heat exchangers10.1016/j.icheatmasstransfer.2010.10.006 ↗
13. The use of contact angle measurements to estimate the adhesion propensity of calcium carbonate to solid substrates in water10.1016/j.apsusc.2008.12.017 ↗
14. Study of the influence of the supersaturation coefficient on scaling rate using the pre-calcified surface of a quartz crystal microbalance10.1016/j.watres.2018.05.052 ↗
15. Characterisation of calcareous deposits by electrochemical methods: role of sulphates, calcium concentration and temperature10.1016/j.electacta.2004.01.067 ↗
16. Influence of the interfacial pH on electrochemical CaCO3 precipitation10.1149/1.1613294 ↗
17. Nucleation-growth process of scale electrodeposition - Influence of the mass transport10.1016/j.electacta.2006.05.008 ↗
18. Surface inorganic scale formation in oil and gas industry: as adhesion and deposition processes10.1016/j.petrol.2015.11.005 ↗
19. Electrochemical study of calcium carbonate deposition on iron. Effect of the anion10.1016/j.electacta.2008.10.064 ↗
20. Nucleation-growth process of scale electrodeposition - influence of the magnesium ions10.1016/j.jcrysgro.2009.07.021 ↗
21. Role of sulphate ions on the formation of calcareous deposits on steel in artificial seawater; the formation of Green Rust compounds during cathodic protection10.1016/j.electacta.2009.01.023 ↗
22. Study of the effect of magnesium concentration on the deposit of allotropic forms of calcium carbonate and related carbon steel interface behavior10.1016/j.electacta.2010.01.109 ↗
23. Influence of ionic species on scaling and corrosion performance of AISI 316L rotating disk electrodes in artificial seawater10.1016/j.desal.2017.01.017 ↗
24. Nucleation-growth process of calcium carbonate electrodeposition in artificial water-Influence of the sulfate ions10.1016/j.jcrysgro.2011.02.005 ↗
25. Effect of various cations on the formation of calcium carbonate and barium sulfate scale with and without scale inhibitors10.1021/ie2003494 ↗
26. The role of Mg2+ as an impurity in calcite growth10.1126/science.290.5494.1134 ↗
27. Investigation of zinc as a scale and corrosion inhibitor of carbon steel in artificial seawater10.1016/j.corsci.2019.03.045 ↗
28. Speciation of Fe(II) and Fe(III) effect on CaCO3 crystallization10.1002/crat.201400444 ↗
29. Mechanistic study of the synergetic inhibiting effects of Zn2+, Cu2+, and Mg2+ ions on calcium carbonate precipitation10.1016/j.watres.2020.116323 ↗
30. Influence of clay on calcareous deposit in natural and artificial sea water10.1016/j.electacta.2005.09.006 ↗
31. Kaolinite influence on calcareous deposit formation10.1016/j.electacta.2009.08.037 ↗
32. Green inhibitors reduce unwanted calcium carbonate precipitation: implications for technical settings10.1016/j.watres.2021.117850 ↗
33. Calcareous deposit formation under cathodic polarization and marine biocalcifying bacterial activity10.1016/j.bioelechem.2022.108271 ↗
34. A mathematical model for modeling the formation of calcareous deposits on cathodically protected steel in seawater10.1016/j.electacta.2012.06.056 ↗
35. Electrochemical scaling of stainless steel in artificial seawater: role of experimental conditions on CaCO3 and Mg(OH)2 formation10.1016/j.desal.2012.07.011 ↗
36. Investigation of the hydrogen evolution phenomenon on CaCO3 precipitation in artificial seawater10.1016/j.desal.2018.05.018 ↗
37. Modelling of delay effect of calcium carbonate deposition kinetics on rotating disk electrode in the presence of green inhibitor10.1016/j.electacta.2015.12.089 ↗
38. Multi-meshes coupled cathodes enhanced performance of electrochemical water softening system10.1016/j.seppur.2019.01.054 ↗
39. Study on electrochemical water softening mechanism of high-efficient multi-layer mesh coupled cathode10.1016/j.seppur.2020.117001 ↗
40. Electrochemical water softening technology: From fundamental research to practical application10.1016/j.watres.2023.121077 ↗
41. Enhanced electrochemical softening of cooling water with three-dimensional cathodes10.1016/j.desal.2024.117405 ↗
42. Local scaling of CaCO3 on carbon steel surface with different corrosion types10.1016/j.powtec.2019.09.021 ↗
43. Origin of aragonite scale deposition on carbon steel at ambient circumstances10.1021/acs.iecr.7b03399 ↗
44. The role of corrosion inhibition in the mitigation of CaCO3 scaling on steel surface10.1016/j.corsci.2018.06.003 ↗
45. Improving cathode cleaning and current efficiency by regulating loose scale deposition in scale inhibitor-containing water10.1016/j.seppur.2023.124494 ↗
46. Anti-scale performance degradation of carboxylic acid scale inhibitors under corrosion conditions10.1016/j.corsci.2023.111423 ↗
47. Corrosion-induced performance degradation of phosphorus-containing scale inhibitors at carbon steel-water interface10.1021/acs.iecr.8b00223 ↗
48. Characterization of calcareous deposits in artificial seawater by impedance techniques 3 - Deposit of CaCO3 in the presence of Mg(II)10.1016/S0013-4686(03)00075-6 ↗
49. Formation of various polymorphs of calcium carbonate on porous membrane by electrochemical approach10.1016/j.jcrysgro.2009.06.016 ↗
50. Influence of pulse current on the electrodeposition behaviors of CaCO3 scale in the industrial circulating water system10.1016/j.desal.2023.116495 ↗
51. Unprecedented roles of submillimetric interelectrode distances and electrogenerated gas bubbles on mineral cathodic electro-precipitation: modeling and interface studies10.1016/j.cej.2021.133413 ↗
52. Effect of the passive films on CaCO3 scale depositing on Q235 steel: electrochemical and surface investigation10.1016/j.jcis.2021.12.078 ↗
53. Growth mechanisms of composite fouling: the impact of substrates on detachment processes10.1016/j.cej.2022.137008 ↗
54. Calcium carbonate fouling on double-pipe heat exchanger with different heat exchanging surfaces10.1016/j.powtec.2017.03.057 ↗
55. The role of carbon steel corrosion process on CaCO3 scaling in deoxidized oilfield injection water10.1002/slct.202002489 ↗
56. The study of under deposit corrosion of carbon steel in the flowback water during shale gas production10.1016/j.apsusc.2020.146534 ↗
57. Inhibition performance of benzimidazole derivatives with different heteroatoms on the under-deposit corrosion of carbon steel in CO2-saturated solution10.1016/j.corsci.2021.109841 ↗
58. Comparison study of the effect of oxide film properties on cathodic kinetics of stainless steel 304L and 316L during ORR potential window in sulfate solution10.5006/3134 ↗
59. State of the art of friendly "Green" scale control inhibitors: a review article10.1021/ie200370v ↗
60. Simultaneous EIS and in situ microscope observation on a partially blocked electrode application to scale electrodeposition10.1016/j.electacta.2005.02.117 ↗
61. Nucleation-growth process of calcium carbonate on rotating disk electrode in mineral potable water10.1016/j.electacta.2013.07.148 ↗
62. A study by electrochemical impedance spectroscopy and surface analysis of corrosion product layers formed during CO2 corrosion of low alloy steel10.1016/j.corsci.2020.108666 ↗
63. Determination of effective capacitance and film thickness from constant-phase-element parameters10.1016/j.electacta.2009.10.065 ↗
64. Identifying the dominant electrochemical reaction in electrochemical impedance spectroscopy10.1016/j.electacta.2021.139460 ↗