journal article·2024-08Open access

Intermetallic particles distribution in 7010-T7451 and 7175-T6 aluminium alloys substrate impacts cathodic stability of silicate sealed anodic oxide film

Florian Raffin, Maxime Magnan, Antoine Seyeux, Sandrine Zanna, Jacques Echouard, Jolanta Światowska, Polina Volovitch

Corrosion Science· Volume 237

Abstract

Effect of silicate sealing on tartaric sulphuric acid anodized 7010-T7451 and 7175-T6 alloys with different distributions of intermetallics (IMPs) in aluminum substrates was studied. Surface characterisations evidenced similar morphology and chemical composition of the sealed layers on both substrates. Electrochemistry and time-lapse microscopy demonstrated the layer’s stability under anodic polarization and its localized pitting under cathodic polarization in NaCl electrolyte. No chemical or morphological modifications were detected outside of the pits. The number and size of the pits depended on the IMPs distribution in the alloy, buried under 6 µm thick oxide. A degradation mechanism explaining these observations was proposed.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Anodic Oxide Films and Nanostructures · Corrosion Behavior and Inhibition · Concrete Corrosion and Durability

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (53)

Show source-provided references
1. Handbook of Aluminum
2. Anodisation de l’aluminium et de ses alliages
3. Chromate replacement: what does the future hold?10.1038/s41529-018-0034-5 ↗
4. R. Viroulaud, Protection contre la corrosion des alliages d’aluminium par la conversion TCP, influence de la chimie de surface, Université Pierre et Marie Curie, 2016.
5. FESEM and EIS Study of Sealed AA2024 T3 anodized in sulfuric acid electrolytes: influence of tartaric acid10.1149/1.2969277 ↗
6. Role of tartaric acid on the anodizing and corrosion behavior of AA 2024 T3 aluminum alloy10.1149/1.3077602 ↗
7. Effect of postreatment on the corrosion behaviour of tartaric–sulphuric anodic films10.1016/j.electacta.2009.03.083 ↗
8. Sealing of tartaric sulfuric (TSA) anodized AA2024 with nanostructured LDH layers10.1039/C5RA27286F ↗
9. Studies on the sealing processes of corrosion resistant coatings formed on 2024 aluminium alloy with tartaric-sulfuric anodizing10.1016/j.surfcoat.2018.12.092 ↗
10. Effect of acid traces on hydrothermal sealing of anodising layers on 2024 aluminium alloy10.1016/j.electacta.2010.07.089 ↗
11. Corrosion resistance of tartaric-sulfuric acid anodized AA2024-T3 sealed with Ce and protected with hybrid sol–gel coating10.1016/j.surfcoat.2019.05.028 ↗
12. EIS evolution of anodised aluminium by cerium salt sealing in NaCl solution with exposure time10.1179/1743278212Y.0000000045 ↗
13. Application of EIS to In Situ Characterization of Hydrothermal Sealing of Anodized Aluminum Alloys: comparison between Hexavalent Chromium-Based Sealing, Hot Water Sealing and Cerium-Based Sealing10.1149/2.0231610jes ↗
14. Mechanism of formation of silicate thin films on porous anodic alumina10.1016/j.surfcoat.2011.05.029 ↗
15. Sealing processes of anodic coatings—Past, present, and future10.1016/S0026-0576(01)80002-7 ↗
16. Comparative study of the effects of sealing processes on the wear resistance and the sealing quality of hard anodic coatings10.1016/S0026-0576(00)81731-6 ↗
17. Rapid sealing of an alumina nanoporous network grown by anodizing and dye-filled10.1016/j.surfcoat.2019.03.004 ↗
18. Factors controlling stress generation during the initial growth of porous anodic aluminum oxide10.1016/j.electacta.2015.01.183 ↗
19. Anodic film formation on AA 2099-T8 aluminium alloy in tartaric-sulfuric acid10.1149/1.3523262 ↗
20. N. Sukiman, X. Zhou, N. Birbilis, A.E. Hughes, J.M.C. Mol, S.J., X. Zhou, G. E, Durability and Corrosion of Aluminium and Its Alloys: Overview, Property Space, Techniques and Developments, in: Z. Ahmad (Ed.), Aluminium Alloys - New Trends in Fabrication and Applications, InTech, 2012: p. 52. https://doi.org/10.5772/53752.10.5772/53752 ↗
21. Influence of the microstructure on the corrosion behaviour of 2024 aluminium alloy coated with a trivalent chromium conversion layer10.1016/j.corsci.2018.07.007 ↗
22. Electrochemical characteristics of intermetallic phases in aluminum alloys10.1149/1.1869984 ↗
23. Investigation and discussion of characteristics for intermetallic phases common to aluminum alloys as a function of solution pH10.1149/1.2829897 ↗
24. Exploring the use of an AC-DC-AC technique for the accelerated evaluation of anticorrosion performance of anodic films on aluminium alloys
25. Chloride Ion Interactions with Oxide-Covered Aluminum Leading to Pitting Corrosion: A Review10.1149/2.1011409jes ↗
26. P. Marcus, ed., Corrosion Mechanisms In Theory and Practice, 3rd ed., CRC Press, 2011.10.1201/b11020 ↗
27. Corrosion Protection by Organic Coatings
28. Mechanisms of corrosion protection with organic coatings
29. Cathodic delamination of polybutadiene from steel-A review10.1163/156856187X00094 ↗
30. Dissolution/precipitation kinetics of boehmite and gibbsite: application of a pH-relaxation technique to study near-equilibrium rates10.1016/j.gca.2008.02.019 ↗
31. Controlling aluminium silicate formation in membrane separation processes
32. New experimental approach for intelligent screening of buried metal/oxide/polymer interfaces via local electrochemistry: example of undamaged model epoxy-coated Zn alloys10.1016/j.electacta.2020.137411 ↗
33. Electrochemical study of different ageing tests for the evaluation of a cataphoretic epoxy primer on aluminium10.1016/j.porgcoat.2005.04.004 ↗
34. Influence of the anodizing time on the microstructure and immersion stability of tartaric-sulfuric acid anodized aluminium alloys10.3390/met13050993 ↗
35. F. Andreatta, Local electrochemical behaviour of 7xxx aluminium alloys., TU Delft, 2004. http://resolver.tudelft.nl/uuid:a0692f2f-59e3-4d2f-9816-3c70211ca87e.
36. The influence of thickness, interpore distance and compositional structure on the optical properties of self-ordered anodic aluminum oxide films10.1039/C6TC01904H ↗
37. Chromate formed in a trivalent chromium conversion coating on aluminum10.1149/2.0021709jes ↗
38. A study on the self-sealing process of anodic films on aluminum by EIS10.1016/j.surfcoat.2005.10.031 ↗
39. Characterization of porous aluminium oxide films from a.c. impedance measurements10.1023/A:1003481418291 ↗
40. Characterization of anodized and sealed aluminium by EIS10.1016/S0010-938X(02)00137-3 ↗
41. Characterisation of sealed anodic films on 7050 T74 and 2214 T6 aluminium alloys10.1016/S0257-8972(01)01717-0 ↗
42. Overaging of sealed and unsealed aluminium oxide films10.1016/S0010-938X(97)00019-X ↗
43. Corrosion protection of clad 2024 aluminum alloy anodized in tartaric-sulfuric acid bath and protected with hybrid sol–gel coating10.1016/j.electacta.2013.09.004 ↗
44. Electrochemical impedance spectroscopy of protective coatings10.1002/maco.19850361102 ↗
45. AC-impedance measurements on porous aluminium oxide films10.1016/0010-938X(84)90115-X ↗
46. The sealing of porous anodic oxide films on aluminium10.1016/0013-4686(62)87009-1 ↗
47. Electrochemical impedance spectroscopy10.1038/s43586-021-00039-w ↗
48. Application of electrochemical impedance spectroscopy to study the degradation of polymer-coated metals10.1016/0300-9440(95)00581-1 ↗
49. Determination of effective capacitance and film thickness from constant-phase-element parameters10.1016/j.electacta.2009.10.065 ↗
50. Plasma-mediated nanosilver-organosilicon composite films deposited on stainless steel: synthesis, surface characterization, and evaluation of anti-adhesive and anti-microbial properties on the model yeast saccharomyces cerevisiae10.1002/ppap.201100033 ↗
51. The effect of chloride concentration and pH on pitting corrosion of AA7075 aluminum alloy coated with phenyltrimethoxysilane10.1007/s10008-011-1476-7 ↗
52. A.J. Bard, L.R. Faulkner, Electrochemical Methods Fundamentals and Applications.pdf, 2nd ed., n.d.
53. Initial cathodic reactivity of intermetallic particles in 7175 aluminum alloy buried under 6 µm thick anodized oxide layer revealed by in-situ reflective microscopy10.1016/j.electacta.2024.144155 ↗