Electron transfer kinetics and corrosion resistance of electrodeposited composit coating on titanium alloy
Source abstract
Abstract
Abstract A electrodeposited composit (EDC) coating is fabricated on Ti-6Al-4V alloys via cathodic co-deposition. The surface of EDC coating is smooth with densely distributed nanoparticles. The EDC coating is stable in corrosive media because, combining the results of comprehensive coating characterizations and electron transfer theories, its activation energy of electron transfer reaction is higher than that of the native oxide film, contributing to the decreased electron transfer constant, which eventually restrains electrode reactions and results in an enormously improvement of corrosion resistance for Ti-6Al-4V alloys.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Corrosion Behavior and Inhibition · Electrocatalysts for Energy Conversion · Electrodeposition and Electroless Coatings
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (55)
Show source-provided references
1. TC4/Ag metal matrix nanocomposites modified by friction stir processing: surface characterization, antibacterial property, and cytotoxicity in vitro10.1021/acsami.8b16343 ↗
2. Improvement of corrosion and tribocorrosion behavior of pure titanium by subzero anodic spark oxidation10.1021/acsami.8b02331 ↗
3. Effect of fluoride ions on corrosion behaviour of commercial pure titanium in artificial seawater environment10.1016/j.apsusc.2019.144759 ↗
4. In situ corrosion monitoring of Ti-6Al-4V alloy in H2SO4/HCl mixed solution using electrochemical AFM10.1016/j.electacta.2010.10.024 ↗
5. Effect of roughness on electrochemical and pitting corrosion of Ti-6Al-4V alloy in 12 wt.% HCl solution at 35 °C
6. The influence of surface modification on bacterial adhesion to titanium-based substrates10.1021/am507148n ↗
7. Surface functionalization of titanium alloy with miR-29b nanocapsules to enhance bone regeneration10.1021/acsami.5b10650 ↗
8. Enhanced osseointegration of titanium alloy implants with laser microgrooved surfaces and graphene oxide coating10.1021/acsami.9b12733 ↗
9. Effects of carbon and nitrogen plasma immersion ion implantation on in vitro and in vivo biocompatibility of titanium alloy10.1021/am302961h ↗
10. Self-assembly of TaC@Ta coreeshell-like nanocomposite film via solid-state dewetting: Toward superior wear and corrosion resistance10.1016/j.actamat.2018.08.055 ↗
11. Removing loose oxide layer and producing dense α-phase layer simultaneously to improve corrosion resistance of Ti-6Al-4V titanium alloy by coupling electrical pulse and ultrasonic treatment10.1016/j.surfcoat.2019.125329 ↗
12. Effect of decorating titanium with different self-assembled monolayers on the electrodeposition of calcium phosphate10.1021/acs.cgd.6b00057 ↗
13. Selective electrodeposition of tantalum(V) oxide electrodes10.1021/acs.langmuir.7b02414 ↗
14. Electrodeposition of diamond-like carbon films on titanium alloy using organic liquids: corrosion and wear resistance10.1016/j.apsusc.2012.08.052 ↗
15. A non-particle and fluorine-free superhydrophobic surface based on one-step electrodeposition of dodecyltrimethoxysilane on mild steel for corrosion protection10.1016/j.corsci.2019.108284 ↗
16. Electrochemical behavior and electrodeposition of Ni-Co alloy from choline chloride-ethylene glycol deep eutectic solvent10.1016/j.apsusc.2019.144889 ↗
17. Cathodic electrodeposition of nanocrystalline titanium dioxide thin films10.1149/1.1836677 ↗
18. Cathodic electrodeposition of oxide semiconductor thin films and their application to dye-sensitized solar cells10.1016/S0167-2738(02)00599-4 ↗
19. A mechanistic study on templated electrodeposition of one-dimensional TiO2 nanorods and nanotubes using TiOSO4 as a precursor10.1016/j.elecom.2014.07.011 ↗
20. TiO2/Fe2O3 photoanodes for solar water oxidation prepared via electrodeposition of amorphous precursors10.1016/j.materresbull.2019.110623 ↗
21. Kinetics of lead dioxide electrodeposition from nitrate solutions containing colloidal TiO210.1016/j.jelechem.2009.04.021 ↗
22. Anodic composite deposition of hydrous RuO2–TiO2 nanocomposites for electrochemical capacitors10.1016/j.electacta.2012.07.123 ↗
23. Mechanism of codeposition of silicon carbide with electrolytic cobalt10.1149/1.2056239 ↗
24. Direct and pulse current electrodeposition of Ni–W–TiO2 nanocomposite coatings10.1016/j.ceramint.2012.09.054 ↗
25. Introduction to electron transfer: theoretical foundations and pedagogical examples10.1021/acs.jchemed.9b00489 ↗
26. On the theory of oxidation-reduction reactions involving electron transfer10.1063/1.1742723 ↗
27. The effect of cryogenic burnishing on the formation mechanism of corrosion product film of Ti-6Al-4V titanium alloy in 0.9% NaCl solution10.1016/j.surfcoat.2018.03.102 ↗
28. Effect of nano-scale martensite and β phase on the passive film formation and electrochemical behaviour of Ti-10V-2Fe-3Al alloy in 3.5% NaCl solution10.1016/j.electacta.2018.07.047 ↗
29. 2020
30. Cathodic electrodeposition of ceramic and organoceramic materials. Fundamental aspects10.1016/S0001-8686(01)00068-9 ↗
31. Growth mechanisms of Co-Mo/TiO2 nano-composite coatings for long-term electrodeposition on disk electrodes10.1016/j.surfcoat.2019.02.028 ↗
32. Enhanced photoelectrochemical water oxidation on bismuth vanadate by electrodeposition of amorphous titanium dioxide10.1021/ja5082475 ↗
33. Different corrosion behaviors between α and β phases of Ti6Al4V in fluoride-containing solutions: Influence of alloying element Al10.1016/j.corsci.2020.108605 ↗
34. Electrochemical and tribocorrosion performances of CrMoSiCN coating on Ti-6Al-4V titanium alloy in artificial seawater10.1016/j.corsci.2019.108385 ↗
35. Development of carbon nanotubes reinforced hydroxyapatite composite coatings on titanium by electrodeposition method10.1016/j.corsci.2013.04.021 ↗
36. An electrochemical study on the effect of stabilization and sensitization heat treatments on the intergranular corrosion behaviour of AISI 321H austenitic stainless steel10.1016/j.corsci.2018.03.043 ↗
37. Tailoring hardness and electrochemical performance of TC4 coated Cu/a-C thin coating with introducing second metal Zr
38. Bio-corrosion behaviour of oxygen diffusion layer on Ti-6Al-4V during tribocorrosion10.1016/j.corsci.2017.08.031 ↗
39. A novel combined method for fabrication of stable corrosion resistance superhydrophobic surface on Al alloy10.1016/j.corsci.2019.108144 ↗
40. Improved corrosion behaviour of electron beam melted Ti-6Al–4V alloy in phosphate buffered saline10.1016/j.corsci.2017.05.003 ↗
41. Dual role of Psudoalteromonas piscicida biofilm for the corrosion and inhibition of carbon steel in artificial seawater10.1016/j.corsci.2019.02.025 ↗
42. Electrodeposition of Sn and NiSn alloys coatings using choline chloride based ionic liquids—Evaluation of corrosion behavior10.1016/j.electacta.2013.08.043 ↗
43. Anion-adsorption-related frequency-dependent double layer capacitance of the platinum-group metals in the double layer region10.1016/j.electacta.2007.11.068 ↗
44. New insight of stabilizing electrode/electrolyte interphase: regulating the specific adsorption of the inner Helmholtz plane10.1016/j.jechem.2019.10.002 ↗
45. Observation of the turnover between the solvent friction (overdamped) and tunneling (nonadiabatic) charge-transfer mechanisms for a Au/Fe(CN) 6 3-/4- electrode process and evidence for a freezing out of the marcus barrier10.1021/jp0041095 ↗
46. Bard · 1980
47. Conway · 1965
48. Study of ion transfer across the liquid-liquid interface coupled to electrochemical redox reaction at the Pt electrode with a three-electrode potentiostat10.1021/jp0757560 ↗
49. Monolayer‐protected clusters of gold nanoparticles: impacts of stabilizing ligands on the heterogeneous electron transfer dynamics and voltammetric detection10.1021/la904463g ↗
50. Contemporary issues in electron transfer research10.1021/jp9605663 ↗
51. Electron-transfer reactions of ruthenium trisbipyridyl-viologen donor-acceptor molecules: comparison of the distance dependence of electron-transfer rates in the normal and marcus inverted regions10.1021/ja00090a026 ↗
52. The distance dependence of intramolecular electron-transfer rates: importance of the nuclear factor10.1021/ja00210a074 ↗
53. Observation of the turnover between the solvent friction (overdamped) and tunneling (nonadiabatic) charge-transfer mechanisms for a Au/Fe(CN)63-/4- electrode process and evidence for a freezing out of the marcus barrier10.1021/jp0041095 ↗
54. In-situ XAFS and SERS study of self-healing of passive film on Ti in Hank’s physiological solution10.1016/j.apsusc.2019.143657 ↗
55. Understanding of the corrosion protection by V(IV) conversion coatings from a sol-gel perspective10.1016/j.corsci.2019.108196 ↗