journal article·2024-06

Formation of intragranular nanocavities in the Cr2O3 layer during the corrosion of Cr3C2+Cr coated Zirlo™

Shijing Xie, Keqiang Liu, Ruizhi Meng, Yanguang Cui, Chen Wang, Junqiang Lu, Zhongxiao Song, Dawei Wang, Wenbo Liu, Jie Qiu, Di Yun

Corrosion Science· Volume 233
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Abstract

Intragranular nanocavities were observed in the Cr 2O 3 layer of a Cr 3C 2+Cr coated Zirlo™ specimen corroded in steam at 1200 ℃ for 1 h. By comparing the coated specimen that was quenched from 1200 ℃ with the one that was not, we considered the root cause of the intragranular nanocavities in Cr 2O 3 was that the nanocavities that formed in the original coating were trapped into the Cr 2O 3 grains during the corrosion process. This explanation may also apply to the formation of intragranular nanocavities in single metal Cr-coated zirconium alloys corroded at high temperatures.
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Research context

OpenAlex topics: Nuclear Materials and Properties · Radioactive element chemistry and processing · High-Temperature Coating Behaviors

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