journal article·2024-02Open access

Delayed parabolic oxidation via transient thermal exposures on a polycrystalline nickel-based superalloy

J.W.X. Wo, D.M. Collins, M.P. Taylor, M.C. Hardy, H.J. Stone

Corrosion Science· Volume 227

Abstract

Multiple oxides were observed during the transient oxidation stage of the polycrystalline Ni-based superalloy, RR1000, before a protective Cr2O3 scale formed. Thermogravimetric analysis, synchrotron grazing incidence X-ray diffraction, and electron microscopy were performed on samples subjected to isothermal exposures at 800 °C for up to 100 hours. Transient effects governed the early stages up to 40 hours. NiO, spinels (NiCr2O4, (Ni,Co)(Cr,Co)2O4), Cr2O3/(Cr0.88Ti0.12)2O3, NiTiO3, and CrTaO4 formed during the initial stage with pseudo-linear kinetics. At the onset of parabolic kinetics, extensive Cr2O3 and TiO2 growth dominated scale formation with the former emerging as the major passivating oxide.
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Research context

OpenAlex topics: High-Temperature Coating Behaviors · Metallurgical Processes and Thermodynamics · High Temperature Alloys and Creep

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