journal article·2023-08Open access

Revealing the elusive role of water vapor in the oxidation behavior of a Mn-Si containing NiCr alloy at 950 °C

M. Romedenne, S. Lambeets, M. Song, C. Roach, A. Devaraj, R. Pillai

Corrosion Science· Volume 221

Abstract

Detailed nanoscale characterizations revealed the formation of a considerably higher fraction of SiO 2 particles in the external Cr 2O 3 layer on a NiCr alloy. In addition, atom probe tomography revealed substantially lower segregation of Mn at the Cr 2O 3 grain boundaries in wet air compared to dry air exposures, where the intriguing formation of Mn-rich clusters was observed in the Cr 2O 3 grains for the very first time. These findings provided additional evidence regarding the impact of distinct transport processes through the Cr 2O 3 layer on the resulting oxidation rates and subsurface alloy compositional changes.
Source: expertdata · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Advanced Materials Characterization Techniques · High-Temperature Coating Behaviors · Hydrogen embrittlement and corrosion behaviors in metals

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (39)

Show source-provided references
1. The role of green and blue hydrogen in the energy transition-A technological and geopolitical perspective
2. Reviewing H2 combustion: A case study for non-fuel-cell power systems and safety in passive autocatalytic recombiners10.1021/acs.energyfuels.8b00724 ↗
3. Influence of alloy additions on oxidation10.1179/mst.1989.5.8.734 ↗
4. Oxidation of Ni-Cr alloys between 800 degrees and 1200 degrees c
5. Kofstad · 1988
6. Diffusion of cations in chromia layers grown on iron-base alloys10.1007/BF00665632 ↗
7. Atom probe study of impurity segregation at grain boundaries in chromia scales grown in CO2 gas10.1016/j.corsci.2017.12.024 ↗
8. Effect of Nb addition on oxidation mechanisms of high Cr ferritic steel in Ar–H2–H2O10.1007/s11085-019-09933-x ↗
9. A nanoscale study of thermally grown chromia on high-Cr ferritic steels and associated oxidation mechanisms10.1149/1945-7111/ab7d2e ↗
10. Oxidation behavior of candidate NiCr alloys for engine exhaust valves: Part I—Effect of minor alloying elements10.1007/s11085-020-10017-4 ↗
11. Growth and adherence of chromia based surface scales on Ni-base alloys in high- and low-pO2 gases10.1016/j.msea.2007.05.035 ↗
12. Effect of water vapor on lifetime of 625 and 120 foils during oxidation between 650 and 800 °C10.1007/s11085-021-10069-0 ↗
13. Effect of cycle frequency on high-temperature oxidation behaviour of alumina- and chromia-forming alloys
14. In situ site-specific specimen preparation for atom probe tomography10.1016/j.ultramic.2006.06.008 ↗
15. Three-dimensional nanoscale characterisation of materials by atom probe tomography10.1080/09506608.2016.1270728 ↗
16. Su · 2023
17. ImageJ2: Imagej for the next generation of scientific image data10.1186/s12859-017-1934-z ↗
18. Gault · 2012
19. Effect of alloying additions and presence of water vapour on short-term air oxidation behaviour of cast Ni-base superalloys10.1016/j.corsci.2020.108774 ↗
20. Phase studies in the system chromium-manganese-titanium oxide at different oxygen partial pressures
21. Effects of silicon and water vapour on corrosion of Fe–20Cr and Fe–20Cr–20Ni alloys in CO2 at 650 ° C10.1007/s11085-016-9681-5 ↗
22. Absolute atomic-scale measurements of the Gibbsian interfacial excess of solute at internal interfaces10.1103/PhysRevB.48.6724 ↗
23. Silicon contamination during alloy oxidation in water vapour at 650 °c10.1007/s11085-022-10108-4 ↗
24. Crank · 1956 · 402
25. Diffusion of magnesium, silicon, and molybdenum in nickel10.1007/BF03397944 ↗
26. Chapter 11 - Effects of water vapour on oxidation
27. Indication of chromium oxide hydroxide evaporation during oxidation of 304L at 873 K in the presence of 10% water vapor10.1023/A:1018875024306 ↗
28. Chromium volatilization rates from Cr2O3 scales into flowing gases containing water vapor10.1007/s11085-006-9030-1 ↗
29. Vaporisation of chromia in humid air10.1016/j.jpcs.2004.06.092 ↗
30. Effect of water vapour on growth and adherence of chromia scales formed on Cr in high and low pO2-environments at 1000 and 1050° C10.3184/096034005782744443 ↗
31. About the synergetic influence of manganese and silicon on the oxidation rate of chromia forming nickel-based model alloys at 1050 ° C10.1007/s11085-020-09988-1 ↗
32. The effect of silicon and manganese on the oxidation mechanism of Ni-20 Cr10.1007/BF00603657 ↗
33. Influence of silicon additions on the oxidation resistance of a stainless steel10.1007/BF00656225 ↗
34. Effects of silicon on the oxidation behavior of Ni-base chromia-forming alloys10.1007/s11085-006-9003-4 ↗
35. Water in silica glass10.1039/tf9615701208 ↗
36. Phase equilibria in the system Cr2 O3-SiO2
37. Simultaneous sulfidation and oxidation of Fe-25wt-percent Cr and silicon-containing fe-25wt-percent Cr alloys in H2-H2O-H2S gas-mixtures at high-temperatures10.1016/0921-5093(90)90172-Y ↗
38. Identification of thin healing layers at base of oxide scales on FeCr base alloys10.1016/S0010-938X(69)80097-1 ↗
39. Defects in solids