journal article·2023-05Open access

Novel magnetron sputtered yttrium-silicon-iron oxide as CMAS resistant top coat material for environmental barrier coatings

Alexandra Rose, Juan J. Gomez Chavez, Peter Mechnich, Klemens Kelm, Uwe Schulz, Ravisankar Naraparaju

Corrosion Science· Volume 215

Abstract

A nano-crystalline coating containing X2-yttrium monosilicate, yttrium ferrite and yttria was developed as a potential CaO-MgO-Al2O3-SiO2 (CMAS) resistant top layer for Environmental Barrier Coatings (EBCs) to protect Ceramic Matrix Composites. High temperature reactions at 1300 °C with a synthetic CMAS and Colima volcanic ash revealed that the phases react quickly with the melt to oxyapatite and garnet which effectively restricted the infiltration into the coating. The Fe played a major role in stabilizing the multi-phase coating as well as X2-yttrium monosilicate. Iron-free YSi-Ox coatings could not induce garnet formation and found to be less effective in restricting the CMAS infiltration.
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Research context

OpenAlex topics: Advanced ceramic materials synthesis · High-Temperature Coating Behaviors · Nuclear materials and radiation effects

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (48)

Show source-provided references
1. Accelerated oxidation of SiC CMC's by water vapor and protection via environmental barrier coating approach10.1016/S0955-2219(02)00141-3 ↗
2. D. Zhu, Aerospace Ceramic Materials: Thermal, Environmental Barrier Coatings and SiC/SiC Ceramic Matrix Composites For Turbine Engine Applications, Glenn Research Center, 2018.
3. Advanced structural ceramics in aerospace propulsion10.1038/nmat4687 ↗
4. Thermal and environmental barrier coatings for SiC/SiC CMCs in aircraft engine applications10.1111/j.1744-7402.2004.tb00181.x ↗
5. Perspectives on environmental barrier coatings (EBCs) manufactured via air plasma spray (APS) on ceramic matrix composites (CMCs): a tutorial paper10.1007/s11666-021-01168-0 ↗
6. Paralinear oxidation of CVD SiC in water vapor10.1111/j.1151-2916.1997.tb02810.x ↗
7. An investigation on burner rig testing of environmental barrier coatings for aerospace applications10.1016/j.jeurceramsoc.2020.06.016 ↗
8. Environmental degradation of high-temperature protective coatings for ceramic-matrix composites in gas-turbine engines10.1038/s41529-019-0075-4 ↗
9. Effects of the chemistry of coating and substrate on the steam oxidation kinetics of environmental barrier coatings for ceramic matrix composites10.1016/j.jeurceramsoc.2021.04.037 ↗
10. Interaction of yttrium disilicate environmental barrier coatings with calcium-magnesium-iron alumino-silicate melts10.1016/j.actamat.2017.12.004 ↗
11. Characterization of Yb2Si2O7–Yb2SiO5 composite environmental barrier coatings resultant from in situ plasma spray processing10.1016/j.ceramint.2020.05.228 ↗
12. Recent progress on synthesis, multi-scale structure, and properties of Y–Si–O oxides10.1179/1743280414Y.0000000033 ↗
13. Thin single-phase yttrium-based environmental barrier coating systems for SiC/SiC CMCs10.1016/j.jeurceramsoc.2022.08.035 ↗
14. Thermal expansion and high-temperature phase transformation of the yttrium silicate Y2SiO510.1557/JMR.2001.0309 ↗
15. CMAS degradation of environmental barrier coatings10.1016/j.surfcoat.2007.06.045 ↗
16. Chemical and mechanical consequences of environmental barrier coating exposure to calcium–magnesium–aluminosilicate10.1111/j.1551-2916.2011.04448.x ↗
17. Calcium–magnesium aluminosilicate (CMAS) reactions and degradation mechanisms of advanced environmental barrier coatings10.1016/j.surfcoat.2013.08.036 ↗
18. Calcium–magnesium alumino-silicate interaction with yttrium monosilicate environmental barrier coatings10.1111/j.1551-2916.2010.03916.x ↗
19. Effects of cation substitution and temperature on the interaction between thermal barrier oxides and molten CMAS10.1016/j.jeurceramsoc.2014.09.006 ↗
20. Molten silicate reactions with plasma sprayed ytterbium silicate coatings10.1016/j.surfcoat.2015.12.053 ↗
21. Phase equilibria and crystal chemistry in the calcia–silica–yttria system10.1016/j.jeurceramsoc.2016.01.046 ↗
22. High-Temperature thermochemical interactions of molten silicates with Yb2Si2O7 and Y2Si2O7 environmental barrier coating materials10.1016/j.jeurceramsoc.2019.06.051 ↗
23. Hot corrosion of RE2SiO5 with different cation substitution under calcium–magnesium–aluminosilicate attack10.1016/j.ceramint.2017.04.045 ↗
24. Corrosion of RE2Si2O7 (RE=Y, Yb, and Lu) environmental barrier coating materials by molten calcium-magnesium-alumino-silicate glass at high temperatures10.1016/j.jeurceramsoc.2019.05.036 ↗
25. Environmental-barrier coating ceramics for resistance against attack by molten calcia-magnesia-aluminosilicate (CMAS) glass: part II, β-Yb2Si2O7 and β-Sc2Si2O710.1016/j.jeurceramsoc.2018.03.010 ↗
26. The influence of calcium–magnesium–aluminosilicate deposits on internal stresses in Yb2Si2O7 multilayer environmental barrier coatings10.1016/j.actamat.2015.12.016 ↗
27. Modeling of thermal residual stress in environmental barrier coated fiber reinforced ceramic matrix composites10.1177/0021998311414950 ↗
28. 2ZrO2·Y2O3 thermal barrier coatings resistant to degradation by molten CMAS: part II, interactions with sand and fly ash10.1111/jace.13209 ↗
29. Composition effects of thermal barrier coating ceramics on their interaction with molten Ca–Mg–Al–silicate (CMAS) glass10.1016/j.actamat.2012.06.053 ↗
30. Effect of CMAS deposits on MOCVD coatings in the system Y2O3–ZrO2: phase relationships10.1111/jace.12502 ↗
31. Effects of yttria content on the CMAS infiltration resistance of yttria stabilized thermal barrier coatings system10.1016/j.jmst.2019.09.039 ↗
32. Comparative study of EB-PVD gadolinium-zirconate and yttria-rich zirconia coatings performance against Fe-containing calcium-magnesium-aluminosilicate (CMAS) infiltration10.1016/j.corsci.2021.109660 ↗
33. Interaction and infiltration behavior of Eyjafjallajökull, Sakurajima volcanic ashes and a synthetic CMAS containing FeO with/in EB-PVD ZrO2-65 wt% Y2 O3 coating at high temperature10.1016/j.actamat.2017.06.055 ↗
34. P. Mechnich, 43rd International conference and exposition on advanced ceramics and composites, Complex Melting Behavior of Si-lean, Fe-Ti-CMAS and its effects on the Recession of EB-PVD Gadolinium-Zirconate TBC (2019).
35. R. Naraparaju, CMAS-Resistente Schutzschicht DE 10 2017 119 387 A1 2019.02.28 (2017).
36. R. Naraparaju, CMAS resistant Protective layer US2019/0062898 (2019).
37. High temperature interaction of volcanic ashes with 7YSZ TBC's produced by APS: infiltration behavior and phase stability10.1016/j.surfcoat.2019.124915 ↗
38. Reaction products from high temperature treatments of (LaxGd1−x)2Zr2O7 system and volcanic ash powder mixtures10.1007/s11837-022-05302-3 ↗
39. Thermochemical interaction of thermal barrier coatings with molten CaO–MgO–Al2O3–SiO2 (CMAS) deposits10.1111/j.1551-2916.2006.01209.x ↗
40. Hafnia-doped silicon bond coats manufactured by PVD for SiC/SiC CMCs10.1016/j.actamat.2019.10.050 ↗
41. Y2SiO5 coatings fabricated by RF magnetron sputtering10.1016/j.surfcoat.2013.08.015 ↗
42. V. Leisner, LINCET 1 Symposium, Development of EBCs for SiC/SiC CMCs Employing PVD Technologies (2017).
43. Reactive sputtered ytterbium silicate environmental barrier coatings for protection of Mo-Si-based alloys10.3390/coatings12081086 ↗
44. Yttrium silicate coatings on chemical vapor deposition-SiC-precoated C/C–SiC: thermodynamic assessment and high-temperature investigation10.1111/j.1551-2916.2005.00077.x ↗
45. The relationship between specific heat capacity and oxidation resistance of TiAl alloys
46. Influence of iron on the synthesis and stability of yttrium silicate apatite10.1016/S1293-2558(01)01151-7 ↗
47. Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides10.1107/S0567739476001551 ↗
48. Role of thermodynamic miscibility gaps in phase selection in sol-gel synthesis of yttrium silicates10.1016/j.jeurceramsoc.2017.06.040 ↗