journal article·2023-03

Effect of polyethylene glycol modification on the corrosion behavior of hydroxyapatite-coated AZ31 Mg alloy under tensile deformation

Sachiko Hiromoto, Kotaro Doi

Corrosion Science· Volume 212
Publisher page

Abstract

The effect of polyethylene glycol (PEG) modification on the corrosion behavior under tensile deformation of hydroxyapatite-coated Mg-3mass% Al-1mass% Zn (HAp-AZ31) was examined in Hanks’ solution. Slow strain rate tensile (SSRT) and rapid straining electrode (RSE) tests and electrochemical impedance measurements were performed. In SSRT tests, PEG-modified HAp-AZ31 showed 1.4 times longer elongation to failure than HAp-AZ31. In RSE tests, the PEG modification showed little effect on cracking of HAp coating, while it reduced corrosion propagation from the cracks by half. The improvement in tensile elongation of HAp-AZ31 with PEG is attributed to the inhibition of corrosion propagation from coating cracks.
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Research context

OpenAlex topics: Magnesium Alloys: Properties and Applications · Aluminum Alloys Composites Properties · Corrosion Behavior and Inhibition

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (26)

Show source-provided references
1. The history of biodegradable magnesium implants: a review10.1016/j.actbio.2010.02.028 ↗
2. Biodegradable magnesium alloys as temporary orthopaedic implants: a review10.1007/s10534-019-00170-y ↗
3. Early results using a biodegradable magnesium screw for modified chevron osteotomies10.1002/jor.23241 ↗
4. Current status on clinical applications of magnesium-based orthopaedic implants: a review from clinical translational perspective10.1016/j.biomaterials.2016.10.017 ↗
5. Orthopedic applications
6. Influence of a MAO plus PLGA coating on biocorrosion and stress corrosion cracking behavior of a magnesium alloy in a physiological environment10.1016/j.corsci.2018.12.005 ↗
7. High corrosion resistance of magnesium coated with hydroxyapatite directly synthesized in an aqueous solution10.1016/j.electacta.2009.07.033 ↗
8. Influence of substrate microstructure on hydroxyapatite coating and corrosion behavior of coated Mg-Zn alloys10.1016/j.surfcoat.2021.127414 ↗
9. Osteoclast and osteoblast responsive carbonate apatite coatings for biodegradable magnesium alloys10.1080/14686996.2020.1761237 ↗
10. In vitro and in vivo biocompatibility and corrosion behaviour of a bioabsorbable magnesium alloy coated with octacalcium phosphate and hydroxyapatite10.1016/j.actbio.2014.09.026 ↗
11. In vivo degradation and bone formation behaviors of hydroxyapatite-coated Mg alloys in rat femur10.1016/j.msec.2021.111942 ↗
12. Short- and long-term corrosion behavior of carbonate apatite-coated Mg-4mass% Y-3mass% RE alloy in cell culture medium10.1016/j.corsci.2022.110222 ↗
13. Self-healing property of hydroxyapatite and octacalcium phosphate coatings on pure magnesium and magnesium alloy10.1016/j.corsci.2015.08.001 ↗
14. Self-healing behavior of sodium polyacrylate-hydroxyapatite coatings on biodegradable magnesium alloy10.5006/2509 ↗
15. Hydrogels
16. Vibrational-spectra and conformation of polyethylene-glycol complexed with calcium and magnesium chlorides10.1016/0022-2860(90)80200-4 ↗
17. Chap. 8 Characterization of calcium phosphates using vibrational
18. Stress corrosion cracking behavior of the wrought magnesium alloy AZ31 under controlled cathodic potentials
19. Pitting-induced hydrogen embrittlement of magnesium-aluminium alloy10.1016/j.matdes.2012.06.007 ↗
20. Intergranular stress corrosion crack propagation in hot-rolled AZ31 Mg alloy sheet10.1016/j.msea.2014.02.077 ↗
21. Hydrogen-induced embrittlement of fine-grained twin-roll cast AZ31 in distilled water and NaCl solutions10.1007/s10853-015-9064-3 ↗
22. Breakdown of passive films and repassivation of Ti-6Al-4V alloy with rapid elongation in simulated body fluid including osteoblast-like cells10.1149/2.085311jes ↗
23. Microstructure of hydroxyapatite- and octacalcium phosphate-coatings formed on magnesium by a hydrothermal treatment at various pH values10.1016/j.actamat.2010.09.041 ↗
24. M. Itagaki, Electrochemical Impedance Method, Principle, Measurement and Analysis, Maruzen, Japan, 2011.
25. Electrochemical impedance of thin rust film of low-alloy steels10.1016/j.corsci.2003.08.002 ↗
26. Concerning the conversion of the constant phase element parameter Y0 into a capacitance10.5006/1.3280607 ↗