journal article·2024-05

Distinct phase-selective corrosions of Ti-48Al alloy in aqueous electrolyte and molten salt

Xiaohu Huang, P.S. Sankara Rama Krishnan, Kai Xiang Kuah, Tzee Luai Meng, Yee Ng, Hailong Liu, Siew Lang Teo, Rahul Karyappa, Ming Lin, Andrew Chun Yong Ngo, R.V. Ramanujan, Daniel J. Blackwood, Hongfei Liu

Corrosion Science· Volume 231
Publisher page

Abstract

Corrosion of Ti-48Al alloys, consisting of γ-TiAl phase and α 2-Ti 3 Al phase in lamellar structures, has been studied by electrochemical method at room temperature and molten salt method at elevated temperatures, respectively. Morphological, crystallographic, and microstructural studies provide direct evidence for γ-phase selective etching by the electrochemical corrosion at room temperature. In contrast, α 2 -phase selective etching of the Ti-48Al alloy occurred during molten salt corrosion, alongside α 2 -to-γ phase transformations at elevated temperatures. The distinct corrosion behaviors have been discussed and attributed to different chemical and physical properties between γ-TiAl and α 2-Ti 3Al phases within the Ti-48Al alloy.
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Research context

OpenAlex topics: Intermetallics and Advanced Alloy Properties · Metallurgical and Alloy Processes · Hydrogen Storage and Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (63)

Show source-provided references
1. Prediction modeling of type-I hot corrosion performance of Ti–Al–Mo-X (X=Cr, Mn) alloys in (Na, K)2so4 molten salt mixture environment at 900°C10.1016/j.jallcom.2020.156010 ↗
2. Hot corrosion behavior of Ti-48al and Ti-48al-2cr intermetallic alloys produced by electric current activated sintering10.1007/s11661-018-4581-8 ↗
3. Effect of microstructure on the high-temperature deformation behavior of Ti-48al-2w intermetallic compounds10.1016/S0921-5093(99)00259-2 ↗
4. Improved mechanical properties of a Ti-48al Alloy processed by mechanical alloying and spark plasma sintering
5. Development of Gamma titanium aluminide (Γ-Tial) Alloys: a review10.1016/j.jallcom.2022.167262 ↗
6. Isothermal oxidation behaviour of TiAl alloys prepared by spark plasma sintering with the addition of Gd under Water vapour at 900 °C10.1016/j.intermet.2022.107796 ↗
7. Additive manufacturing of gamma titanium aluminide alloys: a review10.1007/s10853-022-06896-4 ↗
8. Titanium aluminides processing by additive manufacturing – a review10.1007/s00170-022-08728-w ↗
9. Effect of C/N INcorporation on Structural and Crystallographic Properties of Tanbzr coatings deposited by double-glow plasma surface alloying on Ti-Alloy substrate10.1016/j.surfcoat.2023.130356 ↗
10. Systematic investigation of the deformation mechanisms of a Γ-Tial single crystal10.1038/s41598-018-33377-z ↗
11. Musi, M.; Graf, G.; Clemens, H.; Spoerk-Erdely, P., Alloying Elements in Intermetallic Γ-Tial Based Alloys – a Review on Their Influence on Phase Equilibria and Phase Transformations. Advanced Engineering Materials, n/a.
12. Emerging functional metals in additive manufacturing10.1002/adem.202201800 ↗
13. Development of low-cost titanium alloys: a chronicle of challenges and opportunities10.1016/j.matpr.2020.02.978 ↗
14. A new experimental technique to investigate the Α2/Γ interface of lamellar tial alloy three dimensionally10.1016/S0966-9795(01)00120-0 ↗
15. Atomic layer deposition of Al2o3 thin films for corrosion protections of additive manufactured and wrought stainless steels 316l10.1016/j.matlet.2022.133434 ↗
16. Galvanic corrosion protection of Al-Alloy in contact with carbon fibre reinforced polymer through plasma electrolytic oxidation treatment10.1038/s41598-022-08727-7 ↗
17. Stress corrosion cracking of titanium aluminide alloys in aqueous solution and methanol10.1016/0956-716X(92)90683-6 ↗
18. A comparative assessment of Ti-47.5 at%Al cathodically modified by precious metal addition.
19. High-temperature oxidation and hot corrosion of Ni-based single crystal superalloy in the incubation stage10.1016/j.corsci.2023.111026 ↗
20. Hot corrosion and internal spallation of laser-cladded inconel 625 superalloy coatings in molten sulfate salts10.1016/j.corsci.2021.109869 ↗
21. Hot corrosion studies of a salt-coated Ni-based superalloy under flowing wet air and sulfur vapor ambient10.1002/maco.202011667 ↗
22. Analysis on corrosion fatigue cracking mechanism of 17–4 ph blade of low pressure rotor of steam turbine10.1016/j.engfailanal.2020.104925 ↗
23. Computational modeling of non-equilibrium condensing steam flows in low-pressure steam turbines10.1016/j.rineng.2019.100065 ↗
24. Molten salt vapour corrosion of Ti3al and Tial based intermetallics10.1515/HTMP.2002.21.3.167 ↗
25. Inter-phase selective corrosion of Γ-TiAl alloy in molten salt environment at high temperature10.1016/S1002-0071(12)60064-1 ↗
26. Comparative study of the oxidation and hot corrosion behaviors of TiAl-Cr intermetallic alloy produced by electric current activated sintering10.1016/j.jallcom.2018.11.324 ↗
27. Hot corrosion behaviour of (Γ+Α2)-Ti-46al-8nb (at%) and Α-Ti-6al-1mn (at%) Alloys10.1016/j.corsci.2016.11.006 ↗
28. Phase transformations in TiAl based alloys10.1016/j.actamat.2005.02.025 ↗
29. High-temperature phase change materials for thermal energy storage10.1016/j.rser.2009.11.011 ↗
30. Assessment of a novel ternary Eutectic chloride salt for next generation high-temperature sensible heat storage10.1016/j.enconman.2018.04.100 ↗
31. Laser-cladding and interface evolutions of inconel 625 alloy on low alloy steel substrate upon heat and chemical treatments10.1016/j.surfcoat.2020.126607 ↗
32. The influence of pore morphology on corrosion10.1016/S0010-938X(97)00152-2 ↗
33. Influence of porosity on mechanical and corrosion properties of Slm 316l stainless steel10.1007/s00339-021-05191-4 ↗
34. Voltage contrast in scanning electron microscopy to distinguish conducting Ag nanowire networks from nonconducting Ag nanowire networks10.1021/acsomega.9b04222 ↗
35. Field-emission sem imaging of compositional and doping layer semiconductor superlattices10.1016/0304-3991(94)00183-N ↗
36. Solid-state reaction studies in Al2O3–Tio2 system by diffusion couple method10.2355/isijinternational.ISIJINT-2017-042 ↗
37. The anodic polarization of titanium in Halide solutions10.1016/0010-938X(64)90041-1 ↗
38. Corrosion behavior of binary titanium aluminide intermetallics10.5006/1.3292153 ↗
39. Electrochemical behavior of Ti/Al2o3 interfaces produced by diffusion bonding10.1590/S1516-14392003000400002 ↗
40. Hot corrosion behaviour of Ti–Al based intermetallics.10.1016/S0167-577X(02)00882-0 ↗
41. Cvd growth of Mos2-based two-dimensional materials10.1002/cvde.201500060 ↗
42. Vapor-phase growth and characterization of Mo1−Xwxs2 (0 ≤ X ≤ 1) atomic layers on 2-inch sapphire substrates10.1039/C3NR04515C ↗
43. Influence of stress on structural properties of Algan/Gan high electron mobility transistor layers grown on 150 Mm diameter Si (111) substrate
44. Growth and in-plane undulations of Gaas/Ge superlattices on [001]-oriented Ge and Gaas substrates: formation of regular 3D island-in-network nanostructures10.1039/C8TC04799E ↗
45. Direct deposition of low-cost carbon fiber reinforced stainless steel composites by twin-wire arc spray10.1016/j.jmatprotec.2021.117440 ↗
46. Laser-treatment-induced morphology and structure modifications of stainless steel: element segregations and phase evolutions10.1016/j.matchemphys.2021.124570 ↗
47. Raman scattering study on Anatase Tio2 nanocrystals10.1088/0022-3727/33/8/305 ↗
48. Raman spectroscopy of Tio2 thin films formed by hybrid treatment for biomedical applications10.1016/j.saa.2014.05.045 ↗
49. Cobalt sulfide nanoparticles decorated on Tio2 nanotubes via thermal vapor sulfurization of conformal Tio2-Coated Co(Co3)0.5(Oh)·0.11h2o COre–shell Nanowires for Energy Storage Applications.10.1039/C5RA07444D ↗
50. Ordered domains in TiAl coexisting with Ti3al in the lamellar structure of Ti-Rich TiAl compounds10.1080/01418619208201574 ↗
51. Alignment of the TiAl/Ti3al lamellar microstructure in TiAl alloys by growth from a seed material10.1016/S1359-6454(96)00335-7 ↗
52. Effects of heat treatment on the microstructures and mechanical properties of as-cast Ti-45al-2nb-2cr-(0.2, 0.5) C alloys
53. Effects of cycle heat treatment on the microstructure and mechanical property of as-cast Γ-Tial alloy10.1016/j.msea.2022.144053 ↗
54. Research progress on the corrosion behavior of titanium alloys10.1515/corrrev-2022-0031 ↗
55. Fabricating high-quality Gan-based nanobelts by strain-controlled cracking of thin solid films for application in piezotronics10.1016/j.nanoen.2011.12.007 ↗
56. Epitaxial growth and chemical lift-Off of Gainn/Gan heterostructures on C- and R-sapphire substrates employing Zno sacrificial templates10.1116/1.3443220 ↗
57. Effects of lift-off and strain relaxation on optical properties of Ingan/Gan blue led grown on 150mm diameter Si (111) substrate10.1016/j.jcrysgro.2014.05.024 ↗
58. Method to determine Mgo and Mgohcl in chloride molten salts10.1021/acs.analchem.9b04301 ↗
59. A thermochemical analysis of the production of anhydrous Mgcl210.1016/S1471-5317(01)00004-9 ↗
60. Nacl-induced hot corrosion of a titanium aluminide alloy10.1016/0921-5093(95)03345-9 ↗
61. High temperature oxidation and hot corrosion behaviors of Ti2alnb alloy at 923 K and 1023 K10.1016/j.corsci.2021.109336 ↗
62. Diffusion in the Ti–Al system10.1016/S1359-6454(99)00400-0 ↗
63. High speed dynamic deformation of polysynthetic twinned titanium aluminide intermetallic compound10.1016/j.actamat.2018.04.037 ↗