journal article·2021-09Open access

Influence of uniaxial deformation on surface morphology and corrosion performance of chromium-based coatings for packaging steel

Jordan Whiteside, Arnoud C.A. de Vooys, Elizabeth Sackett, Hamilton N. McMurray

Corrosion Science· Volume 190

Abstract

Abstract Chromium-based coatings on steel, cathodically electroplated from Cr(VI) and Cr(III) electrolytes, were studied to compare their corrosion resistance following application of uniaxial strain. An organic overcoat (PVB) was applied to strained samples and an in-situ scanning Kelvin probe technique was used to determine rates of PVB cathodic disbondment. The Cr(VI) derived coatings were fully resistant to cathodic disbondment post-deformation. The Cr(III) derived coatings exhibited increased rates of cathodic disbondment with increasing uniaxial strain. The Kinetics of cathodic disbondment are explained on the basis of coating morphology produced by deformation, and the exposure of underlying iron. The electrochemical availability of iron is estimated by measuring hydrogen evolution kinetics on cathodically polarised samples.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Corrosion Behavior and Inhibition · Hydrogen embrittlement and corrosion behaviors in metals · Concrete Corrosion and Durability

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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