journal article·2020-08Open access

Effect of a pre-oxidation on the hydrogen desorption from Zircaloy-4

C. Juillet, M. Tupin, F. Martin, Q. Auzoux, S. Bosonnet, C. Berthinier

Corrosion Science· Volume 173

Abstract

Abstract During the transport of nuclear spent fuel, part of the tritium formed by ternary fission in core of nuclear reactors is susceptible to desorb from the oxidized cladding. This study aimed at identifying the rate-limiting step in the hydrogen desorption process from pre-oxidized Zircaloy-4 specimens. Controlled-thickness oxide scales shifted the hydrogen desorption from the alloy towards higher temperatures during a temperature ramp under vacuum. Scanning electron microscopy observations and finite elements modelling of the oxide layer dissolution led to the conclusion that, in such conditions, hydrogen desorption from the alloy was controlled by the oxide dissolution kinetics.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Nuclear Materials and Properties · Fusion materials and technologies · Nuclear reactor physics and engineering

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (36)

Show source-provided references
1. IAEA · 1998
2. Kinetics of hydrogen desorption from Zircaloy-4: Experimental and modelling10.1016/j.ijhydene.2019.06.034 ↗
3. Penetration mechanisms of surface-adsorbed hydrogen atoms into bulk metals: Experiment and model10.1103/PhysRevB.78.115411 ↗
4. Absorption and desorption kinetics of hydrogen storage alloys10.1016/0925-8388(96)02217-7 ↗
5. Low‐Pressure Solubility and Diffusion of Hydrogen in Zirconium10.1149/1.2428522 ↗
6. Analyse a l’aide d’une methode nucleaire des impuretes introduites dans les metaux par leurs preparations d’etat de surface: Application au zirconium10.1016/0022-3115(69)90093-2 ↗
7. An autoradiographic technique for the study of tritium in metals and its application to diffusion in zirconium at 149° to 240° C10.1016/0022-3115(62)90272-6 ↗
8. Diffusion of tritium in zircaloy-210.1016/0022-3115(80)90381-5 ↗
9. The diffusion and solubility of hydrogen in the alpha phase of Zircaloy-210.1016/0022-3115(60)90025-8 ↗
10. Observation of the behavior of hydrogen in zirconium
11. Hydrogen Pickup and redristribution in alpha annealed Zircaloy-4, Zircon
12. The study of hydrogen segregation on Zr(0001) and Zr(1010) surfaces by static secondary ion mass spectroscopy, work function, Auger electron spectroscopy and nuclear reaction analysis10.1016/0925-8388(95)01847-6 ↗
13. Tritium diffusion in zircaloy-2 in the temperature range −78 to 204° C10.1016/0022-3115(74)90197-4 ↗
14. Hydrogen diffusion process in the oxides formed on zirconium alloys during corrosion in pressurized water reactor conditions10.1016/j.corsci.2016.10.027 ↗
15. Deuterium diffusion in steam-corroded oxide layer of zirconium alloys10.1016/j.jnucmat.2011.06.001 ↗
16. Tritium release from Zircaloy-2: Dependence on temperature, surface conditions and composition of surrounding medium10.1016/0022-3115(85)90026-1 ↗
17. Andrieu · 1998
18. Influence of oxide layer on hydrogen desorption from zirconium hydride10.1016/j.jallcom.2008.01.157 ↗
19. Diffusion of tritium in zircaloy: Influence of low irradiation damage, oxygen concentration and formation of δ-hydrides10.1016/0022-3115(82)90372-5 ↗
20. High-temperature absolute hydrogen desorption kinetics of zirconium hydride under clean and oxidized surface conditions10.1016/j.jnucmat.2010.05.025 ↗
21. XPS study of hydrogen and oxygen interactions on the surface of zirconium10.1016/S0925-8388(03)00356-6 ↗
22. Release of fission tritium through Zircaloy-4 fuel cladding tubes10.1016/j.jnucmat.2005.06.008 ↗
23. Oxidation kinetics and oxygen diffusion in low-tin Zircaloy-4 up to 1523K10.1016/j.jnucmat.2008.03.012 ↗
24. The O−Zr (Oxygen-Zirconium) system10.1007/BF02881546 ↗
25. Dependence of surface oxidation on hydrogen absorption and desorption behaviors of Ti–6Al–4V alloy10.1016/S0022-3115(98)00607-2 ↗
26. Effect of cold rolling on the hydrogen absorption and desorption kinetics of Zircaloy-410.1016/j.matchemphys.2015.02.036 ↗
27. Effect of pH on hydrogen pick-up and corrosion in zircaloy-4
28. www-cast3m.cea.fr/.
29. Finite element modelling of the oxidation kinetics of Zircaloy-4 with a controlled metal-oxide interface and the influence of growth stress10.1016/j.corsci.2015.07.024 ↗
30. Differences in reactivity of oxide growth during the oxidation of Zircaloy-4 in water vapour before and after the kinetic transition10.1016/S0022-3115(02)01704-X ↗
31. The relation between tarnishing and corrosion
32. Barret · 1973
33. Parise · 1996
34. Transport of Oxygen in Oxide Films on Zirconium Determined by the Nuclear Reaction O17 (He3,a)O16
35. Douglass · 1962
36. Debuigne · 1962