journal article·2018-10

Silicon effects on the wet oxidation of type 310 stainless steel

Shooka Mahboubi, Hatem S. Zurob, Gianluigi A. Botton, Joseph R. Kish

Corrosion Science· Volume 143
Publisher page

Abstract

Abstract The wet oxidation performance of a high-Si (5.9 wt.%) Type 310 stainless steel exposed in flowing ambient pressure (0.1 MPa) air-10% H2O mixture at 800 °C was investigated. A lower parabolic rate constant, relative to that exhibited by conventional low-Si (0.6 wt.%) Type 310S stainless steel, in the observed paralinear kinetics is linked to the formation of a continuous SiO2 layer at the oxide scale/metal interface. Accelerated formation of non-protective Fe-rich oxides is significantly delayed due to Cr-rich silicide intermetallic phase, present in the starting microstructure, serving as reservoir to sufficiently supply Cr to replace oxidized Cr lost to volatilization.
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OpenAlex topics: High-Temperature Coating Behaviors · High Temperature Alloys and Creep · Nuclear Materials and Properties

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