journal article·2023-12Open access

Unravelling the effect of F phase on hydrogen-assisted intergranular cracking in nickel-based Alloy 725: Experimental and DFT study

Xu Lu, Yan Ma, Yuan Ma, Dong Wang, Lei Gao, Wenwen Song, Lijie Qiao, Roy Johnsen

Corrosion Science· Volume 225

Abstract

The effect of the scarcely reported F phase on hydrogen-assisted cracking in nickel-based Alloy 725 was thoroughly studied by combining tensile tests, advanced characterization, and density functional theory (DFT) calculations. The results show grain boundary precipitate F phase promotes intergranular fracture in a hydrogen environment. DFT calculations further indicates hydrogen atoms lower the binding strength of the F phase and Ni matrix interfaces. More importantly, our study showed for the first time that the addition of approximately 0.01 wt.% boron can effectively suppress F phase precipitation, thereby elevating the hydrogen resistance of Alloy 725.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Hydrogen embrittlement and corrosion behaviors in metals · Corrosion Behavior and Inhibition · High Temperature Alloys and Creep

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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