journal article·2021-03Open access

The influence of temperature on hydrogen environmentally assisted cracking of AA7449-T7651 in moist air

Unai De Francisco, Nicolas O. Larrosa, Matthew J. Peel

Corrosion Science· Volume 180

Abstract

The 7xxx series of aluminium alloys are sensitive to intergranular hydrogen environmentally assisted cracking (HEAC) in moist air environments. A new generation of 7xxx alloys used in aircraft components (including AA7449) have been found to be more sensitive to HEAC. This investigation aims to quantify the HEAC crack growth rates of AA7449-T7651 in moist air at different temperatures. Double cantilever beam specimens were loaded at a constant displacement and placed in moist air (80–85% relative humidity) at temperatures between 25 and 80 °C. Regular measurements of crack length permitted the determination of the crack growth rate as a function of the stress intensity factor (KI) during stage I (high KI dependence of growth rate) and stage II (low KI dependence of growth rate). Increasing the temperature was found to increase the crack growth rate during stage II cracking, following Arrhenius kinetics. The activation energy for the stage II crack growth rate at a stress intensity factor of 14.5 MPam was estimated as 84.7 kJ/mol. Additionally, the threshold stress intensity factor for HEAC was found to decrease with increasing temperature. This was attributed to a higher hydrogen solubility at higher temperatures. The crack growth rate of AA7449-T7651 at room temperature was similar to that of overaged AA7050 and AA7075-T7651, ranging between 1.3 and 2.1 × 10−7 mm/s. It was inferred that the alloy temper has more influence than the composition during stage II cracking at room temperature.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Hydrogen embrittlement and corrosion behaviors in metals · Fatigue and fracture mechanics · Corrosion Behavior and Inhibition

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (35)

Show source-provided references
1. E. A. S. A. (EASA) · 2018
2. Hydrogen environmentally assisted cracking during static loading of aa7075 and aa744910.1016/j.msea.2019.138662 ↗
3. Stress-corrosion cracking of high-strength aluminum alloys
4. Stress corrosion cracking of aluminum alloys10.1007/BF02672284 ↗
5. The effects of test temperature, temper, and alloyed copper on the hydrogen-controlled crack growth rate of an Al-Zn-Mg-(Cu) alloy10.1007/s11661-002-0218-y ↗
6. Improvements in strength and stress corrosion cracking properties in aluminum alloy 7075 via low-temperature retrogression and re-aging heat treatments10.5006/1.3277583 ↗
7. Some effects of alloy composition on stress corrosion cracking in Al-Zn-Mg-Cu alloys10.1016/j.corsci.2015.05.016 ↗
8. Environmentally assisted crack growth rates of high-strength aluminum alloys10.1007/s11837-003-0195-7 ↗
9. Cole · 1997
10. Environmental cracking performance of new generation thick plate 7000-t7x series alloys in humid air10.1016/j.corsci.2020.108701 ↗
11. International alloy designations and chemical composition limits for wrought aluminum and wrought aluminum alloys
12. E. ASTM · 2017
13. E. ASTM · 2012
14. Acidic vapors above saturated salt solutions commonly used for control of humidity10.1109/33.19024 ↗
15. Vapor pressure of aqueous hydrogen chloride solutions, 0° to 50° c10.1021/i460001a002 ↗
16. N. I. of Standards, T. (NIST) · 2015
17. Crack propagation during sustained-load cracking of Al-Zn-Mg-Cu aluminum alloys exposed to moist air or distilled water10.1007/s11661-011-0793-x ↗
18. Theoretical aspects of the kinetics of hydrogen embrittlement of metals10.1007/BF00754757 ↗
19. Ciaraldi · 1980 · 437
20. Hydrogen embrittlement understood10.1007/s11661-015-2836-1 ↗
21. Mechanistic and fractographic aspects of stress corrosion cracking10.1515/corrrev-2012-0501 ↗
22. A critical evaluation of the stress-corrosion cracking mechanism in high-strength aluminum alloys10.1007/BF02665007 ↗
23. Pérez · 2012
24. Electrochemical characteristics of intermetallic phases in aluminum alloys an experimental survey and discussion10.1149/1.1869984 ↗
25. J. Scully, G. Young Jr., S. Smith, Hydrogen solubility, diffusion and trapping in high purity aluminum and selected al-base alloys, in: Materials Science Forum, vol. 331, Trans Tech Publ., 1583–1600.10.4028/www.scientific.net/MSF.331-337.1583 ↗
26. Strain gradient plasticity-based modeling of hydrogen environment assisted cracking10.1016/j.actamat.2016.07.022 ↗
27. Combined microtomography, thermal desorption spectroscopy, X-ray diffraction study of hydrogen trapping behavior in 7XXX aluminum alloys10.1016/j.msea.2015.12.092 ↗
28. Wei · 2010
29. Development of high strength aa 7010 aluminum alloy resistant to environmentally assisted cracking10.1016/j.corsci.2016.03.025 ↗
30. Hydrogen embrittlement susceptibility and hydrogen-induced additive stress of 7050 aluminum alloy under various aging states10.1007/s11665-015-1616-9 ↗
31. Effect of Zn content on the microstructure and properties of super-high strength Al-Zn-Mg-Cu alloys10.1007/s11661-013-1731-x ↗
32. Hydrogen embrittlement susceptibility of over aged 7010 Al-alloy10.1007/s10853-006-0287-1 ↗
33. Microstructural effects on hydrogen embrittlement in a high purity 7075 aluminum alloy10.1016/0001-6160(87)90139-8 ↗
34. S. Lynch, S. Knight, N. Birbilis, B. Muddle, Stress-corrosion cracking of Al-Zn-Mg-Cu alloys effects of composition and heat-treatment, in: Effects of Hydrogen on Materials: Proceedings of the 2008 International Hydrogen Conference, September 7–10, 2008, Jackson Lake Lodge, Grand Teton National Park, Wyoming, USA, ASM International, 243.
35. The role of crack branching in stress corrosion cracking of aluminium alloys10.1515/corrrev-2015-0050 ↗