journal article·2021-06

The corrosion resistance mechanisms of the cr-coated SiC in molten Na2SO4 salt: Strengthened boundaries and protective scales

Xiaoguang Shi, Bingsheng Li, Haiyong Liu, Yirong Yao, Peng Li, Yongan Min, Feng Huang, Qing Huang, Fangfang Ge

Corrosion Science· Volume 185
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Abstract

Abstract The corrosion resistance of pressureless-sintered silicon carbide (SiC) plates in the molten Na2SO4 salt was greatly enhanced by their surfaces coated with magnetron-sputtered chromium (Cr) coatings. The Cr-coated SiC plates remained good structural integrity in the 1000 °C molten Na2SO4 salt for >20 h, in contrast to the uncoated ones that completely crushed into pieces after 4 h. The corrosion-resistance mechanisms mainly depend on the strengthened boundaries by formation of the Cr-C and Cr-Si compounds to avoid the preferred corrosion of boundaries, and the barrier effect of the Cr2O3/Cr/Cr-Si-C protective scale.
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Research context

OpenAlex topics: Advanced ceramic materials synthesis · Advanced materials and composites · Aluminum Alloys Composites Properties

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