journal article·2010-06Open access

Microstructure and analysis of oxide scales formed on Cr–Si–Ni compacts in air and H2O-containing atmosphere

Akira Yamauchi, Yoshio Suzuki, Norihito Sakaguchi, Seiichi Watanabe, Shigeji Taniguchi, Kazuya Kurokawa

Corrosion Science· Volume 52· Issue 6

Abstract

The purpose of this study was to characterize the oxide scales formed on various Cr-Si-Ni compacts at 1273 K in air and H2O-containing atmosphere by TEM. It was found that CrSi2-(5-20) mass%Ni compacts form double layer scales, consisting of an outer Cr2O3 layer and an inner SiO2 layer. The oxide scale changed from SiO2- to Cr2O3-based scale with an increase in the Ni concentration. However, it was observed that the oxide scale formed in H2O-containing atmospheres showed local SiO2 growth into the substrate. This result suggests that the inward oxidant diffusion promotes the local growth of SiO2 in the H2O-containing atmospheres.
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Research context

OpenAlex topics: Metallurgical Processes and Thermodynamics · High-Temperature Coating Behaviors · Metal Extraction and Bioleaching

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