journal article·2020-02Open access

Analysis of combined static load and low temperature hot corrosion induced cracking in CMSX-4 at 550°C

L. Brooking, S. Gray, K. Dawson, J.R. Nicholls, N.J. Simms, J. Sumner, G.J. Tatlock

Corrosion Science· Volume 163

Abstract

A CMSX-4 3-point bend specimen was statically loaded under hot corrosion conditions and SEM, (S)TEM and EDX techniques were used to analyse the cracking generated. Sulphur, chlorine, sodium and oxygen were found at the crack tip, and an influence of loading on the corrosion mechanism’s preference to interact with either the γ or γʹ was observed. The microscopy analysis is in support of the corrosive mechanism being a combined stress and electrochemical corrosion linked with low temperature hot corrosion, where crack propagation occurs as a result of localised corrosion enhanced material degradation. High magnification EDX mapping identified W as segregating to the γʹ at room temperature.
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Research context

OpenAlex topics: Hydrogen embrittlement and corrosion behaviors in metals · Corrosion Behavior and Inhibition · High Temperature Alloys and Creep

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