journal article·2019-03

Microstructural investigation using advanced TEM techniques of inner oxide layers formed on T92 steel in oxyfuel environment

K. Chandra, I. Dörfel, N. Wollschläger, A. Kranzmann

Corrosion Science· Volume 148
Publisher page

Abstract

Abstract T92 steel was oxidized at 650 °C for 1000 h in dry and wet oxyfuel gases. The microstructure of inner oxide layer was investigated using scanning transmission electron microscopy and energy dispersive spectroscopy on thin lamellas of oxide cross-sections. The oxides were composed of fine equiaxed grains and separated into Fe-rich and Cr-rich regions. Fe-rich regions were wustite and iron sulphide while Cr-rich regions consisted of Fe-Cr spinel with different stoichiometries. Precipitates of (W,Mo)-rich oxides were formed within the oxide scale and beneath the oxide/alloy interface. Often iron sulphide and (W,Mo)-rich oxide were surrounded by Cr-rich spinel.
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OpenAlex topics: High-Temperature Coating Behaviors · Metallurgical Processes and Thermodynamics · High Temperature Alloys and Creep

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