Kinetic study and structural evolution of SON68 nuclear waste glass altered from 35 to 125 °C under unsaturated H2O and D2O18 vapour conditions
Source abstract
Abstract
Abstract The French reference SON68 nuclear waste glass corrosion under H2O and D2O18 atmosphere was investigated at 35−125 °C and different relative humidities (92–99.9%). The hydration kinetic was followed by FTIR and solid characterization was achieved using SEM/EDX, Raman and TOF-SIMS. The water diffusion coefficients in the glass ranged from 8.7 × 10−22 to 5.3 × 10−19 m2 s−1. The alteration products were calcite, apatite, powellite and tobermorite. Pre-hydrated glass alteration in synthetic groundwater at 50 °C showed an instantaneous release of elements from the surface, making it important to evaluate well the vapour hydration period of the glass.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Glass properties and applications · Nuclear materials and radiation effects · Recycling and utilization of industrial and municipal waste in materials production
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (43)
Show source-provided references
1. The hydration alteration of a commercial nuclear waste glass10.1016/0009-2541(85)90088-9 ↗
2. Aqueous corrosion of natural nuclear waste glasses. I. Comparative rates of hydration in liquid and vapor environments at elevated temperatures10.1016/0022-3093(86)90783-0 ↗
3. Vapor hydration and subsequent leaching of transuranic-containing SRL and WV glasses
4. The french SON68 glass vapor hydration under different atmospheres10.1016/j.jnoncrysol.2012.07.020 ↗
5. A preliminary investigation of the ISG glass vapor hydration10.1111/ijag.12055 ↗
6. Vapor hydration of a simulated borosilicate nuclear waste glass in unsaturated conditions at 50 C and 90 C10.1039/C5RA12384D ↗
7. The experimental hydration of obsidian as a function of relative humidity and temperature10.2307/280898 ↗
8. Reasserting the utility of obsidian hydration dating: a temperature-dependent empirical approach to practical temporal resolution with archaeological obsidians10.1006/jasc.2000.0629 ↗
9. Obsidian diffusion dating by secondary ion mass spectrometry: a test using results from mound 65 chalco, Mexico10.1006/jasc.2001.0692 ↗
10. Mechanisms of rhyolitic glass hydration below the glass transition10.2138/am.2008.2516 ↗
11. Late Pleistocene/Early Holocene seafaring in the Aegean: new obsidian hydration dates with the SIMS-SS method10.1016/j.jas.2011.05.019 ↗
12. The sorption of water on obsidian and a nuclear waste glass
13. Thermodynamics of high temperature brines
14. Analytical electron microscopy study of surface layers formed on the French SON68 nuclear waste glass during vapor hydration at 200 C10.1016/S0022-3115(97)00349-8 ↗
15. The long-term corrosion and modelling of two simulated Belgian reference high-level waste glasses10.1557/PROC-112-631 ↗
16. Compositional effects on long-term dissolution of borosilicate glass10.1016/S0022-3093(00)00154-X ↗
17. Effect of composition on the short-term and long-term dissolution rates of ten borosilicate glasses of increasing complexity from 3 to 30 oxides10.1016/j.jnoncrysol.2012.05.024 ↗
18. The French SON68 glass vapor hydration under different Atmospheres10.1016/j.mspro.2014.10.024 ↗
19. SON68 glass alteration under Si-rich solutions at low temperature (35–90 _C): kinetics, secondary phases and isotopic exchange studies
20. Argile, tome, phenomenological evolution of a geological repository
21. Caractérisation géochimique des forages PAC et nouvelles modélisations
22. Water diffusion in the simulated French nuclear waste glass SON68 contacting silica rich solutions: experimental and modeling10.1016/j.jnucmat.2006.04.005 ↗
23. An infrared spectroscopic study of water-related species in silica glasses10.1016/0022-3093(95)00631-1 ↗
24. Neeway · 2011
25. Crank · 1956 · 12
26. Solid state diffusion during nuclear glass residual alteration in solution10.1016/j.jnucmat.2007.01.095 ↗
27. Impact of soda-lime borosilicate glass composition on water penetration and water structure at the first time of alteration10.1016/j.jnoncrysol.2012.07.014 ↗
28. Surface layers on a borosilicate nuclear waste glass corroded in MgCl2 solution10.1016/S0022-3115(96)00672-1 ↗
29. Trivalent actinide coprecipitation with powellite (CaMoO4): secondary solid solution formation during HLW borosilicate-glass dissolution10.1524/ract.92.9.639.54976 ↗
30. Structure and chemistry of the apatites and other calcium orthophosphates
31. Uptake of Eu(III) by 11 Å tobermorite and xonotlite: a TRLFS and EXAFS study10.1016/j.gca.2010.10.028 ↗
32. The H2O–D2O solvent isotope effects on the molar volumes of alkali-chloride solutions at T = (288. 15, 298. 15, and 308. 15) K10.1016/j.jct.2007.05.002 ↗
33. Distribution of isotopic water molecules, H2O HDO and D2O, in vapour and liquid phases in pure xater and aqueous solutions systems10.1016/S0016-7037(99)00281-1 ↗
34. FTIR studies of H2O and D2O decomposition on porous silicon surfaces10.1016/0039-6028(91)90038-T ↗
35. Low-temperature isotopic exchange in obsidian: implications for diffusive mechanisms10.1016/j.gca.2009.02.035 ↗
36. Icenhower · 2009
37. The structure of Na2O–Al2O3–SiO2 glass: impact on sodium ion exchange in H2O and D2O10.1016/S0022-3093(01)00890-0 ↗
38. Mechanisms of rhyolitic glass hydration below the glass transition10.2138/am.2008.2516 ↗
39. Mineralogy and sedimentology of the Miocene Göcenoluk borate deposit Kırka district, western Anatolia, Turkey10.1016/j.sedgeo.2013.03.006 ↗
40. Hydration aging of nuclear waste glass10.1126/science.218.4567.51 ↗
41. Study of the interaction of Ni2+ and Cs+ on MX-80 bentonite; effect of compaction using the capillary method10.1021/es052483i ↗
42. Microbial mobilization of cesium from illite: the role of organic acids and siderophores10.1016/j.chemgeo.2016.02.024 ↗
43. Z. Zhiyi, X. Gaozhi, P. Guang, Z. Pinqing and Z. Ming, Application of deuterium oxide in producing silicon containing and metal containing materials, In (patent application), Pub. N 0.2 US 2001/0047665 A1. Dec. 6, 2001.