journal article·2015-09Open access

Modelling of the kinetics of pitting corrosion by metal dusting

Aurélien Fabas, Daniel Monceau, Sébastien Doublet, Aurélie Rouaix-Vande Put

Corrosion Science· Volume 98
Publisher page

Abstract

Commercial 800HT alloy was exposed to 49.1%H2–12.8%CO–3.1%CO2–1.6CH4–33.4%H2O gas at 21bars and 570°C up to 5000h. Metal dusting attack by pitting was observed. The kinetics parameters were identified to be the incubation time, pit density and individual pit growth rate. These parameters were introduced in a nucleation-growth model to simulate the pitted surface area kinetics. This model was then extended to the volume considering several geometrical hypotheses. Considering only surface coalescence of the pits without their volume coalescence allowed to correctly reproduce the experimental mass loss kinetics. An even simpler conservative model was proposed for an easy lifetime modelling.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Corrosion Behavior and Inhibition · Hydrogen embrittlement and corrosion behaviors in metals · Concrete Corrosion and Durability

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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