Efficiency and durability of protective treatments on cultural heritage copper corrosion layers
Source abstract
Abstract
Abstract To protect copper artefacts of the cultural heritage from atmospheric degradation protective treatment must be applied. Two types of protective treatments: microcrystalline wax (Cosmolloid wax) and decanoate solution (HC10) were tested. Two aspects were considered: the penetration of the treatments in the corrosion layers, and its durability. Equivalent efficiencies for both treatments were demonstrated. The penetration of the treatments seems to depend essentially on its application mode. Re-corrosion experiments of treated samples under immersion in D2O demonstrate that the efficiency and the durability with time or after water leaching depend on the penetration of the treatments in the corrosion layers.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Corrosion Behavior and Inhibition · Building materials and conservation · Cultural Heritage Materials Analysis
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (60)
Show source-provided references
1. New model of outdoor bronze corrosion and its implications for conservation
2. Environmental effects on metallic materials–results of an outdoor exposure programme running in Switzerland10.1002/maco.19960470803 ↗
3. Environmental effects on materials: the effect of the air pollutants SO2, NO2, NO and O3 on the corrosion of copper, zinc and aluminium. A short literature survey and results of laboratory exposures10.1016/S0010-938X(97)00047-4 ↗
4. Brostoff · 2003
5. Restoration and conservation of outdoor bronze monuments: diagnosis and non-destructive investigation
6. The metal patina and surface layer of El caballito: calling things by their name
7. Atmospheric corrosion of copper and the colour, structure and composition of natural patinas on copper10.1016/j.corsci.2005.09.011 ↗
8. Morphological study of 16-year patinas formed on copper in a wide range of atmospheric exposures10.1016/j.corsci.2007.05.030 ↗
9. The evolution of outdoor copper patina10.1016/S0010-938X(01)00081-6 ↗
10. Determination of instantaneous corrosion rates and runoff rates of copper from naturally patinated copper during continuous rain events10.1016/S0010-938X(02)00015-X ↗
11. The reaction of simulated rain with copper, copper patina, and some copper compounds10.1016/0010-938X(87)90052-7 ↗
12. Influence of the environment on the atmospheric corrosion of bronze10.1023/B:JACH.0000042667.84920.e2 ↗
13. Multianalytical in situ investigation of the initial atmospheric corrosion of bronze10.1016/S0010-938X(01)00083-X ↗
14. The characterization of Sn‐based corrosion products in ancient bronzes: a Raman approach10.1002/jrs.4037 ↗
15. The atmospheric corrosion of quaternary bronzes: an evaluation of the dissolution rate of the alloying elements10.1007/s00339-008-4451-0 ↗
16. Atmospheric corrosion of fire-gilded bronze: corrosion and corrosion protection during accelerated ageing tests10.1016/j.corsci.2015.08.013 ↗
17. New insight into the nature and properties of pale green surfaces of outdoor bronze monuments10.1007/s00339-008-4468-4 ↗
18. Characterization of typical patinas simulating bronze corrosion in outdoor conditions10.1016/j.matchemphys.2017.07.091 ↗
19. Copper patinas formed in the atmosphere-II. A qualitative assessment of mechanisms10.1016/0010-938X(87)90053-9 ↗
20. Atmospheric corrosion and conservation of copper and bronze10.2495/978-1-84564-032-3/04 ↗
21. Atmospheric corrosion of copper and silver10.1149/1.2127403 ↗
22. Metallographic studies of the copper patina formed in the atmosphere10.1016/0010-938X(87)90048-5 ↗
23. Characterisation of a centuries-old patinated copper roof tile from Queen Anne’s Summer Palace in Prague10.1016/j.matchar.2017.09.034 ↗
24. 26 - corrosion inhibitors for the preservation of metallic heritage artefacts
25. Investigation of the corrosion protection of chemically and electrochemically formed patinas on recent bronze10.1016/j.electacta.2010.09.093 ↗
26. Innovative treatments for the protection of outdoor bronze monuments
27. Laboratory and field tests on patinas and protective coating systems for outdoor bronze monuments
28. The use of electrochemical impedance spectroscopy in the evaluation of coatings for outdoor bronze
29. Characterisation of bronze corrosion and protection by contact-probe electrochemical impedance measurements
30. An electrochemical study of waxes for bronze sculpture
31. Electrochemical evaluation of the anti-corrosion performance of waxy coatings for outdoor bronze conservation
32. Electrochemical impedance studies of the corrosion resistance of wax coatings on artificially patinated bronze
33. Effects of wax-based anti-graffiti on copper patina composition and dissolution during four years of outdoor urban exposure10.1016/j.culher.2010.02.001 ↗
34. Les cires microcristallines dans la protection de la stauaire en cuivre et alliages de cuivre exposée en extérieur
35. A preliminary note on the use of benzotriazole for stabilizing bronze objects
36. Benzotriazoles: toxicity and degradation
37. Toxicity of Benzotriole and benzotriazole derivatives to three aquatic species10.1016/S0043-1354(00)00268-2 ↗
38. Comparison of a bio-based corrosion inhibitor versus benzotriazole on corroded copper surfaces10.1016/j.corsci.2018.08.020 ↗
39. Evaluation of new non-toxic corrosion inhibitors for conservation of iron artefacts10.1179/147842210X12732285051311 ↗
40. Development of new non-toxic corrosion inhibitors for cultural property made of iron and copper alloys
41. The application of non-toxic corrosion inhibitors for the temporary protection of iron and copper alloy in uncontrolled environments
42. Inhibition of copper aqueous corrosion by non-toxic linear sodium heptanoate: mechanism and ECAFM study
43. The methodology for the PROMET project to develop/test new non-toxic corrosion inhibitors and coatings for iron and copper alloy objects housed in Mediterranean museums
44. Hollner · 2009
45. Rocca · 2012 · 120
46. Etude de l’inhibition de la corrosion aqueuse du cuivre par les carboxylates linéaires saturés. I. Pouvoir inhibiteur des carboxylates linéaires de formule CH3 (CH2) n-2COONa10.1051/metal/199693020281 ↗
47. Etude de l’inhibition de la corrosion aqueuse du cuivre par les carboxylates linéaires saturés.-II. Caractérisation des films superficiels formés par réaction entre le cuivre et l’anion heptanoate10.1051/metal/199693050719 ↗
48. The formation of hydrophobic and corrosion resistant surfaces on copper and bronze by treatment in myristic acid10.1007/s10800-010-0078-x ↗
49. Syvilay · 2011
50. Correlation of diffusion coefficients in dilute solutions10.1002/aic.690010222 ↗
51. The evolution of out copper patina10.1016/S0010-938X(01)00081-6 ↗
52. The characterization of metal soaps
53. Microsonde nucléaire: principe et appareillage, Tech. l’ingénieur
54. The Pierre Süe Laboratory nuclear microprobe as a multi-disciplinary analysis tool10.1016/S0168-583X(01)00564-X ↗
55. Mayer · 1997
56. Socrates · 2004
57. A study of copper runoff in an urban atmosphere10.1016/S0010-938X(97)00081-4 ↗
58. Analysis of Historic Copper Patinas. Influence of Inclusions on Patina Uniformity10.3390/ma10030298 ↗
59. A laboratory study of copper and zinc runoff during first flush and steady-state conditions10.1016/S0010-938X(00)00066-4 ↗
60. Precise deposition of molten microdrops: the physics of digital microfabrication10.1098/rspa.1994.0037 ↗