journal article·2014-12Open access

Multi-element-resolved electrochemical corrosion analysis. Part I. Dissolution behavior and passivity of amorphous Fe50Cr15Mo14C15B6

J. Klemm, S.O. Klemm, M.J. Duarte, L. Rossrucker, K.J.J. Mayrhofer, F.U. Renner

Corrosion Science· Volume 89

Abstract

Multi-element dissolution analysis of amorphous Fe 50 Cr 15 Mo 14 C 15 B 6 in 0.1 M H 2 SO 4 was investigated electrochemically and by coupled online mass spectrometry. We fully discuss the most important aspects of the application of the newly-developed methodology to study complex multi-elemental alloys. The resulting partial dissolution rates of Fe, Cr and Mo reflect the passive behavior and are compared to the measured total current density as function of time. The deviations between the added elemental dissolution currents and the measured total current density are discussed. Furthermore, the inferred growth of oxide thickness was correlated to results obtained from surface analysis.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Electrocatalysts for Energy Conversion · Electrodeposition and Electroless Coatings · Nanoporous metals and alloys

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (37)

Show source-provided references
1. Award lecture: in pursuit of new corrosion-resistant alloys10.5006/1.3277653 ↗
2. The passivity of iron–chromium alloys10.1016/0010-938X(89)90060-7 ↗
3. The corrosion behavior of amorphous Fe–Cr–Mo–P–C and Fe–Cr–W–P–C alloys10.1016/0010-938X(92)90147-U ↗
4. Pitting corrosion behaviour of austenitic stainless steels – combining effects of Mn and Mo additions10.1016/j.corsci.2008.04.005 ↗
5. Coupling of a high throughput microelectrochemical cell with online multielemental trace analysis by ICP-MS10.1016/j.elecom.2011.10.017 ↗
6. Dissolution of platinum: limits for the deployment of electrochemical energy conversion?10.1002/anie.201207256 ↗
7. The influence of halide additives on the initial anodic dissolution of Cu3Au (111)10.1016/j.electacta.2012.08.059 ↗
8. The application of ICP-MS and XPS to studies of ion selectivity during passivation of stainless-steels10.1149/1.2086860 ↗
9. Spatially and time-resolved element-specific in situ corrosion investigations with an online hyphenated microcapillary flow injection inductively coupled plasma mass spectrometry set-up10.1016/j.sab.2008.04.015 ↗
10. A microelectrochemical scanning flow cell with downstream analytics10.1016/j.electacta.2011.01.052 ↗
11. Atomic emission spectroelectrochemistry applied to dealloying phenomena II. Selective dissolution of iron and chromium during active–passive cycles of an austenitic stainless steel10.1016/j.electacta.2009.08.028 ↗
12. Effect of surface roughness and electrostatic surface potentials on forces between dissimilar surfaces in aqueous solution10.1002/adma.201003709 ↗
13. Pressure solution – the importance of the electrochemical surface potentials10.1016/j.gca.2011.09.019 ↗
14. Nitric-oxide adsorption and oxidation on Pt(111) in electrolyte solution under potential control10.1016/S0039-6028(02)01337-7 ↗
15. Pt-based core–shell catalyst architectures for oxygen fuel cell electrodes10.1021/jz4014135 ↗
16. Stabilization of metallic supercooled liquid and bulk amorphous alloys10.1016/S1359-6454(99)00300-6 ↗
17. The electrochemical properties of metallic glasses10.1016/0013-4686(87)87002-0 ↗
18. Iron-based bulk metallic glasses10.1179/1743280412Y.0000000007 ↗
19. Bulk glassy Fe–Cr–Mo–C–B alloys with high corrosion resistance10.1016/S0010-938X(02)00002-1 ↗
20. Element-resolved corrosion analysis of stainless-type glass-forming steels10.1126/science.1230081 ↗
21. A round robin on combined electrochemical and AES/ESCA characterization of the passive films on Fe–Cr and Fe–Cr–Mo alloys10.1016/0010-938X(88)90026-1 ↗
22. Influence of yttrium as a minority alloying element on the corrosion behavior in Fe-based bulk metallic glasses10.1016/j.electacta.2008.08.017 ↗
23. Comparison of the sputter rates of oxide films relative to the sputter rate of SiO10.1116/1.3456123 ↗
24. Longitudinal diffusion and resistance to mass transfer as causes of nonideality in chromatography10.1016/0009-2509(56)80003-1 ↗
25. A combined surface analytical and electrochemical study of the formation of passive layers on FeCr alloys in 0.5M H2SO410.1016/0010-938X(94)00104-E ↗
26. Surface composition of stainless steels during anodic dissolution and passivation studied by ESCA10.1149/1.2113683 ↗
27. Passive films on stainless steels - chemistry, structure and growth10.1016/S0013-4686(02)00841-1 ↗
28. Compositional changes of passive films due to different transport rates and preferential dissolution10.1016/0010-938X(90)90164-Z ↗
29. An X-ray photoelectron spectroscopy study of the passivity of amorphous Fe–Mo alloys10.1016/0010-938X(79)90014-3 ↗
30. Sputtering by Particle Bombardment, in: R. Behrisch, W. Eckstein (Eds.), Topics in Applied physics 110, Springer Verlag, Berlin Heidelberg, 2007.
31. Corrosion of the glassy metals Fe80B20 and Fe40Ni40B20
32. An X-ray photoelectron spectroscopy study of the chemical changes in oxide and hydroxide surfaces induced by Ar+ ion bombardment10.1016/0040-6090(78)90365-6 ↗
33. X-ray photoelectron spectroscopy of the effects of Ar ion sputtering on the nature of some standard compounds of Zn, Cr, and Fe10.1016/j.corsci.2014.01.018 ↗
34. Influence of sputter damage on the XPS analysis of metastable nanocomposite coatings10.1016/j.surfcoat.2009.08.006 ↗
35. Decomposition of metal oxide films under electron beam bombardment10.1016/0010-938X(77)90101-9 ↗
36. Resolving surface chemical states in XPS analysis of first row transition metals, oxides and hydroxides: Cr, Mn, Fe, Co and Ni10.1016/j.apsusc.2010.10.051 ↗
37. The role of chromium and molybdenum in passivation of amorphous Fe–Cr–Mo–P–C alloys in deaerated 1M HCl10.1016/S0010-938X(96)00071-6 ↗