journal article·2014-10

Semiconducting properties of thermal scales grown on a chromia-forming alloy under controlled oxygen partial pressures

Y. Madi, L. Latu-Romain, S. Mathieu, V. Parry, J.-P. Petit, M. Vilasi, Y. Wouters

Corrosion Science· Volume 87
Publisher page

Abstract

Abstract The present work is focused on the oxidation at 1050 °C of a model chromia-forming alloy, paying special attention to the control of the oxygen partial pressure. Taking benefit of a recently developed approach to describe and fit photocurrent energy spectra, photoelectrochemical characterizations allowed to reveal the presence, in the scale formed at low P (O 2 ) (10 −15 atm), of an unexpected high number of oxide phases. This result underlines the complexity of the scale in term of chemical composition as well as of the semiconducting types of the individual phases.
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Research context

OpenAlex topics: ZnO doping and properties · High-Temperature Coating Behaviors · Nuclear Materials and Properties

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