journal article·2019-10

Investigating the transport mechanisms governing the oxidation of Hastelloy BC-1 by in situ ToF-SIMS

Jeffrey D. Henderson, Antoine Seyeux, Sandrine Zanna, Mark C. Biesinger, David W. Shoesmith, James J. Noël, Philippe Marcus

Corrosion Science· Volume 159
Publisher page

Abstract

Abstract This paper presents insight into the structure and transport mechanisms involved in the surface oxidation of Hastelloy BC-1, gained by means of in situ time-of-flight secondary ion mass spectrometry and X-ray photoelectron spectroscopy. The native, air-formed oxide, comprising Cr-rich (inner) and Mo-rich (outer) layers, was found to be on the order of 1–2 nm thick. Oxide thickness did not change when the temperature was increased to 300 °C in oxygen atmosphere but increased to ˜10 nm after exposure at 500 °C. The mechanisms of oxide growth/maintenance as well as observations on the effect of elevated temperatures on oxide structure are discussed.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Semiconductor materials and devices · Electronic and Structural Properties of Oxides · Ion-surface interactions and analysis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (45)

Show source-provided references
1. Materials selection for use in concentrated hydrochloric acid10.5006/2193 ↗
2. The role of corrosion-resistant alloying elements in passivity10.1016/j.corsci.2006.05.003 ↗
3. Current developments of nanoscale insight into corrosion protection by passive oxide film10.1016/j.cossms.2018.05.004 ↗
4. Progress in corrosion science at atomic and nanometric scales10.1016/j.pmatsci.2018.03.001 ↗
5. Marcus · 2011
6. Characterization of the corrosion products of crevice corroded alloy 2210.1149/1.3160365 ↗
7. The role of internal cathodic support during the crevice corrosion of Ni-Cr-Mo alloys10.1016/j.electacta.2018.07.048 ↗
8. Influence of temperature on passive film properties on Ni–Cr–Mo Alloy C-200010.1016/j.corsci.2013.07.016 ↗
9. Characterization of film properties on the Ni Cr Mo alloy C-200010.1016/j.electacta.2012.11.029 ↗
10. Passive films on stainless steels - chemistry, structure and growth10.1016/S0013-4686(02)00841-1 ↗
11. A combined experimental and first-principle study on the oxidation mechanism of super austenitic stainless steel S32654 at 900 °C
12. A new insight into high-temperature oxidation mechanism of super-austenitic stainless steel S32654 in air10.1016/j.jallcom.2016.06.023 ↗
13. Effects of molybdenum on the composition and nanoscale morphology of passivated austenitic stainless steel surfaces10.1039/C4FD00231H ↗
14. Gas phase initial oxidation of Incoloy 800 surfaces10.1007/s11085-012-9316-4 ↗
15. ToF-SIMS study of oxide films thermally grown on nickel-base alloys10.1016/j.corsci.2018.06.043 ↗
16. Characterization of oxide structures formed on nickel-chromium alloy during low pressure oxidation at 500–600 °C10.1007/BF00666809 ↗
17. The effect of oxide volatilization on the oxidation kinetics of Cr and Fe-Cr alloys10.1149/1.2424115 ↗
18. 2011
19. Volatilization and transport mechanisms during Cr oxidation at 300 °C studied in situ by ToF-SIMS10.1007/s11085-017-9756-y ↗
20. In situ observations of early stage oxidation of Ni-Cr and Ni-Cr-Mo alloys10.5006/2807 ↗
21. Comparative study of the surface oxide films on lean duplex and corresponding single phase stainless steels by XPS and ToF-SIMS10.1016/j.corsci.2018.08.009 ↗
22. Peng · 2014
23. Calculations of electron inelastic mean free path. II. Data for 27 elements over the 50–2000 eV range10.1002/sia.740171304 ↗
24. ToF-SIMS study of the behavior of thermally oxidized films formed on nickel-based 690 alloy in high-temperature water10.1002/sia.5060 ↗
25. Effect of oxide film properties on the kinetics of O2 reduction on alloy C-2210.1149/2.1831713jes ↗
26. A bipolar model of the passivity of stainless steel: the role of Mo addition10.1149/1.2108451 ↗
27. Oxidation behaviour of Incoloy 800HT in pure oxygen
28. Potentiostatic oxide growth kinetics on Ni-Cr and Co-Cr alloys: potential and pH dependences10.1016/j.electacta.2015.02.176 ↗
29. Combined effect of gamma-radiation and pH on corrosion of Ni-Cr-Fe alloy Inconel 60010.1016/j.corsci.2016.03.015 ↗
30. X-ray photoelectron spectroscopic chemical state quantification of mixed nickel metal, oxide and hydroxide systems10.1002/sia.3026 ↗
31. Resolving surface chemical states in XPS analysis of first row transition metals, oxides and hydroxides: Cr, Mn, Fe, Co and Ni10.1016/j.apsusc.2010.10.051 ↗
32. X-ray photoelectron spectroscopy studies of chromium compounds10.1002/sia.1983 ↗
33. Thermal reduction of MoO310.1021/j100201a062 ↗
34. XPS study of passive films formed on molybdenum‐implanted austenitic stainless steels10.1002/sia.740190175 ↗
35. Round Robin on combined electrochemical and AES/ESCA characterization of the passive films on Fe- Cr and Fe-Cr-Mo alloys10.1002/sia.740111106 ↗
36. Characterization of slightly hydrated Ni(OH)2 by XPS10.1116/1.1247753 ↗
37. Characterization of α‐Ni(OH)2 by XPS10.1116/1.1247754 ↗
38. XANES, X-ray photo-electron and optical spectra of divalent nickel at the crystallographic transition in NiCr2O4 and the Ni1-xCuxCr2O4 system: correlation with the Jahn-Teller effect10.1088/0022-3719/19/17/003 ↗
39. Oxidative dehydrogenation of propane on NixMg1− xAl2O4 and NiCr2O4 spinels10.1006/jcat.1999.2626 ↗
40. The anodic dissolution and passivation of Ni-Cr-Fe alloys studied by ESCA10.1016/0010-938X(92)90113-H ↗
41. Understanding multi-element alloy passivation in acidic solutions using operando methods10.1016/j.elecom.2017.05.015 ↗
42. X-ray photoelectron spectroscopy and scanning tunneling microscopy study of passive films formed on (100) Fe—18Cr—13Ni single-crystal surfaces10.1149/1.1838366 ↗
43. Oxidation of Molybdenum 550° to 1700 °C10.1149/1.2425918 ↗
44. Theory of the oxidation of metals10.1088/0034-4885/12/1/308 ↗
45. Low-temperature oxidation10.1007/BF00603582 ↗