journal article·2020-05Open access

Characterization of zirconium oxides part II: New insights on the growth of zirconia revealed through complementary high-resolution mapping techniques

Corey M. Efaw, Jordan L. Vandegrift, Michael Reynolds, Brian J. Jaques, Hongqiang Hu, Hui Xiong, Michael F. Hurley

Corrosion Science· Volume 167

Abstract

Abstract Raman mapping, scanning Kelvin probe force microscopy (SKPFM), and scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM/EDS) were combined to investigate oxidized zirconium alloys. Raman provided spatially resolved phase composition and relative stress state. When coupled with SKPFM, phase composition was correlated to Volta potentials differences. The potential of tetragonal zirconia was lower than the metal zirconium, making the tetragonal phase favorable for reaction with diffusing species, thus hindering further oxidation of the relatively cathodic metal. This provides new insight to the theory of the tetragonal phase being an oxidation barrier.
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Research context

OpenAlex topics: Nuclear Materials and Properties · Radioactive element chemistry and processing · Hydrogen embrittlement and corrosion behaviors in metals

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