journal article·2018-05Open access

Conversion of steel by polyphenolic model molecules: Corrosion inhibition mechanism by rutin, esculin, esculetol

Delphine Veys-Renaux, Solenn Reguer, Ludovic Bellot-Gurlet, François Mirambet, Emmanuel Rocca

Corrosion Science· Volume 136

Abstract

This paper focuses on the potential corrosion protection of steel in presence of three polyphenolic model molecules (rutin, esculin, esculetol) in a weak acidic medium (pH = 4). From an electrochemical point of view, the cathodic inhibition was attributed to the oxygen scavenger role of the considered antioxidant compounds. SEM observations, Raman spectroscopy and Synchrotron X-ray absorption spectroscopy revealed furthermore the formation of a surface film by precipitation of iron polyphenolate conversion products, in which iron III is likely coordinated with free-catechol groups. Glycosylated catechol groups are rather adsorbed on a FeOOH layer.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Corrosion Behavior and Inhibition · Concrete Corrosion and Durability · Hydrogen embrittlement and corrosion behaviors in metals

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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