Corrosion behavior of glassy Ni55Co5Nb20Ti10Zr10 alloy in 1N HCl solution studied by potentiostatic polarization and XPS

Corrosion resistance of glassy Ni55Co5Nb20Ti10Zr10 (at.%) alloy in 1 N HCl solution was investigated with respect to the electrochemical behavior and the compositions of the passive film and the underlying alloy surface just below the passive film. The potentiostatic polarization curve indicated that the alloy was spontaneously passivated with a low passive current density of the order of 10−3 A m−2. The quantitative X-ray photo-electron spectroscopy (XPS) analysis revealed that the thickness of the surface film increased linearly with an anodizing ratio of 1.5 nm V−1. The high corrosion resistance of the glassy alloy was due to the formation of niobium, titanium and zirconium-enriched passive film. The growth mechanism of the passive films is also discussed.