journal article·2014-08

Microstructure and ablation resistance of carbon/carbon composites with a zirconium carbide rich surface layer

Cuiyan Li, Kezhi Li, Hejun Li, Yulei Zhang, Haibo Ouyang, Dongjia Yao, Lei Liu

Corrosion Science· Volume 85
Publisher page

Abstract

Abstract Zirconium carbide (ZrC) rich surface layer with a thickness of 80–100 μm was prepared on carbon/carbon (C/C) composites. The ZrC-rich layer consisted of submicron ZrC particles, homogeneously dispersed in the carbon matrix. The mass ablation rate of the composite with the ZrC-rich layer was 69% lower than that of the bare C/C composites. The ZrC-rich layer could seal the surface pores and cracks to restrain the preferential ablation in the defect area and form a continuously melting ZrO 2 layer to prevent the carbon from oxidizing during ablation. The strengthened ZrC-rich layer could reduce the mechanical denudation of the composites.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Advanced ceramic materials synthesis · Metal and Thin Film Mechanics · Diamond and Carbon-based Materials Research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (22)

Show source-provided references
1. Savage · 1993 · 331
2. Buckley · 1993 · 267
3. J.J. Choury, Carbon–carbon materials for nozzles of solid propellant rocket motors, in: 12th Propulsion Conference, Palo Alto, CA, AIAA-76-609, 1976.10.2514/6.1976-609 ↗
4. Resistance to ablation of pitch derived ZrC/C composites10.1016/j.carbon.2004.05.006 ↗
5. Ablation resistance and thermal conductivity of carbon/carbon composites containing hafnium carbide10.1016/j.corsci.2012.10.018 ↗
6. Effect of reaction melt infiltration temperature on the ablation properties of 2D C/C–SiC–ZrC composites10.1016/j.corsci.2012.01.001 ↗
7. Effect of HfC on the ablative and mechanical properties of C/C composites10.1016/j.msea.2009.03.040 ↗
8. Mechanism of ablation of 3D C/ZrC–SiC composite under an oxyacetylene flame10.1016/j.corsci.2012.11.009 ↗
9. Ablation in different heat fluxes of C/C composites modified by ZrB2–ZrC and ZrB2–ZrC–SiC particles10.1016/j.corsci.2013.04.038 ↗
10. Ablation behaviors of carbon/carbon composites with C–SiC–TaC multi-interlayers10.1016/j.apsusc.2009.07.006 ↗
11. The effect of zirconium carbide on ablation of carbon/carbon composites under an oxyacetylene flame10.1016/j.corsci.2010.09.028 ↗
12. Microstructure and ablation properties of zirconium carbide doped carbon/carbon composites10.1016/j.carbon.2009.09.035 ↗
13. Microstructure and ablation performances of dual-matrix carbon/carbon composites10.1016/j.carbon.2006.01.017 ↗
14. Processing, microstructure and ablation behavior of C/SiC–Ti3SiC2 composites fabricated by liquid silicon infiltration10.1016/j.corsci.2013.04.029 ↗
15. Preparation of ceria–zirconia (Ce0.75Zr0.25O2) powders by microwave–hydrothermal (MH) route10.1016/S0254-0584(01)00485-0 ↗
16. Facile controlled synthesis and growth mechanisms of flower-like and tubular MnO2 nanostructures by microwave-assisted hydrothermal method10.1016/j.jcis.2011.12.013 ↗
17. Influence of hydrothermal treatment temperature on oxidation modification of C/C composites with aluminum phosphates solution by a microwave hydrothermal process10.1016/j.corsci.2010.07.026 ↗
18. Effect of reaction melt infiltration temperature on the ablation properties of 2D C/C–SiC–ZrC composites10.1016/j.corsci.2012.01.001 ↗
19. Anti-oxidation and ablation properties of carbon/carbon composites infiltrated by hafnium boride10.1016/j.carbon.2012.09.053 ↗
20. Ablation behaviors of ultra-high temperature ceramic composites10.1016/j.msea.2007.02.040 ↗
21. C/C–ZrC composite prepared by chemical vapor infiltration10.1016/j.ceramint.2012.04.017 ↗
22. C/C–SiC–ZrC composites fabricated by reactive melt infiltration with Si0.87Zr0.13 alloy10.1016/j.ceramint.2012.02.016 ↗