Zirconium ions integrated in 1-hydroxyethylidene-1,1-diphosphonic acid (HEDP) as a metalorganic-like complex coating on biodegradable magnesium for corrosion control
Source abstract
Abstract
Abstract In this study, a coating of ionic Zr integrated in 1-hydroxyethylidene-1,1-diphosphonic acid (HEDP) metalorganic-like complexes was applied on Mg for corrosion control. HEDP was first immobilized on alkaline pretreated Mg followed by an alternating dip-coating process of Zr ions and HEDP to build a complex coating on Mg. This coating was demonstrated to be homogeneous, compact and with a metalorganic-like framework firmly anchored on Mg. This coating led to reduced corrosion current densities and remarkably suppressed long-term in vitro degradation of Mg in phosphate buffer saline (PBS). This complex coating showed promise for surface modification of Mg in biodegradable applications.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Magnesium Alloys: Properties and Applications · Corrosion Behavior and Inhibition · Layered Double Hydroxides Synthesis and Applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (46)
Show source-provided references
1. Current status on clinical applications of magnesium-based orthopaedic implants: a review from clinical translational perspective10.1016/j.biomaterials.2016.10.017 ↗
2. Reprint of: the history of biodegradable magnesium implants: a review10.1016/j.actbio.2015.07.017 ↗
3. The in vivo degradation and bone-implant interface of Mg-Nd-Zn-Zr alloy screws: 18 months post-operation results10.1016/j.corsci.2016.10.009 ↗
4. Biodegradable metals10.1016/j.mser.2014.01.001 ↗
5. Implant-derived magnesium induces local neuronal production of CGRP to improve bone-fracture healing in rats10.1038/nm.4162 ↗
6. In vivo study of magnesium plate and screw degradation and bone fracture healing10.1016/j.actbio.2015.02.010 ↗
7. Invitro and invivo studies on the degradation of high-purity Mg (99.99wt.%) screw with femoral intracondylar fractured rabbit model10.1016/j.biomaterials.2015.06.031 ↗
8. Magnesium alloy based interference screw developed for ACL reconstruction attenuates peri-tunnel bone loss in rabbits10.1016/j.biomaterials.2017.12.007 ↗
9. Poly (3,4-ethylenedioxythiophene) graphene oxide composite coatings for controlling magnesium implant corrosion10.1016/j.actbio.2016.11.039 ↗
10. Protective properties of inhibitor-containing composite coatings on a Mg alloy10.1016/j.corsci.2015.10.026 ↗
11. Control of biodegradation of biocompatable magnesium alloys10.1016/j.corsci.2007.01.001 ↗
12. Strategies to improve the corrosion resistance of microarc oxidation (MAO) coated magnesium alloys for degradable implants: prospects and challenges10.1016/j.pmatsci.2013.08.002 ↗
13. Sandwiched polydopamine (PDA) layer for titanium dioxide (TiO2) coating on magnesium to enhance corrosion protection10.1016/j.corsci.2015.03.020 ↗
14. Biodegradable magnesium alloys for orthopaedic applications: a review on corrosion, biocompatibility and surface modifications10.1016/j.msec.2016.06.020 ↗
15. Surface modification on biodegradable magnesium alloys as orthopedic implant materials to improve the bio-adaptability: a review10.1016/j.jmst.2016.05.003 ↗
16. Surface design of biodegradable magnesium alloys - a review10.1016/j.surfcoat.2012.10.009 ↗
17. Facile preparation of poly(lactic acid)/brushite bilayer coating on biodegradable magnesium alloys with multiple functionalities for orthopedic application10.1021/acsami.7b00209 ↗
18. Corrosion resistance of a self-healing micro-arc oxidation/polymethyltrimethoxysilane composite coating on magnesium alloy AZ3110.1016/j.corsci.2017.01.025 ↗
19. Corrosion resistance of dicalcium phosphate dihydrate/poly(lactic-co-glycolic acid) hybrid coating on AZ31 magnesium alloy10.1016/j.corsci.2015.10.010 ↗
20. A versatile dopamine-induced intermediate layer for polyether imides (PEI) deposition on magnesium to render robust and high inhibition performance10.1016/j.corsci.2017.03.021 ↗
21. In situ incorporation of heparin/bivalirudin into a phytic acid coating on biodegradable magnesium with improved anticorrosion and biocompatible properties10.1039/C6TB03157A ↗
22. Surface modification using phosphonic acids and esters10.1021/cr2004212 ↗
23. Controlling corrosion rate and behavior of biodegradable magnesium by surface-immobilized ultrathin 1-Hydroxyethylidene-1,1-diphosphonic acid (HEDP) film10.1039/C5RA23228G ↗
24. An Fe(II) metal-organic framework as visible responsive photo-fenton catalyst for the degradation of organophosphates10.1039/C7NJ03815A ↗
25. Corrosion-controlling and osteo-compatible Mg ion-integrated phytic acid (Mg-PA) coating on magnesium substrate for biodegradable implants application10.1021/am506741d ↗
26. Biosorption of heavy metal ions onto agricultural residues buckwheat hulls functionalized with 1-hydroxylethylidenediphosphonic acid10.1021/jf303565d ↗
27. Effects of zirconium and oxygen plasma ion implantation on the corrosion behavior of ZK60 Mg alloy in simulated body fluids10.1016/j.corsci.2013.11.044 ↗
28. Controlling initial biodegradation of magnesium by a biocompatible strontium phosphate conversion coating10.1016/j.actbio.2013.11.016 ↗
29. Epigallocatechin gallate (EGCG) induced chemical conversion coatings for corrosion protection of biomedical MgZnMn alloys10.1016/j.corsci.2015.02.015 ↗
30. Permanganate conversion coating on AZ31 magnesium alloy with enhanced corrosion resistance10.1016/j.corsci.2015.01.040 ↗
31. Designing for the chemical conversion coating with high corrosion resistance and low electrical contact resistance on AZ91D magnesium alloy10.1016/j.corsci.2018.02.051 ↗
32. Phosphate chemical conversion coatings on metallic substrates for biomedical application: a review10.1016/j.msec.2014.11.038 ↗
33. Conversion coating treatment for AZ91 magnesium alloys by a permanganate-REMS bath10.1002/maco.200604000 ↗
34. Design and demonstration of hybrid multilayer structures: layer-by-layer mixed covalent and ionic interlayer linking chemistry10.1021/la000627v ↗
35. Measurement of the corrosion rate of magnesium alloys using Tafel extrapolation10.1016/j.corsci.2009.10.016 ↗
36. 2-Hydroxy-4-methoxy-acetophenone as an environment-friendly corrosion inhibitor for AZ91D magnesium alloy10.1016/j.corsci.2013.04.005 ↗
37. ASTM · 2011
38. Biomedical coatings on magnesium alloys - a review10.1016/j.actbio.2012.04.012 ↗
39. Adsorption and stability of self-assembled organophosphonic acid monolayers on plasma modified Zn–Mg–Al alloy surfaces10.1016/j.surfcoat.2012.12.035 ↗
40. Conversion of glucose into levulinic acid with solid metal(IV) phosphate catalysts10.1016/j.jcat.2013.03.023 ↗
41. Corrosion resistance and durability of superhydrophobic surface formed on magnesium alloy coated with nanostructured cerium oxide film and fluoroalkylsilane molecules in corrosive NaCl aqueous solution10.1021/la2002783 ↗
42. Effective removal of heavy metals from aqueous solutions by graphene oxide–zirconium phosphate (GO–Zr-P) nanocomposite10.1021/acs.iecr.6b00728 ↗
43. Assessing the corrosion of biodegradable magnesium implants: a critical review of current methodologies and their limitations10.1016/j.actbio.2011.11.014 ↗
44. Comparative corrosion behavior of Zn with Fe and Mg in the course of immersion degradation in phosphate buffered saline10.1016/j.corsci.2016.05.039 ↗
45. Accurate electrochemical measurement of magnesium corrosion rates; a combined impedance, mass-loss and hydrogen collection study10.1016/j.electacta.2013.12.124 ↗
46. Strengthened corrosion control of poly (lactic acid) (PLA) and poly (ε-caprolactone) (PCL) polymer-coated magnesium by imbedded hydrophobic stearic acid (SA) thin layer10.1016/j.corsci.2016.07.027 ↗