journal article·2025-01

Insight into the mechanism of abnormal degradation of duplex U-Nb alloy

Licheng Chen, Yawen Zhao, Xianglin Chen, Hefei Ji, Bin Su, Piheng Chen, Xiaolin Wang

Corrosion Science· Volume 242
Publisher page

Abstract

Niobium is introduced to uranium to enhance the corrosion resistance of metallic uranium, while duplex U-Nb alloy exhibits anomalous degradation to hydrogen corrosion. To understand the underlying mechanism, we employed high-resolution transmission electron microscopy (HRTEM) and density functional theory (DFT) calculations to characterize the structure of the phase interface in duplex U-Nb alloy and its interaction with hydrogen and vacancy. Combined with the different behaviors of hydrogen in the two phases of the duplex U-Nb alloy, a mechanism contributing to the observed abnormal degradation is proposed, corroborated by the special distribution of hydride within the duplex U-Nb alloy.
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Research context

OpenAlex topics: Nuclear Materials and Properties · Fusion materials and technologies · High Temperature Alloys and Creep

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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