Insight into selective external oxidation mechanism of Fe-Mn-Si model alloys during recrystallization annealing
Source abstract
Abstract
The selective external oxidation behavior of Fe- xMn -ySi alloys under various dew points (DPs) during recrystallization annealing was investigated. The results indicate that the Si/Mn ratios (form 0.25–1) affect variously on external oxidation at different DPs. At DP-40 ℃, higher Si/Mn ratio significantly increased Mn 2SiO 4/MnSiO 3 films on surface. At DP-10 and +10 ℃, Si and Mn synergistically promoted the internal oxidation. Determined a key inflection point of Si/Mn ratio (0.5) to transform internal oxidation to external oxidation. With higher Si/Mn ratios at DP+10 ℃, the increased internal oxides extruded Fe atoms and formed more Fe nodules on the surface.
Source: expertdata · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Microstructure and Mechanical Properties of Steels · High-Temperature Coating Behaviors · Metallurgical Processes and Thermodynamics
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (55)
Show source-provided references
1. New developments of advanced high-strength steels for automotive applications10.1016/j.crhy.2018.11.004 ↗
2. To correlate the phase transformation and mechanical behavior of QP steel sheets10.1016/j.ijmecsci.2019.01.003 ↗
3. Development of 3rd generation AHSS with medium Mn content alloying compositions10.1016/j.msea.2012.11.113 ↗
4. Nanoscale analysis of the influence of pre-oxidation on oxide formation and wetting behavior of hot-dip galvanized high strength steel10.1016/j.corsci.2015.01.016 ↗
5. Effect of annealing atmosphere on the galvanizing behavior of a dual-phase steel10.1016/j.msea.2006.09.116 ↗
6. On the in-situ aluminothermic reduction of manganese oxides in continuous galvanizing baths10.1016/j.surfcoat.2012.09.038 ↗
7. The influence of Mn Content on the wettability of dual-phase high-strength steels by liquid Zn—0.23% Al10.1007/s10853-012-6737-z ↗
8. M. International
9. Yoshitsugu · Eff. Mn Content Steels Sel. Surf. Oxid. Behav. 1 Mass% Si Bear. Low. C. Steels Recryst. Annealing · 2007 · 93 · 489
10. Effect of Si/Mn ratio on galvannealing behavior of Si-added steel10.2355/isijinternational.ISIJINT-2018-063 ↗
11. F.J.R.d.M.C.d.I. Techniques
12. Influence of oxide morphologies on the galvanizability of the third generation automotive steel10.4028/www.scientific.net/AMR.887-888.233 ↗
13. Selective oxidation and reactive wetting of 1.0 Pct Si-0.5 Pct Al and 1.5 Pct Si TRIP-assisted steels10.1007/s11661-010-0192-8 ↗
14. Selective oxidation of a C-2Mn-1.3Si (Wt Pct) advanced high-strength steel during continuous galvanizing heat treatments10.1007/s11661-018-4854-2 ↗
15. The change of steel surface chemistry regarding oxygen partial pressure and dew point10.1016/j.apsusc.2012.12.103 ↗
16. Effect of dew point and gas flow rate on the surface oxidation of advanced high strength steels10.2355/isijinternational.ISIJINT-2015-158 ↗
17. Role of dew points and Fe pre-coats on the galvanizing and galvannealing of dual phase steel10.1016/j.surfcoat.2021.127573 ↗
18. Selective oxidation of dual phase steel after annealing at different dew points10.1016/j.apsusc.2011.01.126 ↗
19. On the transition of internal to external selective oxidation on CMnSi TRIP steel10.1007/s11661-014-2442-7 ↗
20. Study of selective oxidation behavior of a 1.2Si-1.5Mn TRIP steel during intercritical annealing10.1149/2.050212jes ↗
21. Effect of dew point on the surface selective oxidation and subsurface microstructure of TRIP-aided steel10.1016/j.surfcoat.2011.08.038 ↗
22. Effect of water pressure and soaking time on the selective oxidation of DP980 advanced high strength steel10.1016/j.apsusc.2018.05.034 ↗
23. Selective oxidation of ternary Fe-Mn-Si alloys during annealing process10.1016/j.corsci.2020.108859 ↗
24. Important new values of the physical constants of 1986
25. D. Zhang, Y. Liu, H. Li, Y. Song, C. Wang, H. Sun, B. Wang, C. Ma, Y.J.S. Zheng, Interfaces, High temperature oxidation behavior and microstructure evolution of medium Mn steel, (2024) 104139.10.1016/j.surfin.2024.104139 ↗
26. Grain boundary oxidation in iron-based alloys, investigated by 18O enriched water vapour – the effect of mixed oxides in binary and ternary Fe–{Al, Cr, Mn, Si} systems10.1016/j.corsci.2015.04.009 ↗
27. Influence of Si content on selective oxidation and oxide scale phase transition during hot-rolled coiling10.1016/j.jmrt.2023.06.163 ↗
28. Zhang · Technol., Influ. Si Content Sel. Oxid. oxide Scale phase Transit. hot-Roll. coiling · 2023 · 25 · 3212
29. FactSage thermochemical software and databases — recent developments10.1016/j.calphad.2008.09.009 ↗
30. Influence of selective surface oxidation of Si and Mn on Fe–Zn alloying reaction on hot-rolled steel sheets10.2355/isijinternational.ISIJINT-2019-067 ↗
31. Effect of dew point on the selective surface oxidation behavior of Mn added steels during recrystallization annealing10.2355/tetsutohagane.TETSU-2022-022 ↗
32. O. Kubaschewski, C.B. Alcock, Metallurgical thermochemistry, Metallurgical thermochemistry, 1979.
33. Numerical simulation of internal oxidation of steels during annealing treatments10.1007/s11085-005-5718-x ↗
34. Gong · Anal. Model Sel. Extern. Oxid. Fe-Mn Bin. Alloy. isothermal annealing Treat. · 2020 · 166
35. Morphology and composition of inclusions in Si–Mn deoxidized steel at the solid-liquid equilibrium temperature10.2355/isijinternational.ISIJINT-2019-313 ↗
36. Suzuki · Thermodyn. Anal. Sel. Oxid. Behav. Si Mn-added Steel Recryst. annealing · 2009 · 49 · 564
37. Il-Ryoung, Sohn, Jong-Sang, Kim, Seetharaman, S.J.I. International, Effect of Dew Point and Gas Flow Rate on the Surface Oxidation of Advanced High Strength Steels, (2015).
38. Nucleation and growth of selective oxide particles on ferritic steel10.1016/j.corsci.2010.03.030 ↗
39. Effect of dew point on the reactive wetting of a C-2Mn-1.3Si (wt%) advanced high strength steel during continuous galvanizing10.1016/j.surfcoat.2018.06.060 ↗
40. High temperature oxidation behaviors of steels at initial stages in air10.1016/j.corsci.2024.111838 ↗
41. Selective oxidation in press hardening steel during annealing with different dew points
42. selective oxidation in press hardening steel during annealing with different dew points
43. Thermodynamic and kinetic aspects on the selective surface oxidation of binary, ternary and quarternary model alloys10.1016/j.apsusc.2006.10.031 ↗
44. Resolving surface chemical states in XPS analysis of first row transition metals, oxides and hydroxides: Cr, Mn, Fe, Co and Ni10.1016/j.apsusc.2010.10.051 ↗
45. Characterisation of the spinels MxCo1−xFe2O4 (M = Mn, Fe or Ni) using X-ray photoelectron spectroscopy10.1016/0169-4332(95)00186-7 ↗
46. Use of x-ray photoelectron spectroscopy to study bonding in Cr, Mn, Fe, and Co compounds10.1063/1.1678348 ↗
47. B.P.m. Materials Transactions, m.p. science, Effect of annealing atmosphere and steel alloy composition on oxide formation and radiative properties of advanced high-strength steel strip
48. M.T. B
49. New insights into the effect of Al on the selective oxidation of advanced high-strength steels prior to hot-dip galvanizing10.1016/j.actamat.2024.119651 ↗
50. Defect-driven selective metal oxidation at atomic scale10.1038/s41467-020-20876-9 ↗
51. Changing oxide layer structures with respect to the dew point prior to hot-dip galvanizing of δ-TRIP steel10.1016/j.surfcoat.2017.12.046 ↗
52. Numerical implementation and application of an extended model for diffusion and precipitation of chemical elements in metallic matrices10.1007/s11085-010-9193-7 ↗
53. Internal oxidation of Ni⎕Al and Ni⎕Al⎕Si alloys at the dissociation pressure of NiO10.1016/0956-7151(94)90292-5 ↗
54. A. Paunoiu, Effet de l’atmosphère du recuit de recristallisation sur l’oxydation sélective et les réactions GalvAnnealing d’un acier TRIP MnAl, in, 2018.
55. Investigation of selective oxidation during cooling of hot-rolled iron-manganese-silicon alloys10.1016/j.corsci.2021.109466 ↗