journal article·2024-05Open access

Unique corrosion behavior of an archaeological Roman iron ring: Microchemical characterization and thermodynamic considerations

Valentina Valbi, Fabio Enrico Furcas, Delphine Neff, Philippe Dillmann, Ueli Angst, Myriam Krieg, Anika Duvauchelle, Marion Berranger, Stefano Mischler, Laura Brambilla, Naima Gutknecht, Christian Degrigny

Corrosion Science· Volume 231

Abstract

The corrosion mechanisms of a Roman iron bezel ring were investigated by in-depth characterization of its uncommon corrosion pattern and thermodynamic modelling. A silver foil and altered glass remnants were identified, covered with thick strata of magnetite and goethite. Underneath it, was a multi-millimetric cavity, filled with spheroidal magnetite or magnetite/goethite nodules in a siderite matrix. The bottom of the preserved object showed a marbled corrosion structure composed of goethite, magnetite/maghemite and hematite. Heterogeneous and evolving local conditions, involving synergistic effects of electrolytic and dissolution/precipitation mechanisms might explain the unique morphology and nature of the corrosion products observed.
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Research context

OpenAlex topics: Corrosion Behavior and Inhibition · Cultural Heritage Materials Analysis · Building materials and conservation

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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