journal article·2023-12

Characterization of NiTiNb10.5 shape memory alloy: microstructural aspects and high-temperature oxidation behavior

C.B. Martins Júnior, R. Silva, P. Gargarella, B. Gleeson, C.A.D. Rovere

Corrosion Science· Volume 225
Publisher page

Abstract

The influence of Niobium addition on the high-temperature oxidation behavior of NiTi shape-memory alloys was investigated. Mass-gain kinetics were determined for up to 100 h oxidation at 800, 900 and 1000 °C. Niobium addition drastically reduced the oxidation rates. The surface and cross-section of the resulting oxide layers were characterized by XRD and SEM/EDS. The presence of Nb changed the morphology, phase assemblage, and composition of the scale product, which directly influenced the observed results. The postulated reasons for the improved oxidation resistance were the Nb-doping of TiO 2 and the formation of an Nb-rich layer at the scale/alloy interface.
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Research context

OpenAlex topics: Shape Memory Alloy Transformations · Magnetic and transport properties of perovskites and related materials · Intermetallics and Advanced Alloy Properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (50)

Show source-provided references
1. Otsuka · 1998
2. Physical metallurgy of Ti–Ni-based shape memory alloys10.1016/j.pmatsci.2004.10.001 ↗
3. Manufacturing and processing of NiTi implants: A review10.1016/j.pmatsci.2011.11.001 ↗
4. Oxidation behavior of equiatomic TiNi alloy in high temperature air environment10.1016/0921-5093(96)10409-3 ↗
5. Surface oxidation of NiTi shape memory alloy10.1016/S0142-9612(02)00244-2 ↗
6. Surface oxidation of NiTi and its effects on thermal and mechanical properties10.1016/j.intermet.2018.09.013 ↗
7. Surface oxidation of NiTi during thermal exposure in flowing argon environment10.1016/j.matdes.2017.11.061 ↗
8. Formation mechanism of Ni2Ti4Ox in NITI shape memory alloy10.1016/j.mtla.2018.100194 ↗
9. Impurity levels and fatigue lives of pseudoelastic NiTi shape memory alloys10.1016/j.actamat.2013.02.054 ↗
10. Analysis of New Nitinol Ingot Qualities10.1007/s11665-014-1054-0 ↗
11. Comparative Oxidation Kinetics of a NiPtTi High Temperature Shape Memory Alloy10.1007/s11085-010-9202-x ↗
12. High temperature oxidation behavior of Ti–Ni–Hf shape memory alloy10.1016/j.tca.2014.02.016 ↗
13. Oxidation Behavior of Ti50Ni40Cu10 Shape-Memory Alloy in 700–1,000 °C Air10.1007/s11085-008-9135-9 ↗
14. Oxide Scales Formed on NiTi and NiPtTi Shape Memory Alloys10.1007/s11661-011-1036-x ↗
15. Influence of Ni/Ti ratio and Nb addition on martensite transformation behavior of NiTiNb alloys10.1016/j.jallcom.2019.02.330 ↗
16. Fundamental Deformation and Recovery Behaviors of Ni-Ti-Nb Shape Memory Alloy10.1299/jsmea.44.57 ↗
17. TiNiNb wide hysteresis shape memory alloy with low niobium content10.1016/j.msea.2003.11.044 ↗
18. Wide hysteresis NiTi(Nb) shape memory alloys with low Nb content (4.5at%)10.1016/j.msea.2006.03.110 ↗
19. Thermal, Structural Properties and Potential Dynamic Corrosion Study of Ti-27Ni-21Nb-2Ta SMA
20. The comparison of TiNiNbTa and TiNiNbV SMAs in terms of corrosion behavior, microhardness, thermal and structural properties10.1007/s10973-022-11360-1 ↗
21. Comparison of Thermodynamic Parameters and Corrosion Behaviors of Ti50Ni25Nb25 and Ti50Ni25Ta25 Shape Memory Alloys10.1134/S0031918X21101130 ↗
22. Influence of the Nb Content on the Microstructure and Phase Transformation Properties of NiTiNb Shape Memory Alloys10.1007/s11837-020-04026-6 ↗
23. High temperature oxidation behavior of NiTiNb intermetallic alloys10.1016/j.intermet.2007.01.005 ↗
24. Effect of niobium addition on tensile properties and oxidation resistance of a titanium-based alloy10.1016/j.corsci.2020.109198 ↗
25. Effects of Nb addition on oxidation behavior of TiAl10.1016/0966-9795(95)94254-C ↗
26. Effect of Nb on the high temperature oxidation of Ti–(0–50 at%)Al10.1016/S1359-6462(02)00042-8 ↗
27. High-Temperature Oxidation of β-NbTi Alloys10.1007/s11661-008-9548-8 ↗
28. D. Grummon, K.-B. Low, J. Foltz, J. Shaw, A New Method for Brazing Nitinol Based on the Quasibinary TiNi-Nb System, in: 48th AIAA/ASME/ASCE/AHS/ASC Struct. Struct. Dyn. Mater. Conf., American Institute of Aeronautics and Astronautics, Reston, Virigina, 2007. https://doi.org/10.2514/6.2007–1741.10.2514/6.2007-1741 ↗
29. Microstructure evolution of Ni47Ti44Nb9 shape memory alloy in high-temperature deformation
30. Phase Transformation and Recovery Stress of Ni47Ti44Nb9 Alloy During Constrained Heating and Cooling10.1007/s11661-019-05533-1 ↗
31. Compressive properties and microstructure evolution in NiTiNb alloy with mesh eutectic phase10.1016/j.msea.2020.140434 ↗
32. {111}<110> Orientation Induced Anisotropy of Shape Memory Effect in NiTiNb Pipe Joints
33. Microstructure and Mechanical Properties of NiTi-Based Eutectic Shape Memory Alloy Produced via Selective Laser Melting In-Situ Alloying by Nb
34. Strengthening mechanism and micropillar analysis of high-strength NiTi–Nb eutectic-type alloy prepared by laser powder bed fusion10.1016/j.compositesb.2020.108358 ↗
35. Influence of precipitation on phase transformation and mechanical properties of Ni-rich NiTiNb alloys10.1016/j.matchar.2019.05.013 ↗
36. The Effect of Niobium on the Oxidation Behavior of Titanium in Ar/20% O2 Atmospheres10.1023/A:1004680909484 ↗
37. High-Temperature Oxidation of Ti-4.32 wt% Nb Alloy10.1007/BF00603991 ↗
38. Issues Concerning the Oxidation of Ni(Pt)Ti Shape Memory Alloys10.1149/1.4718005 ↗
39. Oxidation behavior of TiNi shape memory alloy at 450–750°C10.1016/S0921-5093(03)00287-9 ↗
40. Current Status of Research on the Oxidation Behavior of Refractory High Entropy Alloys10.1002/adem.202001047 ↗
41. A comparative study on the oxidation behaviours of a TNM alloy in argon and oxygen atmospheres at 650 °C10.1016/j.corsci.2021.109415 ↗
42. Structure and properties of titanium and the Ti-6Al-7Nb alloy after isothermal oxidation10.1080/02670844.2020.1711631 ↗
43. Effect of Sn addition on the high-temperature oxidation behavior of high Nb-containing TiAl alloys10.1016/j.corsci.2020.108449 ↗
44. Significant enhancement of high temperature oxidation resistance of pure titanium via minor addition of Nb and Si10.1016/j.corsci.2020.108430 ↗
45. Effect of Nb Content on Cyclic Oxidation Behavior of As-Cast Ti-1100 Alloys
46. X. Song, W. Ye, S. Hui, Y. Li, Oxidation Behavior of NiTi-Al Based Alloy with Nb and Mo Additions, IOP Conf. Ser. Mater. Sci. Eng. 250 (2017). https://doi.org/10.1088/1757–899X/250/1/012005.10.1088/1757-899X/250/1/012005 ↗
47. Hauffe · 1995
48. McCafferty · 2010
49. Defect chemistry and semiconducting properties of titanium dioxide: II. Defect diagrams✩10.1016/S0022-3697(02)00480-8 ↗
50. Structural Stability from Crystallographic Shear in TiO2–Nb2O5 Phases: Cation Ordering and Lithiation Behavior of TiNb24O6210.1021/acs.inorgchem.6b03154 ↗