Monitoring alterations in a salt layer’s deliquescence properties during the atmospheric corrosion of a metal surface using a quartz crystal microbalance
Source abstract
Abstract
The deliquescence of salt residues on metal structures can exacerbate the atmospheric corrosion of these structures. However, the conversion of salt residues to corrosion products alters the metal surface time of wetness (TOW) in ways that are difficult to monitor. This study demonstrates the use of quartz crystal microbalance with acoustic impedance measurement (QCM-I) to simultaneously monitor the corrosion and the changing deliquescence properties of various chloride salt layers printed on copper surfaces. While the results herein apply to Canada’s proposed deep geological repository (DGR) for used nuclear fuel, the methodology applies to any combination of salts and metal surfaces.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Acoustic Wave Resonator Technologies · Gas Sensing Nanomaterials and Sensors · Spectroscopy and Laser Applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (37)
Show source-provided references
1. Wetting phenomena and time of wetness in atmospheric corrosion: a review10.1515/corrrev-2012-0015 ↗
2. Effect of relative humidity on corrosion of steel under sea salt aerosol proxies: II. MgCl2, artificial seawater10.1149/2.0231410jes ↗
3. An evaluation of corrosion processes affecting copper-coated nuclear waste containers in a deep geological repository10.1016/j.pmatsci.2020.100766 ↗
4. Effect of relative humidity on corrosion of steel under sea salt aerosol proxies: I. NaCl10.1149/2.0221410jes ↗
5. A spectromicroscopy study of the corrosion of polymer coated steel10.1016/j.corsci.2018.09.008 ↗
6. B.C. Barlow, A. Situm, B. Guo, X. Guo, A.P. Grosvenor, I.J. Burgess, X-ray microprobe characterization of corrosion at the buried polymer-steel interface, Corros. Sci., 144 (2018) 198–206. https://doi.org/10.1016/j.corsci.2018.08.051. https://www.sciencedirect.com/science/article/pii/S0010938×18312459.10.1016/j.corsci.2018.08.051 ↗
7. Atmospheric corrosion in marine environments10.5006/0010-9312-34.12.433 ↗
8. C. Houska, Deicing salt–recognizing the corrosion threat, International Molybdenum Association, Pittsburgh, TMR Consulting, (2007) 1–10. doi: 10.1002/maco.201709907.
9. Corrosion and protection of non-patinated, sulphide-and chloride-patinated bronze
10. Characterization of typical patinas simulating bronze corrosion in outdoor conditions10.1016/j.matchemphys.2017.07.091 ↗
11. Humidity sorption due to deposited aerosol particles studied in situ outdoors on gold surfaces10.1149/1.1837371 ↗
12. Deliquescence phase transition measurements by quartz crystal microbalance frequency shifts10.1021/jp3016722 ↗
13. Simultaneous infrared reflection absorption spectroscopy and quartz crystal microbalance measurements for in situ studies of the metal/atmosphere interface10.1149/1.1837948 ↗
14. In situ viscoelastic properties and chain conformations of heavily hydrated carboxymethyl dextran layers: a comparative study using OWLS and QCM-I chips coated with waveguide material10.1038/s41598-018-30201-6 ↗
15. Design and validation of a low-cost open-source impedance based quartz crystal microbalance for electrochemical research10.1016/j.ohx.2022.e00374 ↗
16. Response of the electrochemical quartz crystal microbalance for gold electrodes in the double‐layer region10.1149/1.1836987 ↗
17. The quartz-crystal microbalance in an undergraduate laboratory experiment. I. Fundamentals and instrumentation10.1021/ed084p1334 ↗
18. The use of quartz oscillators for weighing thin layers and for microweighing10.1007/BF01337937 ↗
19. Monitoring of in situ corrosion rates in a telephone switching office in Burbank, California10.1149/1.2048704 ↗
20. Kinetics of initial oxidation of UHV prepared Zn films
21. The oxidation of aluminum films in low-pressure oxygen atmospheres10.1016/0039-6028(68)90174-X ↗
22. Quartz crystal microbalance measurements of O/Ti and CO/Ti atom ratios on very thin Ti films10.1016/0039-6028(78)90002-X ↗
23. Experimental in situ studies of copper exposed to humidified air10.1016/S0010-938X(99)00125-0 ↗
24. In situ studies of the initial atmospheric corrosion of copper influence of humidity, sulfur dioxide, ozone, and nitrogen dioxide10.1149/1.1393566 ↗
25. Water adsorption vs phase transition of aerosols monitored by a quartz crystal microbalance10.1021/acsomega.0c04698 ↗
26. A review of experimental techniques for aerosol hygroscopicity studies10.5194/acp-19-12631-2019 ↗
27. Temperature-dependent deliquescent and efflorescent properties of methanesulfonate sodium studied by ATR-FTIR spectroscopy10.1021/jp405896y ↗
28. A database for deliquescence and efflorescence relative humidities of compounds with atmospheric relevance10.1016/j.fmre.2021.11.021 ↗
29. Humidity fixed points of binary saturated aqueous solutions10.6028/jres.081A.011 ↗
30. Formation of liquid water at low temperatures via the deliquescence of calcium chloride: implications for Antarctica and Mars10.1016/j.pss.2016.07.006 ↗
31. H. Strandberg, L.G. Johansson, Some aspects of the atmospheric corrosion of copper in the presence of sodium chloride, J. Electrochem. Soc., 145 (1998) Medium: X; Size, 1093–1100. https://doi.org/10.1149/1.1838422.10.1149/1.1838422 ↗
32. Electrochemical aspects of copper atmospheric corrosion in the presence of sodium chloride10.1016/j.electacta.2018.04.184 ↗
33. Atmospheric corrosion of Cu during constant deposition of NaCl10.1149/2.037308jes ↗
34. In situ studies of the effect of CO2 on the initial NaCl-induced atmospheric corrosion of copper
35. In situ studies of the effect of CO2 on the initial NaCl-induced atmospheric corrosion of copper10.1149/1.1984448 ↗
36. Hygroscopicity measurement of sodium carbonate, β-alanine and internally mixed β-alanine/Na2CO3 particles by ATR-FTIR10.1016/j.jes.2019.07.002 ↗
37. M. Gobien, F. Garisto, E. Kremer, C. Medri, Sixth Case Study: Reference Data and Codes, NWMO-TR-2016–10, Nuclear Waste Management Organization, 2016.