journal article·2024-04

Microstructure evolution and oxidation/ablation behaviors of NbSi2/Nb2O5-SiO2/HfC-HfO2 multilayer protective coating at 1200 °C and 1800 °C

Zhiyun Ye, Yongchun Zou, Shuqi Wang, Guoliang Chen, Zhao Wang, Lei Wen, Guangxi Zhang, Lina Zhao, Yaming Wang, Yu Zhou

Corrosion Science· Volume 230
Publisher page

Abstract

In this study, the LPDS-coating charactered by the volcanic-like surface with micropores is synthetized on Nb alloys through halide activated pack cementation (HAPC) combined with a liquid-plasma-assisted particle deposition and sintering (LPDS) technology. Results show that the mass gain of NbSi 2/Nb 2O 5-SiO 2/HfC-HfO 2 coated sample (6.38 mg/cm 2) is only 46% compared to NbSi 2 coated sample (13.8 mg/cm 2 ) and holds the lowest oxidation rate (0.367 mg 2·cm −4·h −1 ) during the isothermal oxidation process after 100 h at 1200°C. Besides, this multilayer coating also exhibits an enhanced oxyacetylene ablation resistance (the lowest mass ablation rate of −0.106 mg/s and a linear ablation rate of −0.333 μm/s) compared with NbSi 2 coating and NbSi 2/Nb 2O 5-SiO 2 coating. Such superior high-temperature oxidation/oxyacetylene ablation resistance of multilayer coating are mainly ascribed to HfC oxygen-consuming phase combined with the oxide scale’s high-temperature stability provided by the HfSiO 4-HfO 2-SiO 2 skeleton.
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Research context

OpenAlex topics: Intermetallics and Advanced Alloy Properties · Advanced ceramic materials synthesis · Metal and Thin Film Mechanics

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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