journal article·2023-06

Oxidation behavior of CrAl-Mo coated Zircaloy-4 in DB and BDB scenarios

Yan Meng, Pengcheng Li, Chen Chen, Sifan Zeng, Song Zeng, Chaowen Zhu, Huahai Shen, Xiaochun Han, Haibin Zhang

Corrosion Science· Volume 217
Publisher page

Abstract

Cr coatings have been widely applied on Zircaloy for accident tolerant fuel materials. However, it has long been a great challenge in the nuclear community for Cr coatings surviving in the beyond design basis conditions (BDB) because of the unstable chromia layer and eutectic reactions between Cr and Zr. In this study, bi-layered CrAl-Mo coatings have been designed to improve the performance of Cr coatings in the BDB conditions. Results showed that the CrAl-Mo coated samples can tolerant in steam at temperatures as high as1400 °C because of the formation of a more stable alumina layer on the surface and the inhibition of eutectic reactions near the coating/substrate interface. Moreover, diffusion of Mo facilitated the formation of a CrAlMo layer, which stabilized the outer alumina layer and reserved the Al inventory within the coating.
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Research context

OpenAlex topics: Nuclear Materials and Properties · Nuclear reactor physics and engineering · Fusion materials and technologies

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References (44)

Show source-provided references
1. Accident tolerant fuels for LWRs: a perspective10.1016/j.jnucmat.2013.12.005 ↗
2. High temperature steam oxidation of chromium-coated zirconium-based alloys: kinetics and process10.1016/j.corsci.2020.108537 ↗
3. A. Michau et al., Interlayers for Cr-coated nuclear fuel claddings (NuMat2020-The Nuclear Materials Conference). 2020.
4. Development status of accident-tolerant fuel for light water reactors in Korea10.1016/j.net.2015.11.011 ↗
5. Accident tolerant fuel cladding development: promise, status, and challenges10.1016/j.jnucmat.2017.12.043 ↗
6. Fuel performance of chromium-coated zirconium alloy and silicon carbide accident tolerant fuel claddings10.1016/j.anucene.2018.06.001 ↗
7. Properties of chromium thin films deposited in a hollow cathode magnetron powered by pulsed DC or HiPIMS10.1016/j.surfcoat.2017.10.006 ↗
8. Chromium coatings deposited by cooled and hot target magnetron sputtering for accident tolerant nuclear fuel claddings10.1016/j.surfcoat.2020.125618 ↗
9. A study of the oxidation of FeCrAl alloy in pressurized water and high-temperature steam environment10.1016/j.corsci.2015.02.027 ↗
10. Performance of iron–chromium–aluminum alloy surface coatings on Zircaloy 2 under high-temperature steam and normal BWR operating conditions10.1016/j.jnucmat.2015.11.037 ↗
11. Oxidation resistance improvement of Zr-4 alloy in 1000° C steam environment using ZrO2/FeCrAl bilayer coating10.1016/j.surfcoat.2018.05.005 ↗
12. Oxidation resistance and micromechanical properties of a Ti–46Al–8Nb (at%) alloy with Cr–Si magnetron-sputtered coatings10.1016/j.surfcoat.2018.07.073 ↗
13. Strengthened Cr-Si-base alloys for high temperature applications10.1016/j.ijrmhm.2018.05.016 ↗
14. Transforming the amorphous Ti-Al-C coatings to high-purity Ti2AlC MAX phase coatings by prolonged annealing at 550 °C
15. Diffusion-controlled intercalation approach to synthesize the Ti2AlC MAX phase coatings at low temperature of 550 °C
16. High temperature steam-oxidation behavior of arc ion plated Cr coatings for accident tolerant fuel claddings10.1016/j.surfcoat.2015.09.022 ↗
17. J. Brachet et al., Behavior of chromium coated M5TM claddings under loca conditions, In: Proceedings of the WRFPM2017 - Water Reactor Fuel Performance Meeting, Ramada Plaza Jeju - Jeju Island, Korea, September 10 - 14, 2017 2017.
18. Early studies on Cr-Coated Zircaloy-4 as enhanced accident tolerant nuclear fuel claddings for light water reactors10.1016/j.jnucmat.2019.02.018 ↗
19. High temperature oxidation and microstructural evolution of cold spray chromium coatings on Zircaloy-4 in steam environments10.1016/j.jnucmat.2019.151737 ↗
20. Oxidation kinetics of Cr-coated zirconium alloy: effect of coating thickness and microstructure10.1016/j.corsci.2020.108883 ↗
21. Predicting oxide stability in high-temperature water vapor10.1007/s11837-006-0063-3 ↗
22. Microstructure evolution and adhesion properties of thick Cr coatings under different thermal shock temperatures10.1016/j.surfcoat.2021.127224 ↗
23. On the oxidation and nitridation of chromium at 1300 °C
24. An interesting oxidation phenomenon of Cr coatings on Zry-4 substrates in high temperature steam environment10.1016/j.corsci.2019.05.017 ↗
25. Systematic investigations on the coating degradation mechanism during the steam oxidation of Cr-coated Zry-4 at 1200 °C10.1016/j.corsci.2022.110310 ↗
26. Oxidation behavior of Cr-coated zirconium alloy cladding in high-temperature steam above 1200°C10.1038/s41529-021-00155-8 ↗
27. Oxidation behavior and Cr-Zr diffusion of Cr coatings prepared by atmospheric plasma spraying on zircaloy-4 cladding in steam at 1300 °C10.1016/j.corsci.2022.110378 ↗
28. Supplemental literature review of binary phase diagrams: B-Fe, Cr-Zr, Fe-Np, Fe-W, Fe-Zn, Ge-Ni, La-Sn, La-Ti, La-Zr, Li-Sn, Mn-S, and Nb-Re10.1007/s11669-016-0465-z ↗
29. Corrosion and corrosion protection of aluminium - ScienceDirect10.1533/9780857090256.2.574 ↗
30. Critical evaluation and selection of standard state thermodynamic properties for chromium metal and its aqueous ions, hydrolysis species, oxides, and hydroxides10.1021/je980080a ↗
31. Investigation of Cr–Al composite coatings fabricated on pure Ti substrate via mechanical alloying method: effects of Cr–Al ratio and milling time on coating, and oxidation behavior of coating10.1016/j.jallcom.2015.11.094 ↗
32. Microstructure and oxidation behavior of CrAl laser-coated zircaloy-4 alloy10.3390/met7020059 ↗
33. Response of Cr and Cr-Al coatings on Zircaloy-2 to high temperature steam10.1016/j.jnucmat.2017.10.021 ↗
34. S. Zeng et al., Influence of Al content on the oxidation behavior of CrAl coating on Zry-4 alloys in 1200°C steam, 2022.10.1016/j.corsci.2022.110115 ↗
35. Effect of Al content on high-temperature oxidation behavior and failure mechanism of CrAl-coated Zircaloy10.1016/j.corsci.2021.109856 ↗
36. Oxidation behavior of FeCrAl coated Zry-4 under high temperature steam environment10.1016/j.corsci.2019.01.004 ↗
37. Behavior of an improved Zr fuel cladding with oxidation resistant coating under loss-of-coolant accident conditions10.1016/j.jnucmat.2016.10.021 ↗
38. Oxidation behavior of Cr-coated zirconium alloy cladding in high-temperature steam above 1200 °C10.1038/s41529-021-00155-8 ↗
39. Investigation of the oxidation mechanisms of superlattice Cr-CrN/TiSiN-Cr multilayer coatings on Zircaloy substrates under high-temperature steam atmospheres10.1016/j.corsci.2021.109782 ↗
40. Microstructure, corrosion resistance and oxidation behavior of Cr-coatings on Zircaloy-4 prepared by vacuum arc plasma deposition10.1016/j.corsci.2019.06.029 ↗
41. A systematic study of the oxidation behavior of Cr coatings on Zry4 substrates in high temperature steam environment10.1016/j.corsci.2020.108826 ↗
42. C. Wagner, Reaktionstypen bei der Oxydation von Legierungen, Zeitschrift Für Elektrochemie Berichte Der Bunsengesellschaft Für Physikalische Chemie, vol. 63, no. 7, pp. 772–782, 2010.10.1002/bbpc.19590630713 ↗
43. Co-doping effect of Hf and Y on improving cyclic oxidation behavior of (Ni,Pt)Al coating at 1150 °C10.1016/j.corsci.2020.109093 ↗
44. Effect and role of alloyed Nb on the air oxidation behaviour of Ni-Cr-Fe alloys at 1000 °C10.1016/j.corsci.2017.08.003 ↗