Numerical model of selective external oxidation of Fe-Mn binary alloys during non-isothermal annealing treatment
Source abstract
Abstract
A numerical model has been developed to describe the kinetics of selective external oxidation of Fe-Mn alloys during non-isothermal annealing. This model involves a thermodynamic analysis of possible reactions during annealing and then numerically solves the theoretical equations describing reactive diffusion and heterogeneous nucleation and growth of MnO oxides. The results of the model are the temperature-dependent evolution of the nucleation rate of MnO embryos and the size and surface coverage fraction of MnO particles. The results were validated by experimental data. The study concludes with a parametric analysis of the different physical constants of the model.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: High-Temperature Coating Behaviors · Corrosion Behavior and Inhibition · Metallurgical Processes and Thermodynamics
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (61)
Show source-provided references
1. Galvanizability of high-strength steels for automotive applications10.1007/s11661-001-1042-5 ↗
2. Diffusive phase transformations in hot-dip galvanizing10.4028/www.scientific.net/MSF.155-156.527 ↗
3. The metallurgy of zinc-coated steels10.1016/S0079-6425(98)00006-1 ↗
4. The role of surface oxides on annealed high-strength steels in hot-dip galvanizing10.1016/j.corsci.2013.01.039 ↗
5. Study of selective oxidation by means of glow discharge optical emission spectroscopy10.1016/j.corsci.2011.01.012 ↗
6. Influence of H2-N2 atmosphere composition and annealing duration on the selective surface oxidation of low-carbon steels10.1016/j.corsci.2005.02.022 ↗
7. Relation between microstructure and adhesion of hot dip galvanized zinc coatings on dual phase steel10.1016/j.actamat.2012.02.003 ↗
8. Effect of oxides on the reaction kinetics during hot-dip galvanizing of high strength steels10.1016/j.corsci.2011.03.027 ↗
9. Wetting and reactive wetting during hot-dip galvanizing of high Mn alloyed steel with Zn-Al-Mg baths10.1016/j.surfcoat.2012.04.023 ↗
10. Influence of annealing treatment on wetting of steels by zinc alloys10.1007/s10853-012-6696-4 ↗
11. Nucleation and growth of selective oxide particles on ferritic steel10.1016/j.corsci.2010.03.030 ↗
12. Changing oxide layer structures with respect to the dew point prior to hot-dip galvanizing of δ-TRIP steel10.1016/j.surfcoat.2017.12.046 ↗
13. Effect of water pressure and soaking time on the selective oxidation of DP980 advanced high strength steel10.1016/j.apsusc.2018.05.034 ↗
14. Selective oxidation of a C-2Mn-1.3Si (wt pct) advanced high-strength steel during continuous galvanizing heat treatments10.1007/s11661-018-4854-2 ↗
15. Selective oxidation of a 0.1C-6Mn-2Si third generation advanced high-strength steel during dew-point controlled annealing10.1007/s11661-018-4513-7 ↗
16. Surface selective oxide reduction during the intercritical of medium Mn steel10.1007/s11661-017-4154-2 ↗
17. Selective oxidation of dual phase steel after annealing at different dew points10.1016/j.apsusc.2011.01.126 ↗
18. Thermodynamic and kinetic aspects on the selective surface oxidation of binary, ternary and quarternary model alloys10.1016/j.apsusc.2006.10.031 ↗
19. Dew-point controlled oxidation of Fe–C–Mn–Al–Si–Cu transformation-induced plasticity-aided steels10.1016/j.scriptamat.2008.03.025 ↗
20. Influence of dew point on the selective oxidation during annealing of cold rolled DP and Ti-IF steels
21. Evolution of near-surface concentration profiles of Cr during annealing of Fe-15Cr polycrystalline alloy10.1016/j.apsusc.2004.11.078 ↗
22. Anomalous oxidation of Fe-Si alloys under a low oxygen pressure at 800 °C10.1016/j.corsci.2015.05.055 ↗
23. Reaktionstypen bei der oxydation von legierungen
24. On the theory of internal oxidation sulphation of alloys10.1179/cmq.1969.8.1.35 ↗
25. Numerical simulation of internal oxidation of steels during annealing treatments10.1007/s11085-005-5718-x ↗
26. Limiting cases of subscale formation10.1016/0001-6160(78)90091-3 ↗
27. The formation of two layers in the internal oxidation of binary alloys by two oxidants in the absence of external scales10.1023/A:1018858303891 ↗
28. Internal oxidation of ternary alloys. Part II: kinetics in the presence of an external scale10.1007/BF01113373 ↗
29. Numerical implementation and application of an extended model for diffusion and precipitation of chemical elements in metallic matrices10.1007/s11085-010-9193-7 ↗
30. Analytical model of selective external oxidation of Fe-Mn binary alloys during isothermal annealing treatment10.1016/j.corsci.2020.108454 ↗
31. Selective oxidation of Fe-Mn (1 wt.%) binary alloy
32. Characterization of selective oxidation of manganese in surface layers of Fe–Mn alloys by different analytical methods10.2355/isijinternational.53.2000 ↗
33. Chen · 2012
34. In-situ investigation on the oxidation behavior of low alloyed steels annealed under N2-5%H2 protective atmosphere10.1002/srin.200100159 ↗
35. Thermochemical surface treatment of iron-silicon and iron-manganese alloys10.1002/sia.1198 ↗
36. Selective oxidation of IFTi stabilized steels during recrystallization annealing and steel / Zn reactivity
37. Surface modification of various Fe-Si and Fe-Mn alloys by oxidation / reduction treatments10.1179/026708404225016517 ↗
38. In situ surface analysis of annealed Fe-1.5%Mn and Fe-0.6%Mn low alloy steels10.1007/s00216-002-1538-x ↗
39. Important values of the physical constants of 1986, vapor pressure formations based on the ITS-90, and psychrometer formulae
40. Nucleation and growth of oxide particles on Fe-Mn (1 wt.%) binary alloy during annealing10.4028/www.scientific.net/MSF.941.1010 ↗
41. Sequential oxidation of Fe(100) by water adsorption: formation of an ordered hydroxylated surface10.1016/0039-6028(91)91179-2 ↗
42. A study of the initial reaction of water vapor with Fe(001) surface10.1016/0039-6028(77)90066-8 ↗
43. Adsorption of H2O on oxidized Fe(100) surfaces: comparison between the oxidation of iron by H2O and O210.1016/0039-6028(93)90155-D ↗
44. The water dissociation reaction on clean and oxidized iron (110)10.1063/1.443154 ↗
45. Interaction of water with clean and gallium precovered Fe(111) surfaces10.1116/1.580025 ↗
46. Solubility, permeability and diffusivity of oxygen in solid iron
47. Permeability, solubility, and diffusivity of oxygen in bcc iron
48. FactSage 7.3 · 2020
49. Critical evaluation and optimization of the thermodynamic properties and phase diagrams of the CaO-FeO, CaO-MnO, FeO-MgO, FeO-MnO, and MgO-MnO systems10.1111/j.1151-2916.1993.tb08334.x ↗
50. Élaboration de la fonte et de l’acier, données thermodynamiques
51. An assessment of the Fe-Mn system10.1016/0364-5916(87)90013-7 ↗
52. Kinetics, microstructures and mechanism of internal oxidation -- its effect and prevention in high temperature alloy oxidation10.5006/0010-9312-21.12.382 ↗
53. Lattice diffusion in iron – a review
54. Thermomechanical properties of iron and iron-carbon alloys: density and thermal contraction10.1002/srin.199101722 ↗
55. The classical theory of nucleation
56. Modeling of nucleation processes
57. Properties of the elements and inorganic compounds
58. Ab inito study of the structural, electronic, and magnetic properties of MnO(100) and MnO(110)10.1103/PhysRevB.75.035404 ↗
59. First-principles studies of antiferromagnetic MnO and NiO surfaces10.1143/JPSJ.72.588 ↗
60. Surface energies
61. The analysis of grain boundary diffusion measurements10.1088/0508-3443/14/6/317 ↗