journal article·2025-03

Effects of pH and Cr content of materials on flow-accelerated corrosion and their prediction

Kazutoshi Fujiwara, Kimitoshi Yoneda

Corrosion Science· Volume 244
Publisher page

Abstract

The efficient management of flow-accelerated corrosion (FAC) occurring in power plant piping requires a deeper understanding of the mechanism underlying FAC. In this study, FAC tests were conducted on carbon steels with different Cr contents in flowing water at 418 K to evaluate the overlapping effects of various factors. In aqueous solutions with pHs 7–9.8, the FAC rate and the dissolved oxygen concentration required for FAC suppression decreased with increasing Cr content. Cr in the material accumulates in the outermost layer of the oxide film as FAC progresses, and the accumulation is found to be more enhanced in neutral solutions than in alkaline solutions. This finding is consistent with our FAC model.
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Research context

OpenAlex topics: Corrosion Behavior and Inhibition · Metallurgical Processes and Thermodynamics · Concrete and Cement Materials Research

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References (30)

Show source-provided references
1. Flow accelerated corrosion (FAC) in nuclear power plant components
2. The Japan Society of Mechanical Engineers, Code for Power Generation Facilities -Ruleson Pipe Wall Thinning Management-, JSME S CA1-2016 (2016).
3. Recommendations for an effective flow-accelerated corrosion program (NSCA-202L-R3)
4. Pipe wall thinning management at electricite de France (EDF)
5. Erosion-corrosion in nuclear steam generators
6. Flow accelerated corrosion study using rotating disk specimen
7. Erosinskorrosion in Wasser-Dampfkreislaufen
8. Electrochemical measurements of carbon steel under high flow rate condition and thermodynamic solubility of iron
9. Redox condition effect on flow accelerated corrosion: influence of hydrazine and oxygen
10. The influence of oxygen and hydrazine on the erosion-corrosion behaviour and electrochemical potentials of carbon steel under boiler feedwater conditions
11. Kim · Arch. Metall. Mater. · 2017 · 62 · 138310.1515/amm-2017-0213 ↗
12. Sanchez-Caldera · J. Eng. Gas. Turbines Power · 1988 · 110 · 18010.1115/1.3240099 ↗
13. Model of physico-chemical effect on flow accelerated corrosion in power plant10.1016/j.corsci.2011.06.027 ↗
14. High-temperature thermodynamic data for species in aqueous solution
15. The solubility of magnetite and hydrolysis of ferrous ion in aqueous solutions at elevated temperatures10.1016/0021-9614(70)90098-4 ↗
16. Ionic conductivity and diffusion at infinite dilution
17. Development of flow-accelerated corrosion prediction method (2) Modeling and validation with thinning rate profile data10.1299/mej.17-00415 ↗
18. Effect of dissolved oxygen on flow-accelerated corrosion in neutral and alkaline solutions
19. Effect of low concentration of chromium in carbon steel on flow-accelerated corrosion
20. Erosionskorrosion an nassdampfturbinen, VGB-Kraftwerkstechnik
21. T. Yuasa, S. Watanabe, K. Yoneda, R. Morita, Proc. ASME 2023 Pressure Vessels & Piping Conference.
22. Some aspects of electrochemistry and corrosion mechanisms influencing flow assisted corrosion in candu outlet feeder pipes
23. The mitigation of flow-accelerated corrosion in the feed-water systems of nuclear reactors – the influence of dissolved oxygen under different operating conditions
24. C.M. Bethke, B. Farrell, S. Yeakel, GWB Essentials Guide. 〈https://www.gwb.com/pdf/GWB12/GWBessentials.pdf〉 (accessed 7 February 2023).
25. Corrosion behavior of stainless steels in simulated pwr primary water10.1080/18811248.2008.9711883 ↗
26. Effect of Cr on characteristic of rust layer formed on low alloy steel in flow-accelerated corrosion environment10.1016/S1006-706X(16)30094-2 ↗
27. Effects of Cr and Mo contents on the flow-accelerated corrosion behavior of low alloy steels in the secondary side of pressurized water reactors10.1016/j.jnucmat.2023.154652 ↗
28. Chilton · Mass Transf. Absorpt. Coeff. Ind. Eng. Chem. · 1934 · 26 · 1183
29. Colebrook · Proc. Roy. Soc. Lond. A · 1937 · 161 · 367
30. Chapter 2 Review of Fundamentals”, in