journal article·2025-01Open access

Corrosion inhibition of WE43 Mg alloy by salicylic compounds: Influence of nitro substitution

François-Xavier Perrin, Nadja Leibl, Lénaïk Belec, Armand Fahs, Nicolas Caussé, Nadine Pébère

Corrosion Science· Volume 242

Abstract

The corrosion inhibition of WE43 Mg alloy by salicylic acid (SA) and 3,5-dinitrosalicylic acid (DNSA) was investigated in a 0.2 M NaCl solution using electrochemical techniques, pH measurements, inductive coupled plasma-optical emission spectroscopy (ICP-OES) and SEM-EDX analyses. SA has a poor performance while DNSA was efficient after some hours of immersion in the NaCl solution. The observed behaviour was attributed, for short immersion times, to a buffering effect of DNSA which delayed the Mg(OH) 2 crystal growth on the alloy surface, and for longer immersion times, to an enrichment of the corrosion products layer by the alloying elements. • SA forms soluble complexes and is not effective to protect the WE43 Mg alloy. • DNSA buffers the interfacial pH and leads to an enrichment in Y and Nd of the corrosion products layers. • The DNSA efficiency is higher for longer immersion times.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Magnesium Alloys: Properties and Applications · Hydrogen Storage and Materials · Corrosion Behavior and Inhibition

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (62)

Show source-provided references
1. Corrosion of magnesium alloys: the role of alloying10.1179/1743280414Y.0000000046 ↗
2. Comprehensive screening of Mg corrosion inhibitors10.1016/j.corsci.2017.07.011 ↗
3. Inhibitor-doped sol-gel coatings for corrosion protection of magnesium alloy AZ3110.1016/j.surfcoat.2009.09.067 ↗
4. Active protection of Mg alloy by composite PEO coating loaded with corrosion inhibitors10.1016/j.apsusc.2019.144462 ↗
5. Improvement of corrosion resistance and biocompatibility of rare-earth WE43 magnesium alloy by neodymium self-ion implantation10.1016/j.corsci.2015.01.049 ↗
6. Chromate-free corrosion protection strategies for magnesium alloys—a review: Part III—corrosion inhibitors and combining them with other protection strategies10.3390/ma15238489 ↗
7. The unexpected role of benzotriazole in mitigating magnesium alloy corrosion: a nucleating agent for crystalline nanostructured magnesium hydroxide film10.1149/2.0781508jes ↗
8. Corrosion inhibition study of aqueous vanadate on Mg alloy AZ3110.1149/2.1171802jes ↗
9. Inhibition of magnesium localised corrosion in chloride containing electrolyte10.1016/j.electacta.2010.03.023 ↗
10. Corrosion inhibition of elektron WE43 magnesium alloy in NaCl solution
11. Alkyl carboxylates as efficient and green inhibitors of magnesium alloy ZE41 corrosion in aqueous salt solution10.1016/j.corsci.2014.04.052 ↗
12. 2-Hydroxy-4-methoxy-acetophenone as an environment-friendly corrosion inhibitor for AZ91D magnesium alloy10.1016/j.corsci.2013.04.005 ↗
13. Research on the inhibition mechanism of tetraphenylporphyrin on AZ91D magnesium alloy10.1016/j.corsci.2012.06.021 ↗
14. Evaluation of the protective ability of typical corrosion inhibitors for magnesium alloys towards the Mg ZK30 variant10.1016/j.corsci.2015.07.028 ↗
15. Unveiling the inhibition mechanism of an effective inhibitor for AZ91 Mg alloy10.1016/j.corsci.2018.12.025 ↗
16. Spectroscopic insight into the role of SDBS on the interface evolution of Mg in NaCl corrosive medium10.1016/j.corsci.2020.109215 ↗
17. New understanding on the mechanism of organic inhibitors for magnesium alloy10.1016/j.corsci.2022.110118 ↗
18. Controlling the ignition and flammability of magnesium for aerospace applications10.1016/j.corsci.2014.04.047 ↗
19. Flammability and the oxidation kinetics of the magnesium alloys AZ31, WE43, and ZE1010.1016/j.corsci.2015.07.020 ↗
20. Corrosion rate determination of rare-earth Mg alloys in a Na2SO4 solution by electrochemical measurements and inductive coupled plasma-optical emission spectroscopy10.1016/j.jma.2018.12.002 ↗
21. Corrosion resistance of WE43 and AZ91D magnesium alloys with phosphate PEO coatings10.1016/j.corsci.2008.03.002 ↗
22. Linking the microstructure of a heat-treated WE43 Mg alloy with its corrosion behavior10.1016/j.corsci.2015.09.005 ↗
23. Different role of second phase in the micro-galvanic corrosion of WE43 Mg alloy in NaCl and Na2SO4 solution10.1016/j.jma.2020.12.013 ↗
24. Corrosion processes of Mg–Y–Nd–Zr alloys in Na2SO4 electrolyte10.1016/j.corsci.2013.03.036 ↗
25. Corrosion resistance of WE43 and AZ91D magnesium alloys with phosphate PEO coatings10.1016/j.corsci.2008.03.002 ↗
26. Influence of a silane treatment on the corrosion resistance of a WE43 magnesium alloy10.1016/j.surfcoat.2005.02.073 ↗
27. Cerium phosphate-based inhibitor for smart corrosion protection of WE43 magnesium alloy10.1016/j.electacta.2020.137368 ↗
28. Aqueous molybdate provides effective corrosion inhibition of WE43 magnesium alloy in sodium chloride solutions10.1016/j.corsci.2021.109664 ↗
29. In situ surface film evolution during Mg aqueous corrosion in presence of selected carboxylates10.1016/j.corsci.2020.108484 ↗
30. ATR-FTIR in Kretschmann configuration integrated with electrochemical cell as in situ interfacial sensitive tool to study corrosion inhibitors for magnesium substrates10.1016/j.electacta.2020.136166 ↗
31. The effect of carboxylate compounds on Volta potential and corrosion inhibition of Mg containing different levels of iron10.1016/j.corsci.2021.109937 ↗
32. Tailoring corrosion and discharge performance of Mg anode by corrosion inhibitor10.1016/j.electacta.2022.141471 ↗
33. On the stability of the oxides film formed on a magnesium alloy containing rare-earth elements10.1016/j.electacta.2018.08.093 ↗
34. Susceptibility of rare-earth-magnesium alloys to micro-galvanic corrosion10.1016/j.corsci.2010.08.006 ↗
35. Solubility and melting properties of salicylic acid10.1021/je060134d ↗
36. Solubility of 3,5-dinitrosalicylic acid in fourteen pure solvents over temperatures from 278.15 to 323.15 K10.1021/acs.jced.0c00122 ↗
37. Dissipative particle dynamics investigation of the transport of salicylic acid through a simulated in vitro skin permeation model10.3390/ph11040134 ↗
38. Formation and stability of inoganic complexes in solution
39. Investigation of magnesium corrosion in aerated sodium sulfate solution by electrochemical impedance spectroscopy10.1016/0013-4686(90)87043-2 ↗
40. An impedance investigation of the mechanism of pure magnesium corrosion in sodium sulfate solutions10.1149/1.2401056 ↗
41. The anodic surface film and hydrogen evolution on Mg10.1016/j.corsci.2015.05.047 ↗
42. An investigation of the corrosion mechanisms of WE43 Mg alloy in a modified simulated body fluid solution: The influence of immersion time10.1016/j.corsci.2014.07.015 ↗
43. A new look on the corrosion mechanism of magnesium: an EIS investigation at different pH10.1016/j.corsci.2022.110463 ↗
44. Corrosion behaviour of a nominally high purity Mg ingot produced by permanent mould direct chill casting10.1016/j.corsci.2012.04.030 ↗
45. Electrochemical estimation of the corrosion rate of magnesium/aluminium alloys10.1155/2010/953850 ↗
46. Corrosion of non-ferrous alloys. III. magnesium alloys10.1002/9783527603978.mst0406 ↗
47. The Influence of microstructure on the corrosion of magnesium alloy ZEK10010.5006/1387 ↗
48. Film breakdown and nano-porous Mg(OH)2 formation from corrosion of magnesium alloys in salt solutions10.1149/2.0171504jes ↗
49. Review of recent developments in the field of magnesium corrosion10.1002/adem.201400434 ↗
50. Corrosion mechanisms of magnesium alloys10.1002/(SICI)1527-2648(199909)1:1<11::AID-ADEM11>3.0.CO;2-N ↗
51. Corrosion mechanism and hydrogen evolution on Mg10.1016/j.cossms.2014.09.005 ↗
52. Lange · 1999
53. Potentiometric equilibrium constants for complexes of nitrosalicylic acids and Mg(II), Mn(II), Cu(II) and Zn(II)10.5935/0103-5053.19960038 ↗
54. Equilibriums and kinetics of complex formation at gallium(III). Evidence for an associative mode of activation10.1021/ic00138a016 ↗
55. ASM handbook
56. Study on the early surface films formed on Mg-Y molten alloy in different atmospheres10.1016/j.jma.2015.06.003 ↗
57. Exploring the possibility of protective surface oxides upon Mg alloy AZ31 via lutetium additions10.1016/j.corsci.2014.08.015 ↗
58. Ternary complexes: equilibrium studies of mixed-ligand complexes of neodymium ion with carboxylic and phenolic acids in aqueous medium10.1246/bcsj.49.2142 ↗
59. Stability constants of mixed ligand complexes of lanthanide(III) and yttrium(III) with complexone and substituted salicylic acids
60. Hydrolysis of Scaq3+ and the stabilities of scandium (III)-Tiron chelates in aqueous solution10.1016/0022-1902(71)80517-1 ↗
61. A.E. Martell, R.M. Smith, NIST Critical Stability Constants of Metal Complexes, NIST database 46, Gaithersburg, MD, USA, 1994.
62. A new concept for corrosion inhibition of magnesium: suppression of iron re-deposition10.1016/j.elecom.2015.10.023 ↗