journal article·2024-06

The polyelectrolyte as corrosion inhibitor for the aluminum anode in alkaline-based primary battery: A comparative study with its monomer

Guangxu Wu, Zhe Xiao, Zesong Wei, Jie Gao, Shuoqi Li, Guoxin Zhang, Lanyue Cui, Rongchang Zeng

Corrosion Science· Volume 233
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Abstract

In this work, the corrosion inhibition effect of the polyelectrolyte , poly(diallyl dimethylammonium chloride) (PDDA), as an additive in the alkaline Al-air battery is described and compared with the monomer dimethyl diallyl ammonium chloride (DMDAAC). Electrochemical measurement and morphology analysis are employed to characterize the inhibition effects of the additives. Additionally, the discharge characteristics of the battery are explored, and the capacity density is derived. These results demonstrate that the polymer additive suppresses Al samples` corrosion process more effectively than DMDAAC. The adsorption mechanism is proposed based on the Freundlich adsorption isotherm theory and quantum mechanical calculation.
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Research context

OpenAlex topics: Conducting polymers and applications · Corrosion Behavior and Inhibition · Fuel Cells and Related Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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