journal article·2013-12

Comments on the paper entitled “Observations of the galvanostatic dissolution of pure magnesium” by N.T. Kirkland, G. Williams and N. Birbilis

Zhiming Shi, Andrej Atrens

Corrosion Science· Volume 77
Publisher page

Abstract

Kirkland et al. [1] state that their data was centred about n=2, where n is the charge per Mg ion delivered by the external current. However, values of n less than n=2 are calculated for each experimental condition from their data (Table 1). These calculated values are consistent with Mg corrosion involving the uni-positive Mg ion. However, their experimental details are unclear and contradictory, and consequently there is uncertainty concerning any conclusions made from the data. Kirkland et al. [1] dismiss much of the prior relevant literature. A summary is provided.
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Research context

OpenAlex topics: Magnesium Alloys: Properties and Applications · Corrosion Behavior and Inhibition · Aluminum Alloy Microstructure Properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (18)

Show source-provided references
1. Observations of the galvanostatic dissolution of pure magnesium10.1016/j.corsci.2012.08.029 ↗
2. Galvanostatic anodic polarisation curves and galvanic corrosion of high purity Mg in 3.5%NaCl saturated with Mg(OH)210.1016/j.corsci.2011.12.002 ↗
3. Galvanostatic anodic polarisation curves and galvanic corrosion of AZ31B in 0.01 M Na2SO4 saturated with Mg(OH)210.1002/adem.201100257 ↗
4. The negative difference effect and unipositive Mg+10.1002/adem.200600275 ↗
5. The anodic oxidation of magnesium metal: evidence for the existence of unipositive magnesium10.1021/ja01631a013 ↗
6. Electrochemical corrosion of pure magnesium in 1N NaCl10.1016/S0010-938X(96)00172-2 ↗
7. The anodic dissolution of magnesium in chloride and sulphate solutions10.1016/S0010-938X(97)00090-5 ↗
8. Corrosion mechanisms of magnesium alloys10.1002/(SICI)1527-2648(199909)1:1<11::AID-ADEM11>3.0.CO;2-N ↗
9. Understanding magnesium corrosion mechanism: a framework for improved alloy performance10.1002/adem.200310405 ↗
10. Recent progress in corrosion and protection of magnesium alloys10.1002/adem.200500013 ↗
11. G. Song, Corrosion electrochemistry of magnesium (Mg) and its alloys, Chapter 1 in Corrosion of magnesium alloys, in: G.L. Song (Ed.), Woodhead Cambridge, 2011, pp. 3–65.10.1533/9780857091413.1.3 ↗
12. Localised corrosion of magnesium in chloride-containing electrolyte studied by a scanning vibrating electrode technique10.1149/1.2918900 ↗
13. The anodic dissolution of Mg in NaCl and Na2SO4 electrolytes by atomic emission spectroelectrochemistry10.1016/j.corsci.2010.02.038 ↗
14. A new theory for the negative difference effect in magnesium corrosion
15. The negative difference effect of magnesium and of the AZ91 alloy in chloride and stannate solutions10.1016/j.corsci.2010.03.010 ↗
16. Insights into microstructure based corrosion mechanism of high pressure die cast AM50 alloy10.1016/j.corsci.2012.04.016 ↗
17. An innovative specimen configuration for the study of Mg Corrosion10.1016/j.corsci.2010.09.016 ↗
18. Corrosion behaviour of a nominally high purity Mg ingot produced by permanent mould direct chill casting10.1016/j.corsci.2012.04.030 ↗