Protection of titanium alloys against high temperature oxidation during closed-die forging: Structural analysis of the boro-silicate glass coating/Ti-6Al-4V alloy interfacial region by correlative imaging
Source abstract
Abstract
We analyse herein the interfacial region formed between a borosilicate glass coating and Ti-6Al-4V alloy after a transient of 8 h at 1150 °C. The correlation of two optical and electron microscopy methods (Raman and Backscatter Electron Diffraction imaging) enabled an accurate description of this particular interface. This interface is composed of five different phases, namely Ti2O3, TiB2, TiB, Ti5Si3 and Ti6Si2B, and it proves to be protective against oxygen permeation. Finally, this study also enabled the development of a Raman database for Ti borides, silicides, and borosilicides, in part from experimental and more completely from theoretical (DFT computations) data.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Nuclear Materials and Properties · Metal and Thin Film Mechanics · Ion-surface interactions and analysis
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References (59)
Show source-provided references
1. MAMA project, 〈https://www.irt-saintexupery.com/mama-project-30-raw-material-savings-for-titanium-aerostructure-parts〉.
2. Study on modified water glass used in high temperature protective glass coating for Ti-6Al-4V titanium alloy10.3390/coatings8050158 ↗
3. The oxidation and oxygen permeation resistance of quartz particle-reinforced aluminosilicate glass coating on titanium alloy10.1111/j.1551-2916.2011.04587.x ↗
4. Influence of MoO3 on boron aluminosilicate glass-ceramic coating for enhancing titanium high-temperature oxidation resistance10.1016/j.jallcom.2017.09.189 ↗
5. Oxidation behaviour of glass–quartz and glass–quartz–aluminium composite coatings on Ti–6Al–4V alloy10.1179/1743294414Y.0000000375 ↗
6. Effect of SiO2–Al2O3 glass composite coating on the oxidation behavior of Ti60 alloy10.3390/ma13225085 ↗
7. Oxidation protection of commercial-purity titanium by Na2O–CaO–SiO2 and Na2O–CaO–Al2O3–SiO2 glass–ceramic coatings10.1016/j.ceramint.2014.08.075 ↗
8. SiO2–Al2O3–glass composite coating on Ti–6Al–4V alloy: oxidation and interfacial reaction behavior10.1016/j.corsci.2013.05.010 ↗
9. Glass-Ceramic protective coating for titanium alloys10.1111/j.1151-2916.2002.tb00547.x ↗
10. Microstructure and properties characterisation of the double layered glass–ceramic coating on near-α titanium alloy10.1016/j.surfcoat.2010.04.008 ↗
11. Glass–ceramic coatings on titanium alloys for high temperature oxidation protection: oxidation kinetics and microstructure10.1016/j.corsci.2013.04.041 ↗
12. Vibrational spectroscopy of binary titanium borides: first-principles and experimental studies
13. Lattice dynamical properties of ScB2, TiB2, and VB2 compounds10.1016/j.ssc.2009.07.010 ↗
14. Lattice dynamics of binary and ternary phases in Ti–Si–C system: A combined Raman spectroscopy and density functional theory study10.1016/j.matchemphys.2015.10.057 ↗
15. Fundamental properties of Ti6Si2B—a new ternary phase in the Ti–Si–B system10.1088/2053-1591/aa7e00 ↗
16. Raman spectra of titanium dioxide10.1016/0022-4596(82)90006-8 ↗
17. Raman spectra of titanium dioxide (anatase, rutile) with identified oxygen isotopes (16, 17, 1810.1039/c2cp42763j ↗
18. Raman study of the semiconductor-metal transition in Ti2O310.1103/PhysRevB.3.4253 ↗
19. Isothermal section of the Ti-Si-B system at 1250 ° C in the Ti-TiSi2-TiB2 region10.1590/S1516-14392013005000172 ↗
20. Thermodynamic modeling and experimental investigation of the Ti-rich corner of the Ti–Si–B system10.1016/j.intermet.2005.02.001 ↗
21. First principles calculation of single-crystal elastic constants of titanium tetraboride (Ti3B4) and experimental validation10.1111/jace.15562 ↗
22. Ab initio molecular dynamics for liquid metals10.1103/PhysRevB.47.558 ↗
23. Generalized gradient approximation made simple10.1103/PhysRevLett.77.3865 ↗
24. Inhomogeneous electron gas10.1103/PhysRev.136.B864 ↗
25. Self-Consistent equations including exchange and correlation effects10.1103/PhysRev.140.A1133 ↗
26. From ultrasoft pseudopotentials to the projector augmented-wave method10.1103/PhysRevB.59.1758 ↗
27. Special points for Brillouin-zone integrations10.1103/PhysRevB.13.5188 ↗
28. First-principles calculations of the ferroelastic transition between rutile-type and CaCl2-type SiO2 at high pressures10.1103/PhysRevB.78.134106 ↗
29. Raman imaging in corrosion science: High-temperature oxidation of the zirconium alloys used in the nuclear industry as an example10.1002/jrs.6181 ↗
30. Potentialities of Raman imaging for the analysis of oxide scales formed on Zircaloy-4 and M5® in air at high temperature10.1007/s11085-012-9331-5 ↗
31. Review of multidimensional data processing approaches for Raman and infrared spectroscopy10.1140/epjti/s40485-015-0018-6 ↗
32. Multivariate Curve Resolution (MCR). Solving the mixture analysis problem10.1039/C4AY00571F ↗
33. Removal of alpha case on titanium alloy surfaces using chemical milling10.1080/10910344.2017.1284558 ↗
34. Preparation and oxidation behavior of SiO2–Al2O3–glass composite coating on Ti–47Al–2Cr–2Nb alloy10.1016/j.surfcoat.2012.12.022 ↗
35. Bioactive glass coatings for orthopedic metallic implants10.1016/S0955-2219(03)00303-0 ↗
36. Structural characterization of the metal/glass interface in bioactive glass coatings on Ti-6Al-4V10.1023/A:1011296903316 ↗
37. Interaction of titanium with silica after rapid thermal annealing in argon, nitrogen, and oxygen10.1111/j.1151-2916.1989.tb06005.x ↗
38. Temporary enamel coatings for oxidation protection of Ti–6Al–4V at its hot working temperature of 1200 °C10.1016/j.jallcom.2019.152295 ↗
39. Measurements of Raman scattering by electrons in metals: the effects of electron-phonon coupling10.1103/PhysRevB.86.045138 ↗
40. Titanium corrosion in molten glasses. Part 1: immersion tests and corrosion kinetics
41. Early oxidation behavior of Si-coated titanium10.1016/j.corsci.2018.05.035 ↗
42. Data on the early oxidation of SiO2-coated pure Ti and bulk Ti5Si3 at 800 °C10.1016/j.dib.2018.08.173 ↗
43. Thermodynamic aspects of nanostructured Ti5Si3 formation during mechanical alloying and its characterization10.1007/s12034-012-0298-2 ↗
44. TiB whisker coating on titanium surfaces by solid-state diffusion: Synthesis, microstructure, and mechanical properties10.1007/s11661-002-0336-6 ↗
45. 2007
46. VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data10.1107/S0021889811038970 ↗
47. Band structure diagram paths based on crystallography10.1016/j.commatsci.2016.10.015 ↗
48. Bilbao crystallographic server: useful databases and tools for phase-transition studies10.1080/0141159031000076110 ↗
49. The Al-B (aluminum-boron) system10.1007/BF02649415 ↗
50. Some aspects of the high-temperature behaviour of an in situ Ti-Ti5Si3 eutectic composite
51. Site Occupation and local vibration of hydrogen isotopes in hexagonal Ti5S3 H(D)1−x10.2320/matertrans1960.27.639 ↗
52. Thermal expansion of the Ti5Si3 and Ti6Si2B phases investigated by high-temperature X-ray diffraction10.1016/j.intermet.2005.05.007 ↗
53. Shape transition in the initial growth of titanium silicide clusters on Si(111)10.1143/JJAP.43.4541 ↗
54. Structure
55. Villars · 1985
56. Ti6Si2B, a new ternary phase in the Ti–Si–B system10.1016/j.intermet.2004.01.001 ↗
57. Experimental evidence for the existence of the Ti3B4 phase10.1111/j.1151-2916.1986.tb04701.x ↗
58. The crystal structure of TiB10.1107/S0365110X5400014X ↗
59. H-TiO oder TiB2?? – eine Korrektur10.1002/zaac.19966220618 ↗